Home Physical Sciences Natural compounds as light stabilizer for a starch-based biodegradable polymer
Article
Licensed
Unlicensed Requires Authentication

Natural compounds as light stabilizer for a starch-based biodegradable polymer

  • NadkaTz. Dintcheva EMAIL logo , Francesco Paolo La Mantia and Rossella Arrigo
Published/Copyright: March 19, 2014
Become an author with De Gruyter Brill

Abstract

The photooxidation behavior of a commercial starch-based biodegradable polymer, i.e., new generation Mater-Bi, loaded with natural stabilizers was investigated in consideration for outdoor agricultural applications. The photooxidation behavior of the biodegradable films was monitored mainly by mechanical tests and spectroscopic analysis. In order to formulate biodegradable films without any synthetic compounds, suitable for outdoor applications and with good photooxidation stability, antioxidants such as α-tocopherol and quercetin (Q) were considered. The results obtained using natural compounds were compared with those obtained by using a synthetic antioxidant and a light stabilizer. Among the investigated natural compounds, the flavonoid compound seemed to work better than the antioxidant and the improvement in the photooxidation behavior of the biodegradable film was very similar to that obtained using the synthetic light stabilizer. A flavonoid compound can be considered as an outstanding natural stabilizer to replace synthetic light stabilizers in the formulation of 100% natural compounds based films, suitable for outdoor applications.


Corresponding author: NadkaTz. Dintcheva, Dipartimento di Ingegneria Civile, Ambientale, Aerospaziale, dei Materiali, Università di Palermo, Viale delle Scienze, Ed. 6, 90128 Palermo, Italy, e-mail:

Acknowledgments

Thanks are due to Novamont for supplying the Mater-Bi CF04P (MB) and for the valuable discussions.

References

[1] Bastioli C, Ed., Handbook of Biodegradable Polymers, Rapra Technol Lim: Shropshire, UK, 2005.Search in Google Scholar

[2] Platt DK, Ed., Biodegradable Polymers – Market Report, Rapra Technol Lim: Shropshire, UK, 2006.Search in Google Scholar

[3] Scott G, Gilead D, Eds., Degradable Polymers, Chapman & Hall: London, 1995.10.1007/978-94-011-0571-2Search in Google Scholar

[4] Copinet A, Bertrand C, Govindin S, Coma V, Couturier Y. Chemosphere 2004, 55, 763–773.10.1016/j.chemosphere.2003.11.038Search in Google Scholar PubMed

[5] Tsuji H, Echizen Y, Mishimura Y. Polym. Degrad. Stab. 2006, 91, 1128–1137.Search in Google Scholar

[6] Bocchini S, Fukushima K, Di Blasio A, Fina A, Frache A, Geobaldo F. Biomacromol. 2010, 11, 2919–2926.Search in Google Scholar

[7] Byun Y, Kim YT, Whiteside S. J. Food Eng. 2010, 100, 239–244.Search in Google Scholar

[8] Gardette M, Therias S, Gardette J-L, Murariu M, Dubois Ph. Polym. Degrad. Stab. 2011, 96, 616–623.Search in Google Scholar

[9] Dintcheva NTz, La Mantia FP. Polym. Degrad. Stab. 2007, 92, 630–634.Search in Google Scholar

[10] Copinet A, Bertrand C, Longieras A, Coma V, Couturier Y. J. Polym. Env. 2003, 11, 169–179.Search in Google Scholar

[11] La Mantia FP, Dintcheva NTz. J. Appl. Polym. Sci. 2004, 91, 2244–2255.Search in Google Scholar

[12] Dintcheva NTz, La Mantia FP. Polym. Degrad. Stab. 2004, 83, 1041–1044.Search in Google Scholar

[13] La Mantia FP, Dintcheva NTz. Plast. Rubber Compos. Macromol. Eng. 2004, 33, 184–186.Search in Google Scholar

[14] La Mantia FP. In Handbook of Polymer Degradation, Halim Hamid S, Amin MB, Maadhah AG, Eds., Marcel Dekker Ind: New York, USA, 1992.Search in Google Scholar

[15] Cerruti P, Santagata G, Gomez d’Ayala G, Ambrogi V, Carfagna C, Malinconico M, Persico P. Polym. Degrad. Stab. 2011, 96, 839–846.Search in Google Scholar

Received: 2013-7-12
Accepted: 2014-1-24
Published Online: 2014-3-19
Published in Print: 2014-7-1

©2014 by Walter de Gruyter Berlin/Boston

Downloaded on 3.3.2026 from https://www.degruyterbrill.com/document/doi/10.1515/polyeng-2013-0169/html
Scroll to top button