Startseite Urea-formaldehyde (UF) resins prepared by means of the aqueous phase of the catalytic pyrolysis of European beech wood. COST Action FP1105
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Urea-formaldehyde (UF) resins prepared by means of the aqueous phase of the catalytic pyrolysis of European beech wood. COST Action FP1105

  • Electra Papadopoulou ORCID logo EMAIL logo , Sotiris Kountouras , Zoe Nikolaidou , Konstantinos Chrissafis , Chrysoula Michailof , Konstantinos Kalogiannis und Angelos A. Lappas
Veröffentlicht/Copyright: 18. Oktober 2016
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Abstract

The aqueous phase resulting from the catalytic pyrolysis (AQcatPy) of biomass has been successfully applied for acidification of urea-formaldehyde (UF) resins. The resins were synthesized at a laboratory scale and characterized by gel permeation chromatography (GPC), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The bonding ability of the resins was tested through the preparation of particle boards (PBs). It was found that the UF resins prepared with AQcatPy as acidification medium have a similar performance to typical UF resins, where conventional chemicals like formic acid (FA) or acetic acid (AA) serve for pH adjustments. The new resins give PBs with somewhat improved thickness swelling (TS) values, while all other properties are at the same level.

Acknowledgments

This research has received funding from the EU 7th Framework Program under grant agreement n° 282873, BIOBOOST “Biomass based energy intermediates boosting biofuel production”.

References

Atar, Í., Nemli, G., Ayrilmis, N., Baharoğlu, M., Sarı, B., Bardak, S., (2014) Effects of hardener type, urea usage and conditioning period on the quality properties of particle board. Mater. Design 56 91–96.10.1016/j.matdes.2013.10.078Suche in Google Scholar

Amen-Chen, C., Riedl, B., Wang, X.-M., Roy, C. (2002a) Softwood bark pyrolysis oil-PF resols. Part 1. Resin synthesis and osb mechanical properties. Holzforschung 56:167–175.10.1515/HF.2002.028Suche in Google Scholar

Amen-Chen, C., Riedl, B., Roy, C. (2002b) Softwood bark pyrolysis oil-PF resols. Part 2. Thermal analysis by DSC and TG. Holzforschung 56:273–280.10.1515/HF.2002.045Suche in Google Scholar

Amen-Chen, C., Riedl, B., Wang, X.-M., Roy, C. (2002c) Softwood bark pyrolysis oil-PF resols. Part 3. Use of propylene carbonate as resin cure accelerator. Holzforschung 56:281–288.10.1515/HF.2002.046Suche in Google Scholar

Azeez, A.M., Meier, D., Odermatt, J. (2011a) Temperature dependence of fast pyrolysis volatile products from European and African biomasses – a review. J. Anal. Appl. Pyrol. 90:81–92.10.1016/j.jaap.2010.11.005Suche in Google Scholar

Azeez, A.M., Meier, D., Odermatt, J., Willner, T. (2011b) Effects of zeolites on volatile products of beech wood using analytical pyrolysis. J. Anal. Appl. Pyrol. 91:296–302.10.1016/j.jaap.2011.03.007Suche in Google Scholar

Bondi, E., Larcher, A. (1969) Process for the preparation of ureaformaldehyde concentrated solutions having a high content of methylenic linkages. US 3450659 A.Suche in Google Scholar

Brennan, M., McLean, J.P., Klingberg, A., Altaner, C., Harris, P.J. (2014) Pyrolysis gas-chromatography mass-spectrometry (Py-GC/MS) to identify compression wood in Pinus radiata saplings. Holzforschung 68:505–517.10.1515/hf-2013-0110Suche in Google Scholar

Cheng, S., Yuan, Z., Anderson, M., Leitch, M., Xu, C. (2012) Synthesis of biobased phenolic resins/adhesives with methylolated wood-derived bio-oil. J. Appl. Polym. Sci. 126:E430–E440.10.1002/app.35655Suche in Google Scholar

