Abstract
A water-dispersed dodecylbenzene sulfonic acid (DBSA)/poly (styrene sulfonic acid) (PSS)/polypyrrole (PPY) composite was prepared by an in situ chemical polymerization method. The prepared solution was spun on indium tin oxide (ITO) glass plates at different rates of 2000 and 3000 rpm. The optical band gap energy (Eg) was calculated by UV spectroscopy. The band gap of the composite thin films was found at 1.89 eV and 1.93 eV, respectively. A Fourier transform infrared (FTIR) spectrum confirms the presence of dopant and co-dopant in the structure. The diode parameters were calculated from current-voltage (I-V) characteristics and discussed. The I-V characteristics of the devices indicated behavior of a Schottky diode. The ideality factor, barrier height (ϕb) and saturation current were investigated. The ϕb was found to be 0.59 eV and 0.52 eV for 2000 rpm and 3000 rpm, respectively. The ideality factor was calculated from the slope of the linear region of the forward bias in the I-V curves and was found to be 6.4 and 13.5. The results of the present study reveal that the 2000 rpm coated ITO/DBSA/PSS/PPY/Al device showed better nonlinearity behavior than the 3000 rpm one.
Acknowledgments
The authors are thankful to the Material Research Center (IISc, Bangalore), University of Hyderabad and Birla Institute of Technology, Mesra, Ranchi for providing instrumental facilities.
References
[1] Tani T, Gill WD, Grant PM, Clarke TC, Street GB. Synth. Met. 1980, 1, 301–306.Search in Google Scholar
[2] Jeon SS, Kim C, Ko J, Im SS. J. Mater. Chem. 2011, 21, 8146–8151.Search in Google Scholar
[3] Tomozawa H, Braun D, Phillips S, Heeger AJ, Kroemer H. Synth. Met. 1987, 22, 63–69.Search in Google Scholar
[4] Tagmouti S, Outzourhit A, Oueriagli A, Khaidar M, Elyacoubi M, Evrard R, Ameziane EL. Thin Solid Films 2000, 379, 272–278.10.1016/S0040-6090(00)01203-7Search in Google Scholar
[5] Tagmouti S, Outzourhit A, Oueriagli A, Khaidar M, Elyacoubi M, Evrard R, Ameziane EL. Sol. Energy Mater. Sol. Cells 2002, 71, 9–18.10.1016/S0927-0248(01)00038-1Search in Google Scholar
[6] Nafdey RA, Kelkar DS. Thin Solid Films 2005, 477, 95–99.10.1016/j.tsf.2004.08.184Search in Google Scholar
[7] Huang L-M, Wen T-C, Gopalan A, Ren F. Mater. Sci. Eng. 2003, 104, 88–95.Search in Google Scholar
[8] Narasimhan M, Hagler M, Cammarata V, Thakur M. Appl. Phys. Lett. 1998, 72, 1063.Search in Google Scholar
[9] Jayamurugan P, Ponnuswamy V, Ashokan S, Mahalingam T. Int. J. Thin Film Sci. Tec. 2013, 3, 261–266.Search in Google Scholar
[10] Huang LM, Chen CH, Wen TC, Gopalan A. Electrochim. Acta 2006, 51, 2756–2764.10.1016/j.electacta.2005.08.012Search in Google Scholar
[11] Wu T-M, Chang H-L, Lin Y-W. Polym. Int. 2009, 58, 1065–1070.Search in Google Scholar
[12] Nabid MR, Entezami AA. J. Applied Polym. Sci. 2004, 94, 254–258.Search in Google Scholar
[13] Bae WJ, Kim KH, Jo WH, Park YH. Macromolecules 2005, 38, 1044–1047.10.1021/ma048850cSearch in Google Scholar
[14] Mahalingam T, Thanikaikarasan S, Dhanasekaran V, Mariappan R, Jayamurugan P, Velumani S, Rhee J-K. Mater. Sci. Eng. B. 2010, 174, 249–252.Search in Google Scholar
[15] Sahoo S, Dhibar S, Hatui G, Bhattacharya P, Das CK. Polymer 2013, 2013, 1–10.Search in Google Scholar
[16] Rhoderick EH, Williams RH. Metal Semiconductor Contacts, 2nd ed., Oxford Science Publications: Oxford, 1988.Search in Google Scholar
[17] Sze SM. Physics of Semiconductor Devices, 2nd ed., John Wiley and Sons (WIE) Publication: New York. 1981.Search in Google Scholar
[18] Islam SS. Semiconductor Physics and Devices, Oxford University Press: New Delhi, 2006.Search in Google Scholar
[19] Crowell CR, Sze SM. Solid-State Electron 1966, 9, 1035–1048.10.1016/0038-1101(66)90127-4Search in Google Scholar
[20] Akkilic K, Uzun I, Kilicoglu T. Synthetic Metals 2007, 157, 297–302.10.1016/j.synthmet.2007.03.009Search in Google Scholar
[21] Ugurel SAE, Serifoglu K, Turut A. Microelectron. Eng. 2008, 85, 2299–2303.Search in Google Scholar
[22] Wessling B. Synth. Met. 1998, 93, 143–154.Search in Google Scholar
©2014 by Walter de Gruyter Berlin/Boston
Articles in the same Issue
- Frontmatter
- Original articles
- Effect of shear factor on bubble nucleation of polystyrene using supercritical fluid as a foaming agent
- The application of carbon black and printing ink technology in molded interconnect devices
- Synthesis and performance of a self crosslinkable acrylate copolymer with high compatibility for an oil well cement modifier
- Preparation and properties of multilayered polymer/nanodiamond composites via an in situ technique
- Study of nanoclay blends based on poly(ethylene terephthalate)/poly(ethylene naphthalene 2,6-dicarboxylate) prepared by reactive extrusion
- Natural compounds as light stabilizer for a starch-based biodegradable polymer
- Studies on polyimides containing thermoplastic-thermosetting merged segments
- Synthesis and characterization studies of γ-radiation crosslinked poly(acrylic acid/2-acrylamido-2-methyl propane sulfonic acid) hydrogels
- Fabrication and characteristics study of ITO/DBSA/PSS/PPY/Al SCHOTTKY junction diode
- Hydrophobic property of hierarchical polymer surfaces fabricated by precision tooling machine
Articles in the same Issue
- Frontmatter
- Original articles
- Effect of shear factor on bubble nucleation of polystyrene using supercritical fluid as a foaming agent
- The application of carbon black and printing ink technology in molded interconnect devices
- Synthesis and performance of a self crosslinkable acrylate copolymer with high compatibility for an oil well cement modifier
- Preparation and properties of multilayered polymer/nanodiamond composites via an in situ technique
- Study of nanoclay blends based on poly(ethylene terephthalate)/poly(ethylene naphthalene 2,6-dicarboxylate) prepared by reactive extrusion
- Natural compounds as light stabilizer for a starch-based biodegradable polymer
- Studies on polyimides containing thermoplastic-thermosetting merged segments
- Synthesis and characterization studies of γ-radiation crosslinked poly(acrylic acid/2-acrylamido-2-methyl propane sulfonic acid) hydrogels
- Fabrication and characteristics study of ITO/DBSA/PSS/PPY/Al SCHOTTKY junction diode
- Hydrophobic property of hierarchical polymer surfaces fabricated by precision tooling machine