Study of nanoclay blends based on poly(ethylene terephthalate)/poly(ethylene naphthalene 2,6-dicarboxylate) prepared by reactive extrusion
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Foued Zouai
Abstract
The success of processing compatible blends, based on poly(ethylene terephthalate) (PET)/poly(ethylene naphthalene 2,6-dicarboxylate) (PEN)/clay nanocomposites in one step by reactive melt extrusion is described. Untreated clay was first purified and functionalized “in situ” with a compound based on an organic peroxide/sulfur mixture and (tetramethylthiuram disulfide) as the activator for sulfur. The PET and PEN materials were first separately mixed in the molten state with functionalized clay. The PET/4 wt% clay and PEN/7.5 wt% clay compositions showed total exfoliation. These compositions, denoted nPET and nPEN, respectively, were used to prepare new nPET/nPEN nanoblends in the same mixing batch. The nPET/nPEN nanoblends were compared to neat PET/PEN blends. The blends and nanocomposites were characterized using various techniques. Microstructural and nanostructural properties were investigated. Fourier transform infrared spectroscopy (FTIR) results showed that the exfoliation of tetrahedral clay nanolayers is complete and the octahedral structure totally disappears. It was shown that total exfoliation, confirmed by wide angle X-ray scattering (WAXS) measurements, contributes to the enhancement of impact strength and tensile modulus. In addition, WAXS results indicated that all samples are amorphous. The differential scanning calorimetry (DSC) study indicated the occurrence of one glass transition temperature Tg, one crystallization temperature Tc and one melting temperature Tm for every composition. This was evidence that both PET/PEN and nPET/nPEN blends are compatible in the entire range of compositions. In addition, the nPET/nPEN blends showed lower Tc and higher Tm values than the corresponding neat PET/PEN blends. In conclusion, the results obtained indicate that nPET/nPEN blends are different from the pure ones in nanostructure and physical behavior.
Acknowledgments
FJBC gratefully acknowledges the MINECO, Spain (Grant FIS2010-18069), for the generous support of this investigation. SB, FZ, DB, FJBC and MEC thank the financial support from the CSIC of the Project I-COOP0123 between the CSIC and the University of Sétif.
References
[1] Pramoda KP, Ashiq M, Phang IY, Tianxi L. Polym. Int. 2005, 54, 226–232.Suche in Google Scholar
[2] Jarrar R, Mahmood AM, Haik Y. J. Appl. Polym. Sci. 2012, 124, 1880–1890.Suche in Google Scholar
[3] Calderas F, Guadalupe SO. In Advances in Nanocomposites-Synthesis, Characterization and Industrial Applications, Reddy BSR, Ed., InTech: Rijeka, Croatia, 2011, p. 101–104.Suche in Google Scholar
[4] Wu G, Cuculo JA. Polymer 1999, 40, 1011–1018.10.1016/S0032-3861(98)00317-6Suche in Google Scholar
[5] Jaehyun K, Whanki K, Jusun Y, Ho-Jong K. Polymer(Korea) 2011, 35, 249–253.Suche in Google Scholar
[6] Bouhelal S, Cagiao ME, Khellaf S, Tabet H, Djellouli B, Benachour D, Baltà-Calleja FJ. J. Appl. Polym. Sci. 2010, 115, 2654–2662.Suche in Google Scholar
[7] Burnside SD, Giannelis EP. Chem. Mater. 1995, 7, 1597–1600.Suche in Google Scholar
[8] Kampert WG, Sauer BB. Polymer 2001, 42, 8703–8714.10.1016/S0032-3861(01)00364-0Suche in Google Scholar
[9] Becker O, Simon GP, Rieckmann T, Forsythe J, Rosu R, Volker S, O’Shea M. Polymer 2001, 42, 1921–1929.10.1016/S0032-3861(00)00485-7Suche in Google Scholar