Dobele, G., Dizhbite, T., Ponomarenko, J., Urbanovich, I., Kreicberga, J., Kampars, V. (2011) Isolation and characterization of the phenolic fractions of wood pyrolytic oil. Holzforschung 6:503–510.10.1515/hf.2011.049Suche in Google Scholar

Dunky, M. (1998) Urea-formaldehyde (UF) adhesive resins for wood. Int. J. Adhes. Adhes 18:95–107.10.1016/S0143-7496(97)00054-7Suche in Google Scholar

Fink, J.K. (2005) Urea/Formaldehyde Resins in Reactive Polymers Fundamentals and Applications. William Andrew Inc, USA, pp. 283–298.10.1016/B978-081551515-9.50007-XSuche in Google Scholar

Formaini, R. (1990), Urea-formaldehyde compositions and method of manufacture. US 4960856 A.Suche in Google Scholar

Iliopoulou, F.E., Stefanidis, S., Kalogiannis, K., Psarras, A.C., Delimitis, A., Triantafyllidis, S.K., Lappas, A.A. (2014) Pilot-scale validation of Co-ZSM-5 catalyst performance in the catalytic upgrading of biomass pyrolysis vapours. Green Chem. 16:662–674.10.1039/C3GC41575ASuche in Google Scholar

Kim, S., Kim, H.J., Kim, H.S., Lee, Y.K., Yang, H.S. (2006) Thermal analysis study of viscoelastic properties and activation energy of melamine-modified urea-formaldehyde resins. J. Adhes. Sci. Technol. 20:803–816.10.1163/156856106777638671Suche in Google Scholar

Langmaier, F., Kolomazník, K., Mládek, M., Šivarová, J. (2005) Curing urea–formaldehyde adhesives with hydrolysates of chrome-tanned leather waste from leather production. Int. J. Adhes. Adhes 25:101–108.10.1016/j.ijadhadh.2004.04.004Suche in Google Scholar

Lappas, A., Iliopoulou, E., Kalogiannis, K. (2010) Catalysts in biomass pyrolysis. In: Thermochemical Conversion of Biomass to Liquid Fuels and Chemicals, Ed. M. Crocker, RSC Publishing, USA, pp. 263–287.10.1039/9781849732260-00263Suche in Google Scholar

Lee, W.-J., I-Min, Kao, Y.-P., Lee, Y.-Y., Hu, M.-S. (2014) Synthesis of alcohol-soluble phenol-formaldehyde resins from pyrolysis oil of Cunninghamia lanceolata wood and properties of molding plates made of resin-impregnated materials. Holzforschung 68:217–222.10.1515/hf-2013-0068Suche in Google Scholar

Lemonidou, A., Kechagiopoulos, P., Heracleous, E., Voutetakis, S. (2013) Steam reforming of bio-oils to hydrogen. In: The Role of Catalysis for the Sustainable Production of Bio-fuels and Bio-chemicals, Eds. K. Triantafyllidis, A. Lappas, M. Stocker, Elsevier, UK, pp. 467–493.10.1016/B978-0-444-56330-9.00014-0Suche in Google Scholar

Mahfud, F.H., Van Geel, F.P., Venderbosch, R.H., Heeres, H.J. (2008) Acetic acid recovery from fast pyrolysis oil. An exploratory study on liquid-liquid reactive extraction using aliphatic tertiary amines separation. Sci. Techn. 43:3056–3074.10.1080/01496390802222509Suche in Google Scholar

Michailof, C., Sfetsas, T., Stefanidis, S., Kalogiannis, K., Theodoridis, G., Lappas, A. (2014) Quantitative and qualitative analysis of hemicellulose, cellulose and lignin pyOils by comprehensive two-dimensional gas chromatography with time-of-flight mass spectrometry. J. Chromatogr. A 1369:147–160.10.1016/j.chroma.2014.10.020Suche in Google Scholar PubMed

Michailof, C., Kalogiannis, K., Sfetsas, T., Patiaka, D., Lappas, A. (2016) Advanced analytical techniques for bio-oil characterization. WIREs Energy Environ. doi:10.1002/WENE.208.Suche in Google Scholar

Moore, P.W. (1993) Aminourea formaldehyde fertilizer method and composition US 5266097 A.Suche in Google Scholar

