Startseite Gas permeation processes in biogas upgrading: A short review
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Gas permeation processes in biogas upgrading: A short review

  • Magda Kárászová EMAIL logo , Zuzana Sedláková und Pavel Izák
Veröffentlicht/Copyright: 24. Juli 2015
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Abstract

Biogas upgrading is a widely studied and discussed topic. Many different technologies have been employed to obtain biomethane from biogas. Methods like water scrubbing or pressure swing adsorption are commonly used and can be declared as well established. Membrane gas permeation found its place among the biogas upgrading methods some years ago. Here, we try to summarize the progress in the implementation of gas permeation in biogas upgrading. Gas permeation has been already accepted as a commercially feasible method for CO2 removal. Many different membranes and membrane modules have been tested and also some commercial devices are available. On the other hand, utilization of gas permeation in other steps of biogas upgrading like desulfurization, drying, or VOC removal is still rather rare. This review shows that membrane gas permeation is able to compete with classical biogas upgrading methods and tries to point out the main challenges of the research.

References

Abatzoglou, N. & Boivin, S. (2009). A review of biogas purification processes. Biofuels, Bioproducts & Biorefining, 3, 42-71. DOI: 10.1002/bbb.117.10.1002/bbb.117Suche in Google Scholar

Air Liquide (2015). MEDAL: Biogaz membrane technology for upgrading biogas to bio-methane. Retrieved January 2, 2015, from http://www.medal.airliquide.com/en/biogazsystems/medal-biogaz-membranes.htmlSuche in Google Scholar

Air Products and Chemicals (2015). PRISM® Membrane Separators for biogas upgrading. Retrieved January 2, 2015, from http://www.airproducts.com/~/media/Files/PDF/products/supply-options/prism-membrane/en-prismmembrane-separators-for-biogas-upgrading.pdfSuche in Google Scholar

Ajhar, M., & Melin, T. (2006). Siloxane removal with gas permeation membranes. Desalination, 200, 234-235. DOI: 10.1016/j.desal.2006.03.308.10.1016/j.desal.2006.03.308Suche in Google Scholar

Baker, R. W. (2002). Future directions of membrane gas separation technology. Industrial & Engineering Chemistry Research, 41, 1393-1411. DOI: 10.1021/ie0108088.10.1021/ie0108088Suche in Google Scholar

BORSIG Membrane Technology (2015). BORSIG Biogas Processing: CO2 separation with membrane technology. Retrieved January 2, 2015, from http://mt.borsig.de/en/products/membrane-units-for-gas-separation/borsig-biogasconditioning.htmlSuche in Google Scholar

Brunetti, A., Scura, F., Barbieri, G., & Drioli, E. (2010). Membrane technologies for CO2 separation. Journal of Membrane Science, 359, 115-125. DOI: 10.1016/j.memsci.2009.11.040.10.1016/j.memsci.2009.11.040Suche in Google Scholar

Brunetti, A., Drioli, E., Lee, Y. M., & Barbieri, G. (2014). Engineering evaluation of CO2 separation by membrane gas separation system. Journal of Membrane Science, 454, 305-315. DOI: 10.1016/j.memsci.2013.12.037.10.1016/j.memsci.2013.12.037Suche in Google Scholar

Corti, A., Fiaschi, D., & Lombardi, L. (2004). Carbon dioxide removal in power generation using membrane technology. Energy, 29, 2025-2043. DOI: 10.1016/j.energy.2004.03.011.10.1016/j.energy.2004.03.011Suche in Google Scholar

Deng, L. Y., & Hägg, M. B. (2010). Techno-economic evaluation of biogas upgrading process using CO2 facilitated transport membrane. International Journal of Greenhouse Gas Control, 4, 638-646. DOI: 10.1016/j.ijggc.2009.12.013.10.1016/j.ijggc.2009.12.013Suche in Google Scholar

Dolejš, P., Poštulka, V., Sedláková, Z., Jandová, V., Vejražka, J., Esposito, E., Jansen, J. C., & Izák, P. (2014). Simultaneous hydrogen sulphide and carbon dioxide removal from biogas by water-swollen reverse osmosis membrane. Separation and Purification Technology, 131, 108-116. DOI: 10.1016/j.seppur.2014.04.041.10.1016/j.seppur.2014.04.041Suche in Google Scholar