[10] Lee HM, Suh Dj, Kil SB, Park OO, Yoon KH. Korea Aust. Rheol. J. 1999, 11, 219–223.Suche in Google Scholar
[11] Park DS, Kim SH. J. Appl. Polym. Sci. 2003, 87, 1842–1851.Suche in Google Scholar
[12] Guo M, Brittain WJ. Macromolecules 1998, 31, 7166–7171.10.1021/ma9716903Suche in Google Scholar
[13] Becker O, Simon GP, Rieckmann T, Forsythe JS, Rosu RF, Volker S. J. Appl. Polym. Sci. 2002, 83, 1556–1567.Suche in Google Scholar
[14] Tonelli AE. Polymer 2002, 43, 637–642.10.1016/S1089-3156(00)00028-3Suche in Google Scholar
[15] Bouhelal S, Cagiao ME, Benachour D, Djellouli B, Rong L, Hsiao BS, Baltà Calleja FJ. J. Appl. Polym. Sci. 2010, 117, 3262–3270.Suche in Google Scholar
[16] Denchev Z, Ezquerra TA, Nogales A, Sics I, Alvarez C, Broza G, Schulte K. J. Polym. Sci., Part B: Polym. Phys. 2008, 40, 2570–2578.Suche in Google Scholar
[17] Salavagione HJ, Cazorla-Amorós D, Tidjane S, Belbachir M, Bouyoucef A, Morallón E. Eur. Polym. J. 2008, 44, 1275–1284.Suche in Google Scholar
[18] Baltá Calleja FJ, Fakirov S. In Microhardness of Polymers, Cambridge University Press: Cambridge, UK, 2000, Chapter 1, 3.10.1017/CBO9780511565021Suche in Google Scholar
[19] Nayak PS, Singh BK. Bull. Mater. Sci. 2007, 30, 235–238.Suche in Google Scholar
[20] Kim J-S, Lee D-S. Polym. J. 2000, 32, 616–618.Suche in Google Scholar
[21] Huang Z-M, Zhang YZ, Kotaki M, Ramakrishna S. Compos. Sci. Technol. 2003, 63, 2223–2253.Suche in Google Scholar
[22] Kim JH, Min BR, Kang YS. Macromolecules 2006, 39, 1297–1299.10.1021/ma052436aSuche in Google Scholar
[23] Brostow W, Chiu R, Kalogeras IM, Vassilikou-Dova A. Mater. Lett. 2008, 62, 3152–3155.Suche in Google Scholar
[24] Hendrick TM. Structure-Miscibility Relationships in Weakly Interacting Polymer Blends, Thesis of Master, New York: College of Science Department of Chemistry, Rochester Institute of Technology, 2012.Suche in Google Scholar
[25] Fermeglia M, Cosoli P, Ferrone M, Piaccarlo S, Mensitieri G, Pricl S. J. Polym. 2006, 47, 5979–5989.Suche in Google Scholar
©2014 by Walter de Gruyter Berlin/Boston
Artikel in diesem Heft
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- Study of nanoclay blends based on poly(ethylene terephthalate)/poly(ethylene naphthalene 2,6-dicarboxylate) prepared by reactive extrusion
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Artikel in diesem Heft
- Frontmatter
- Original articles
- Effect of shear factor on bubble nucleation of polystyrene using supercritical fluid as a foaming agent
- The application of carbon black and printing ink technology in molded interconnect devices
- Synthesis and performance of a self crosslinkable acrylate copolymer with high compatibility for an oil well cement modifier
- Preparation and properties of multilayered polymer/nanodiamond composites via an in situ technique
- Study of nanoclay blends based on poly(ethylene terephthalate)/poly(ethylene naphthalene 2,6-dicarboxylate) prepared by reactive extrusion
- Natural compounds as light stabilizer for a starch-based biodegradable polymer
- Studies on polyimides containing thermoplastic-thermosetting merged segments
- Synthesis and characterization studies of γ-radiation crosslinked poly(acrylic acid/2-acrylamido-2-methyl propane sulfonic acid) hydrogels
- Fabrication and characteristics study of ITO/DBSA/PSS/PPY/Al SCHOTTKY junction diode
- Hydrophobic property of hierarchical polymer surfaces fabricated by precision tooling machine
