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Effect of Al on the glass forming ability of Zr–Ni –Cu–Al alloys

  • Huan-Rong Wang EMAIL logo , Yi-Fu Ye , Guang-Hui Min , Jun-Yan Zhang , Xin-Ying Teng and Zhi-Qiang Shi
Published/Copyright: December 27, 2021
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 93 Issue 3

Abstract

Employing X-ray diffraction, scanning electron microscopy and differential scanning calorimetry techniques, the effect of the aluminium concentration on the glass forming ability (GFA) of Zr65Ni10Cu25–xAl x alloys were systematically studied. The experimental results show that with increasing Al concentration the supercooled liquid region of the as-quenched ribbons of Zr65Ni10Cu25–xAl x alloys increases and the critical cooling rate required to avoid crystallization during the rapid solidification for these alloys decreases, indicating that the GFA of Zr65Ni10Cu25–xAl x alloys is significantly improved by the addition of Al. The effect of Al on the GFA of Zr65Ni10Cu25–xAl x alloys is discussed from the micromechanism point of view.

Keywords: Glass forming ability; Zr–Cu–Ni–Al alloys; Supercooled liquid region; Glass transition
Huan-Rong Wang Key Laboratory of Liquid Structure and Heredity of Materials Shandong University Jinan, P. R. China Fax: +86 531 295 5999

  1. This work was supported by the National Natural Science Foundation of China (Project No. 59871025).

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Received: 2001-09-19
Published Online: 2021-12-27

© 2002 Carl Hanser Verlag, München

Articles in the same Issue

  1. Frontmatter
  2. Articles/Aufsätze
  3. Strain rate dependence of the deformation mechanisms in a fully lamellar γ-TiAl-based alloy
  4. Experimental and thermodynamic assessment of the Fe –Gd–Zr system
  5. Phase diagram of the Fe –Co –Ti system at 1073 K
  6. Copper concentration inside Guinier-Preston I zones formed in an Al –Cu alloy
  7. Identification of precipitates in 6013 aluminum alloy (Al –Mg –Si –Cu)
  8. Redistribution of phosphorus and carbon in steel weldments
  9. Microstructure and compressive properties of in situ synthesized TiC/Ti composites
  10. Effect of Al on the glass forming ability of Zr–Ni –Cu–Al alloys
  11. Fcc-hcp transformation-related internal friction in Fe –Mn alloys
  12. High-temperature stress and strain partitioning in duplex stainless steel
  13. Load sequence effects in the high cycle fatigue of two ferrite-pearlite microalloyed steels
  14. Characterization of intermetallic compounds formed during the interfacial reactions of liquid Sn and Sn– 58Bi solders with Ni substrates
  15. Notifications/Mitteilungen
  16. Personal/Personelles
https://doi.org/10.3139/ijmr-2002-0042
Keywords for this article
Glass forming ability; Zr–Cu–Ni–Al alloys; Supercooled liquid region; Glass transition

Articles in the same Issue

  1. Frontmatter
  2. Articles/Aufsätze
  3. Strain rate dependence of the deformation mechanisms in a fully lamellar γ-TiAl-based alloy
  4. Experimental and thermodynamic assessment of the Fe –Gd–Zr system
  5. Phase diagram of the Fe –Co –Ti system at 1073 K
  6. Copper concentration inside Guinier-Preston I zones formed in an Al –Cu alloy
  7. Identification of precipitates in 6013 aluminum alloy (Al –Mg –Si –Cu)
  8. Redistribution of phosphorus and carbon in steel weldments
  9. Microstructure and compressive properties of in situ synthesized TiC/Ti composites
  10. Effect of Al on the glass forming ability of Zr–Ni –Cu–Al alloys
  11. Fcc-hcp transformation-related internal friction in Fe –Mn alloys
  12. High-temperature stress and strain partitioning in duplex stainless steel
  13. Load sequence effects in the high cycle fatigue of two ferrite-pearlite microalloyed steels
  14. Characterization of intermetallic compounds formed during the interfacial reactions of liquid Sn and Sn– 58Bi solders with Ni substrates
  15. Notifications/Mitteilungen
  16. Personal/Personelles
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