Energoklastr (2015). CLEARGAS: Mobile biogas cleaning unit. Retrieved January 2, 2015, from http://www.cleargas.cz/en.pdfSuche in Google Scholar

Evonik Industries (2015). SEPURAN® for biogas upgrading. Retrieved January 2, 2015, from http://www.sepuran.de/product/sepuran/en/product-overview/Pages/default.aspxSuche in Google Scholar

Gu, Y. Y., & Lodge, T. P. (2011). Synthesis and gas separation performance of triblock copolymer ion gels with a polymerized ionic liquid mid-block. Macromolecules, 44, 1732-1736, DOI: 10.1021/ma2001838.10.1021/ma2001838Suche in Google Scholar

Harasimowicz, M., Orluk, P., Zakrzewska-Trznadel, G., & Chmielewski, A. G. (2007). Aplication of polyimide membranes for biogas purification and enrichment. Journal of Hazardous Materials, 144, 698-702. DOI: 10.1016/j.jhazmat. 2007.01.098.Suche in Google Scholar

Heilman,W., Tammela, V., Meyer, J. A., Stannet, V., & Szwarc, M. (1956). Permeability of polymer films to hydrogen sulfide gas. Industrial & Engeneering Chemistry, 48, 821-824. DOI: 10.1021/ie50556a046.10.1021/ie50556a046Suche in Google Scholar

Hudiono, Y. C., Carlisle, T. K., LaFrate, A. L., Gin, D. L., & Noble, R. D. (2011). Novel mixed matrix membranes based on polymerizable room-temperature ionic liquids and SAPO-34 particles to improve CO2 separation. Journal of Membrane Science, 370, 141-148. DOI: 10.1016/j.memsci.2011.01.012.10.1016/j.memsci.2011.01.012Suche in Google Scholar

Husken, D., Visser, T., Wessling, M., & Gaymans, R. J. (2010). CO2 permeation properties of poly(ethylene oxide)-based segmented block copolymers. Journal of Membrane Science, 346, 194-201. DOI: 10.1016/j.memsci.2009.09.034.10.1016/j.memsci.2009.09.034Suche in Google Scholar

Kárászová, M., Friess, K., Šípek, M., Jansen, J. C., & Izák, P. (2011). Biogas upgrading for the 21st century. In R. Litonjua, & I. Cvetkovski (Eds.), Biogas: Production, consumption and applications (pp. 91-116). New York, NY, USA: Nova Science Publishers.Suche in Google Scholar

Kárászová, M., Vejražka, J., Veselý, V., Friess, K., Randová, A., Hejtmánek, V., Brabec, L., & Izák, P. (2012). A waterswollen thin film composite membrane for effective upgrading of raw biogas to methane. Separation and Purification Technology, 89, 212-216. DOI: 10.1016/j.seppur.2012.01.037.10.1016/j.seppur.2012.01.037Suche in Google Scholar

Kárászová, M., Simcik, M., Friess, K., Randová, A., Jansen, J. C., Ruzicka, M. C., Sedláková, Z., & Izak, P. (2013). Comparison of theoretical and experimental mass transfer coefficients of gases in supported ionic liquid membranes. Separation and Purification Technology, 118, 255-263. DOI: 10.1016/j.seppur.2013.06.045.10.1016/j.seppur.2013.06.045Suche in Google Scholar

Kárászová, M., Kačírková, M., Friess, K., & Izák, P. (2014). Progress in separation of gases by permeation and liquids by pervaporation using ionic liquids: A review. Separation and Purification Technology, 132, 93-101. DOI: 10.1016/j.seppur.2014.05.008.10.1016/j.seppur.2014.05.008Suche in Google Scholar

Kim, H. W., & Park, H. B. (2011). Gas diffusivity, solubility and permeability in polysulfone-poly(ethylene oxide) random copolymer membranes. Journal of Membrane Science, 372, 116-124. DOI: 10.1016/j.memsci.2011.01.053.10.1016/j.memsci.2011.01.053Suche in Google Scholar

Krull, F. F., Fritzmann, C., & Melin, T. (2008). Liquid membranes for gas/vapor separations. Journal of Membrane Science, 325, 509-519. DOI: 10.1016/j.memsci.2008.09.018.10.1016/j.memsci.2008.09.018Suche in Google Scholar

Kujawska, A., Kujawski, J., Bryjak, M., & Kujawski, W. (2015). ABE fermentation product recovery-A review. Renewable and Sustainable Energy Reviews, 48, 648-661. DOI: 10.1016/j.rser.2015.04.028.10.1016/j.rser.2015.04.028Suche in Google Scholar