Nanayakkara, B., Riddell, M., Harrington, J. (2016) Screening of juvenile Pinus radiata wood by means of Py-GC/MS for compression wood focusing on the ratios of p-hydroxyphenyl to guaiacyl units (H/G ratios). Holzforschung 70:313–321.10.1515/hf-2015-0068Suche in Google Scholar

Park, B-D., Jeong, H-W. (2011) Hydrolytic stability and crystallinity of cured urea-formaldehyde resin adhesives with different formaldehyde/urea mole ratios. Int. J. Adhes. Adhes. 31:524–529.10.1016/j.ijadhadh.2011.05.001Suche in Google Scholar

Qi, Z., Jie, C., Tiejun, W., Ying, X. (2007) Review of biomass pyrolysis oil properties and upgrading research. Energ. Convers. Manage. 48:87–92.10.1016/j.enconman.2006.05.010Suche in Google Scholar

Qiang, L., Wen-Zhi, L., Xi-Feng, Z., (2009) Overview of fuel properties of biomass fast pyrolysis oils. Energ. Convers. Manage. 50:1376–1383.10.1016/j.enconman.2009.01.001Suche in Google Scholar

Quea, Z., Furuno, T., Katoh, S., Nishino, Y. (2007) Effects of urea-formaldehyde resin mole ratio on the properties of particle board. Build Environ. 42:1257–1263.10.1016/j.buildenv.2005.11.028Suche in Google Scholar

Rasrendra, C.B., Girisuta, B., van de Bovenkamp, H.H., Winkelman, J.G.M., Leijenhorst, E.J., Venderbosch, R.H., Windt, M., Meier, D., Heeres, H.J. (2011) Recovery of acetic acid from an aqueous pyrolysis oil phase by reactive extraction using tri-n-octylamine. Chem. Eng. J. 176–177:244–252.10.1016/j.cej.2011.08.082Suche in Google Scholar

Sfetsas, T., Michailof, C., Lappas, A., Li, Q., Kneale, B. (2011) Qualitative and quantitative analysis of pyrolysis oil by gas chromatography with flame ionization detection and comprehensive two-dimensional gas chromatography with time-of-flight mass spectrometry. J. Chromatogr. A 1218:3317–3325.10.1016/j.chroma.2010.10.034Suche in Google Scholar PubMed

Smith, J., Garcia-Perez, M., Das, K.C., (2009) Producing fuel and specialty chemicals from the slow pyrolysis of poultry DAF skimmings. J. Anal. Appl. Pyrol. 86:115–121.10.1016/j.jaap.2009.04.010Suche in Google Scholar

Stefanidis, S.D., Kalogiannis, K.G., Iliopoulou, E.F., Michailof, C.M., Pilavachi, P.A., Lappas A.A. (2014) A study of lignocellulosic biomass pyrolysis via the pyrolysis of cellulose, hemicellulose and lignin. J. Anal. Appl. Pyrol. 105:143–150.10.1016/j.jaap.2013.10.013Suche in Google Scholar

Vargiu, S., Mazzoleni, G., Pezzoli, S. (1978) Process for the preparation of urea-formaldehyde condensates to be used as fertilizers. US 4120685 A.Suche in Google Scholar

Yildiz, G., Ronsse, F., van Duren, R., Prins, W. (2016) Challenges in the design and operation of processes for catalytic fast pyrolysis of woody biomass. Renew. Sust. Energ. Rev. 57:1596–1610.10.1016/j.rser.2015.12.202Suche in Google Scholar

Younesi-Kordkheili, H., Kazemi-Najafi, S., Eshkiki, R.B., Pizzi, A., (2015) Improving urea formaldehyde resin properties by glyoxalated soda bagasse lignin. Eur. J. Wood Prod. 73:77–85.10.1007/s00107-014-0850-4Suche in Google Scholar

Received: 2016-3-17
Accepted: 2016-8-24
Published Online: 2016-10-18
Published in Print: 2016-12-1

©2016 Walter de Gruyter GmbH, Berlin/Boston

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