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The Pd-rich part of the Pd–B phase diagram

  • Tilmann Georg Berger , Andreas Leineweber EMAIL logo and Eric Jan Mittemeijer
Published/Copyright: January 7, 2022
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 97 Issue 1

Abstract

The Pd–B system in the composition range of the solid solution PdBy has been the subject of a number of investigations as it provides an attractive model system for interstitial compounds. No consensus about the crystal structures and phase boundaries, particularly in the low-temperature regime, has been reached in the earlier works. In the light of very recent results on the crystal structure and composition ranges of the low-temperature phases, on the basis of X-ray, electron, and neutron diffraction analyses, a tentative phase diagram is presented which is compatible with practically all previous results.

Keywords: Palladium – boron alloys; Phase diagram; Superstructure; Miscibility gap; Interstitial phases
Dr. Andreas Leineweber MPI for Metals Research Heisenbergstr. 3, D-70569 Stuttgart, Germany Tel.: +49 711 689 3365 Fax: +49 711 689 3312

References

[1] R.A. Alqasmi, H. Brodowsky, H.-J. Schaller: Z. Metallkd. 73 (1982) 331.Search in Google Scholar

[2] H. Brodowsky, H.-J. Schaller: Ber. Bunsenges. 7 (1976) 656.10.1002/bbpc.19760800715Search in Google Scholar

[3] K.D. Allard, T.B. Flanagan, E. Wicke: J. Phys. Chem. 74 (1970) 298.10.1021/j100697a012Search in Google Scholar

[4] B. Lengeler: Solid State Comm. 55 (1985) 679.10.1016/0038-1098(85)90232-7Search in Google Scholar

[5] T.G. Berger, A. Leineweber, E.J. Mittemeijer, P. Fischer, Phys. Stat. Sol. (a) 201 (2004) 1484.10.1002/pssa.200306808Search in Google Scholar

[6] M. Beck, M. Ellner, E.J. Mittemeijer: Acta Mater. 49 (2001) 985.10.1016/S1359-6454(00)00399-2Search in Google Scholar

[7] H. Brodowsky, J. Fleischhauer, M. Kayashima: Scr. Metallurg. 17 (1983) 541.10.1016/0036-9748(83)90349-6Search in Google Scholar

[8] G. Hägg: Z. Phys. Chem. B 12 (1931) 33.Search in Google Scholar

[9] G. Hägg: Z. Phys. Chem. B 12 (1931) 221.Search in Google Scholar

[10] H.W. King: J. Mater. Sci. 6 (1971) 1157.10.1007/BF00550085Search in Google Scholar

[11] R.A. Alqasmi, H. Brodowsky, H.-J. Schaller: Z. Metallkd. 77 (1986) 637.Search in Google Scholar

[12] C.D. Gelatt, jr., A.R. Williams, V.L. Moruzzi: Phys. Rev. B 27 (1983) 2005.10.1103/PhysRevB.27.2005Search in Google Scholar

[13] H. Brodowsky: Z. Phys. Chem. NF 44 (1965) 129.10.1524/zpch.1965.44.3_4.129Search in Google Scholar

[14] H. Brodowsky, H.-J. Schaller, H.-J. Wernicke: Z. Metallkd. 70 (1979) 631.Search in Google Scholar

[15] M. Beck, E.J. Mittemeijer: Z. Metallkd. 92 (2001) 1271.Search in Google Scholar

[16] M. Beck, M. Ellner, E.J. Mittemeijer: Z. Kristallogr. 216 (2001) 591.10.1524/zkri.216.11.591.22480Search in Google Scholar

[17] P. Rogl, in: G. Effenberg (Ed.), Phase diagrams of ternary metalboron-carbon systems, ASM International, Materials Park, OH (USA) (1998) 234.Search in Google Scholar

[18] P.K. Liao, K.E. Spear, M.E. Schlesinger: J. Phase Equilib. 17 (1996) 340.10.1007/BF02665561Search in Google Scholar

[19] T.G. Berger, A. Leineweber, E.J. Mittemeijer, M. Knapp: Z. Kristallogr. Suppl. 23 (2006) in print.10.1524/zksu.2006.suppl_23.443Search in Google Scholar

[20] T.G. Berger, A. Leineweber, E.J. Mittemeijer, C. Sarbu, V. Duppel, P. Fischer, accepted for publication.Search in Google Scholar

[21] A. Leineweber, T.G. Berger, E. J. Mittemeijer, in preparation.Search in Google Scholar

[22] P. Villars, M. Berndt, K. Brandenburg, K. Cenzual, J. Daams, F. Hulliger, T. Massalski, H. Okamoto, K. Osaki, A. Prince, H. Putz, S. Iwata, PAULING FILE, Binaries Edition, ASM International, Materials Park, OH (USA) 2002.Search in Google Scholar

[23] A.I. Gusev, A.A. Rempel: Phys. Stat. Sol. (a) 135 (1993) 15.10.1002/pssa.2211350102Search in Google Scholar

[24] G.S. Smith, Q. Johnson, R.E. Elson: Acta Crystallogr. 22 (1967) 300.10.1107/S0365110X67000507Search in Google Scholar
Received: 2005-02-14
Accepted: 2005-08-21
Published Online: 2022-01-07