Lems, R., Langerak, J., & Dirkse, E. H. M. (2014). Next generation biogas upgrading using highly selective gas separation membranes. Showcasing the Poundbury Project. Retrieved January 2014 from http://www.dirkse-milieutechniek.com/dmt/do/download//true/211689/Next_generation_biogas_upgrading.pdfSuche in Google Scholar

Li, Y., & Chung, T. S. (2010). Molecular-level mixed matrix membranes comprising Pebax® and POSS for hydrogen purification via preferential CO2 removal. International Journal of Hydrogen Energy, 35, 10560-10568. DOI: 10.1016/j.ijhydene.2010.07.124.10.1016/j.ijhydene.2010.07.124Suche in Google Scholar

Lin, H., & Freeman, B. D. (2004). Gas solubility, diffusivity and permeability in poly(ethylene oxide). Journal of Membrane Science, 239, 105-117. DOI: 10.1016/j.memsci.2003.08.031.10.1016/j.memsci.2003.08.031Suche in Google Scholar

Makaruk, A., Miltner, M., & Harasek, M. (2010). Membrane biogas upgrading processes for the production of natural gas substitute. Separation and Purification Technology, 74, 83-92. DOI: 10:1016/j.seppur.2010.05.010.10.1016/j.seppur.2010.05.010Suche in Google Scholar

Miltner, M., Makaruk, A., & Harasek, M. (2010). Investigation of the long-term performance of an industrial-scale biogas upgrading plant with grid supply applying gas permeation membranes. Chemical Engineering Transactions, 21, 1213-1218. DOI: 10.3303/cet1021203.Suche in Google Scholar

Molino, A., Nanna, F., Ding, Y. Bikson, B., & Braccio, G. (2013a). Biomethane production by anaerobic digestion of organic waste. Fuel, 103, 1003-1009. DOI: 10.1016/j.fuel.2012.07.070.10.1016/j.fuel.2012.07.070Suche in Google Scholar

Molino, A., Nanna, F., Migliori, M., Iovane, P., Ding, Y., & Bikson, B. (2013b). Experimental and simulation results for biomethane production using PEEK hollow fiber membrane. Fuel, 112, 489-493. DOI: 10.1016/j.fuel.2013.04.046.10.1016/j.fuel.2013.04.046Suche in Google Scholar

Orme, C. J., & Stewart, F. F. (2005). Mixed gas hydrogen sulfide permeability and separation using supported polyphosphazene membranes. Journal of Membrane Science, 253, 243-249. DOI: 10.1016/j.memsci.2004.12.034.10.1016/j.memsci.2004.12.034Suche in Google Scholar

Ozturk, B., & Demirciyeva, F. (2013). Comparison of biogas upgrading performances of different mixed matrix membranes. Chemical Engineering Journal, 222, 209-217. DOI: 10.1016/j.cej.2013.02.062.10.1016/j.cej.2013.02.062Suche in Google Scholar

PermSelect (2015). Methane purification, CO2 removal. Retrieved January 5, 2015, from http://www.permselect.com/ Platform Technology/NG CO2 RemovalSuche in Google Scholar

Poloncarzova, M., Vejrazka, J., Vesely, V., & Izak, P. (2011). Effective purification of biogas by condensing-liquid membrane. Angewandte Chemie International Edition, 50, 669-671. DOI: 10.1002/anie.201004821.10.1002/anie.201004821Suche in Google Scholar PubMed

Porter, J. (1970). US Patent No. 3534528. Washington, DC, USA: U.S. Patent and Trademark Office.Suche in Google Scholar

Quechulpa-Pérez, P., Pérez-Robles, J. F., Pérez-de Brito, A. F., & Aviliés-Arellano, L. M. (2014). Hybrid membranes prepared by the sol-gel process and based on silica-polyvinyl acetate for methane enrichment from biogas. Journal of Membrane Science & Technology, 4, 128. DOI: 10.4172/2155-9589.1000128.10.4172/2155-9589.1000128Suche in Google Scholar

Rasi, S., Veijanen, A., & Rintala, A. (2007). Trace compounds of biogas from different biogas production plants. Energy, 32, 1375-1380. DOI: 10.1016/j.energy.2006.10.018.10.1016/j.energy.2006.10.018Suche in Google Scholar

