Startseite UV-induced reduction of Ag+ by diazene sulphonates: new method of metallisation of surfaces
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UV-induced reduction of Ag+ by diazene sulphonates: new method of metallisation of surfaces

  • Eva Baranovicova , Andrej Stasko und Oskar Nuyken EMAIL logo
Veröffentlicht/Copyright: 25. Juni 2016
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Abstract

The metallisation of surfaces would be technologically very simple if it were possible to use the properties of the substances that decompose upon UV irradiation and produce species with a strong redox potential. In this work, diazene sulphonates are presented as possible reducing agents for Ag+ in aqueous solutions and in thin solid layers. The photo-formation of Agnm+ clusters in the presence of diazene sulphonates in solutions was investigated via UV-VIS spectroscopy. Significant differences were observed in the electrical properties of surfaces after photo reduction; these occurred without any additional reducing agent.


Dedicated to Prof. Dr. Robert Kerber on the occasion of his 90th birthday


Acknowledgements

The authors wish to express their gratitude for the George-Manecke grant received and to the Scientific Grant Agency of the Slovak Republic (VEGA project 1/0289/12) for financial support. They also wish to thank Dr. S. D. Pask for his fruitful discussion and many helpful comments during the preparation of this paper.

Supplementary data

Supplementary data associated with this article can be found in the online version of this paper (DOI: 10.1515/chempap-2016-0077).

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Received: 2015-12-16
Revised: 2016-3-13
Accepted: 2016-3-13
Published Online: 2016-6-25
Published in Print: 2016-10-1

© 2016 Institute of Chemistry, Slovak Academy of Sciences

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