© 2006 Carl Hanser Verlag, München

Articles in the same Issue

  1. Frontmatter
  2. Editorial
  3. The Pd-rich part of the Pd–B phase diagram
  4. Thermodynamic optimizing of the Li–Sn system
  5. Thermodynamic analysis of high-temperature heazlewoodite
  6. Diffusion of chromium in β-Ti under high pressure
  7. Density and surface tension of liquid ternary Ni–Cu–Fe alloys
  8. Influence of electric field strength applied during the solution heat treatment of the Al–Mg–Si–Cu Alloy AA6111
  9. Development of cube recrystallization textures in high-purity Al
  10. Formation of cube recrystallized grains in high-purity Al
  11. Effect of various niobium additions on microstructure and mechanical behavior of a NiAl–Cr–Mo eutectic alloy
  12. The effect of exposure to elevated temperatures on the microstructure and hardness of Mg–Ca–Zn alloy
  13. Kinetics studies of hydrogen reduction of Cu2O
  14. Decomposition kinetics of expanded austenite with high nitrogen contents
  15. Estimation of the viscosity for Ag–In and In–Sb liquid alloys using different models
  16. Elevated temperature tensile properties of an extruded aluminium alloy reinforced with SiCp
  17. Richtlinien für Autoren
  18. Instructions for authors
  19. Personal/ personelles
  20. Press/ Presse
  21. Conferences /Konferenzen
  22. Frontmatter
  23. Editorial
  24. Editorial
  25. Articles Basic
  26. The Pd-rich part of the Pd–B phase diagram
  27. Thermodynamic optimizing of the Li–Sn system
  28. Thermodynamic analysis of high-temperature heazlewoodite
  29. Diffusion of chromium in β-Ti under high pressure
  30. Density and surface tension of liquid ternary Ni–Cu–Fe alloys
  31. Influence of electric field strength applied during the solution heat treatment of the Al–Mg–Si–Cu Alloy AA6111
  32. Articles Applied
  33. Development of cube recrystallization textures in high-purity Al
  34. Formation of cube recrystallized grains in high-purity Al
  35. Effect of various niobium additions on microstructure and mechanical behavior of a NiAl–Cr–Mo eutectic alloy
  36. The effect of exposure to elevated temperatures on the microstructure and hardness of Mg–Ca–Zn alloy
  37. Kinetics studies of hydrogen reduction of Cu2O
  38. Decomposition kinetics of expanded austenite with high nitrogen contents
  39. Estimation of the viscosity for Ag–In and In–Sb liquid alloys using different models
  40. Elevated temperature tensile properties of an extruded aluminium alloy reinforced with SiCp
  41. Notifications/Mitteilungen
  42. Richtlinien für Autoren
  43. Instructions for authors
  44. Personal/ personelles
  45. Press/ Presse
  46. Conferences /Konferenzen
https://doi.org/10.3139/ijmr-2006-0001
Keywords for this article
Palladium – boron alloys; Phase diagram; Superstructure; Miscibility gap; Interstitial phases

Articles in the same Issue

  1. Frontmatter
  2. Editorial
  3. The Pd-rich part of the Pd–B phase diagram
  4. Thermodynamic optimizing of the Li–Sn system
  5. Thermodynamic analysis of high-temperature heazlewoodite
  6. Diffusion of chromium in β-Ti under high pressure
  7. Density and surface tension of liquid ternary Ni–Cu–Fe alloys
  8. Influence of electric field strength applied during the solution heat treatment of the Al–Mg–Si–Cu Alloy AA6111
  9. Development of cube recrystallization textures in high-purity Al
  10. Formation of cube recrystallized grains in high-purity Al
  11. Effect of various niobium additions on microstructure and mechanical behavior of a NiAl–Cr–Mo eutectic alloy
  12. The effect of exposure to elevated temperatures on the microstructure and hardness of Mg–Ca–Zn alloy
  13. Kinetics studies of hydrogen reduction of Cu2O
  14. Decomposition kinetics of expanded austenite with high nitrogen contents
  15. Estimation of the viscosity for Ag–In and In–Sb liquid alloys using different models
  16. Elevated temperature tensile properties of an extruded aluminium alloy reinforced with SiCp
  17. Richtlinien für Autoren
  18. Instructions for authors
  19. Personal/ personelles
  20. Press/ Presse
  21. Conferences /Konferenzen
  22. Frontmatter
  23. Editorial
  24. Editorial
  25. Articles Basic
  26. The Pd-rich part of the Pd–B phase diagram
  27. Thermodynamic optimizing of the Li–Sn system
  28. Thermodynamic analysis of high-temperature heazlewoodite
  29. Diffusion of chromium in β-Ti under high pressure
  30. Density and surface tension of liquid ternary Ni–Cu–Fe alloys
  31. Influence of electric field strength applied during the solution heat treatment of the Al–Mg–Si–Cu Alloy AA6111
  32. Articles Applied
  33. Development of cube recrystallization textures in high-purity Al
  34. Formation of cube recrystallized grains in high-purity Al
  35. Effect of various niobium additions on microstructure and mechanical behavior of a NiAl–Cr–Mo eutectic alloy
  36. The effect of exposure to elevated temperatures on the microstructure and hardness of Mg–Ca–Zn alloy
  37. Kinetics studies of hydrogen reduction of Cu2O
  38. Decomposition kinetics of expanded austenite with high nitrogen contents
  39. Estimation of the viscosity for Ag–In and In–Sb liquid alloys using different models
  40. Elevated temperature tensile properties of an extruded aluminium alloy reinforced with SiCp
  41. Notifications/Mitteilungen
  42. Richtlinien für Autoren
  43. Instructions for authors
  44. Personal/ personelles
  45. Press/ Presse
  46. Conferences /Konferenzen
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