Ryckebosch, E., Drouillon, M., & Vervaeren, H. (2011). Techniques of transformation of biogas to biomethane. Biomass and Bioenergy, 35, 1633-1645. DOI: 10.1016/j.biombioe.2011. 02.033.Suche in Google Scholar

Scovazzo, P. (2009). Determination of the upper limits, benchmarks, and critical properties for gas separations using stabilized ionic liquid membranes (SILMs) for the purpose of guiding future research. Journal of Membrane Science, 343, 199-211. DOI: 10.1016/j.memsci.2009.07.028.10.1016/j.memsci.2009.07.028Suche in Google Scholar

Scholz, M, Melin, T., & Wessling, M. (2013a). Transforming biogas into biomethane using membrane technology. Renewable and Sustainable Energy Reviews, 17, 199-212. DOI: 10.1016/j.rser.2012.08.009.10.1016/j.rser.2012.08.009Suche in Google Scholar

Scholz, M., Frank, B., Stockmeier, F., Falss, S., & Wessling, M. (2013b). Techno-economic analysis of hybrid processes for biogas upgrading. Industrial & Engineering Chemistry Research, 52, 16929-16938. DOI: 10.1021/ie402660s.10.1021/ie402660sSuche in Google Scholar

Scholz, M., Alders, M., Lohaus, T., & Wessling, M. (2015). Structural optimization of membrane-based biogas upgrading processes. Journal of Membrane Science, 474, 1-10. DOI: 10.1016/j.memsci.2014.08.032.10.1016/j.memsci.2014.08.032Suche in Google Scholar

Schweigkofler, M., & Niessner, R. (2001). Removal of siloxanes in biogas. Journal of Hazardous Materials, 83, 183-196. DOI: 10.1016/s0304-3894(00)00318-6.10.1016/S0304-3894(00)00318-6Suche in Google Scholar

Suzuki, H., Tanaka, K., Kita, H., Okamoto, K., Hoshino, H., Yoshinaga, T., & Kusuki, Y. (1998). Preparation of composite hollow fiber membranes of poly(ethylene oxide)- containing polyimide and their CO2/N2 separation properties. Journal of Membrane Science, 146, 31-37. DOI: 10.1016/s0376-7388(98)00081-7.10.1016/S0376-7388(98)00081-7Suche in Google Scholar

Tan, X. Y., Tan, S. P., Teo, W. K., & Li, K. (2006). Polyvinylidene fluoride (PVDF) hollow fibre membranes for ammonia removal from water. Journal of Membrane Science, 271, 59-68. DOI: 10.1016/j.memsci.2005.06.057.10.1016/j.memsci.2005.06.057Suche in Google Scholar

Voss, B. A., Bara, J. E., Gin, D. L., & Noble, R. D. (2009). Physically gelled ionic liquids: Solid membrane materials with liquidlike CO2 gas transport. Chemistry of Materials, 21, 3027-3029. DOI: 10.1021/cm900726p.10.1021/cm900726pSuche in Google Scholar

Vu, D. Q., Koros, W. J., & Miller, S. J. (2002). High pressure CO2/CH4 separation using carbon molecular sieves hollow fiber membranes. Industrial & Engineering Chemistry Research, 41, 367-380. DOI: 10.1021/ie010119w.10.1021/ie010119wSuche in Google Scholar

Wellinger, A., & Lindberg, A. (1999). Biogas upgrading and utilization (IEA Bioenergy: Task 24: Energy from biological conversion of organic waste). Winterthur, Switzerland: Sailer Druck.Suche in Google Scholar

Wind, J. D., Paul, D. R., & Koros, W. J. (2004). Natural gas permeation in polyimide membranes. Journal of Membrane Science, 228, 227-236. DOI: DOI: 10.1016/j.memsci.2003.10.011.10.1016/j.memsci.2003.10.011Suche in Google Scholar

Xie, Z. L., Duond, T., Hoang, M., Nguyen, C., & Bolto, B. (2009). Ammonia removal by sweep gas membrane distillation. Water Research, 43, 1693-1699. DOI: 10.1016/j.watres.2008.12.052. 10.1016/j.watres.2008.12.052Suche in Google Scholar PubMed

Received: 2015-1-22
Revised: 2015-3-24
Accepted: 2015-4-14
Published Online: 2015-7-24
Published in Print: 2015-10-1

© Institute of Chemistry, Slovak Academy of Sciences

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