State of the Art: Recycling of EPDM Rubber Vulcanizates
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P. Sutanto
Abstract
Since the past few decades, environmental issues have become a serious concern in society. It is a requisite for the industry to minimize waste, in order to protect the environment from being polluted. The term waste here comprises processing waste and post-consumer waste. The amount of processing waste should not be underestimated since it might consist of approximately 10% of the total production. The recycling of EPDM rubber is an interesting topic, especially if considered in connection with the continuous market growth of EPDM. This paper is a summary of efforts that have been taken so far on this subject. Studies done on EPDM recycling include reusing EPDM as filler in new rubber products and chemical, thermal, and mechanical devulcanization of EPDM in order to achieve a material that resembles the virgin one and could be revulcanized. Such studies on EPDM recycling are discussed extensively and in the conceptual frame of more general rubber recycling processes.
References
1Isayev, A. I., in: Encyclopedia of Materials: Science and Technology. Elsevier Science, Oxford (2003)Suche in Google Scholar
2Morton, M.: Rubber Technology. van Nostrand Reinhold (1987)10.1007/978-1-4615-7823-9Suche in Google Scholar
3Noordermeer, J. W. M., in: Kirk-Othmer Concise Encyclopedia of Chemical Technology. Kirk, R. E., Othmer, D. F., Grayson, M. (Eds.), Wiley Interscience, New York (1993)Suche in Google Scholar
4Burridge, E.: European Chemical News 10–16, p.15 (2003)Suche in Google Scholar
5Burridge, E.: European Chemical News82, p. 16 (2005)Suche in Google Scholar
6Manuel, H. J., Dierkes, W.: Rapra Review Reports99 (1999)Suche in Google Scholar
7Paul, J. P.: Chemtech9, p. 104 (1979)Suche in Google Scholar
8Dierkes, W. K.: Recent Research Developments in Macromolecules7, p. 265 (2003)Suche in Google Scholar
9Dierkes, W. K., in: Rubber Recycling. De, S. K. (Ed.) CRC Press LLC (2004)Suche in Google Scholar
10Jang, J. W., Yoo, T. S., Oh, J. H., Iwasaki, I.: Resources Conservation and Recycling22, p. 1 (1998)10.1016/S0921-3449(97)00041-4Suche in Google Scholar
11Warner, W. C.: Rubber Chemistry and Technology67, p. 559 (1994)10.5254/1.3538692Suche in Google Scholar
12Verbruggen, M. A. L., van der Does, L., Noordermeer, J. W. M., van Duin, M., Manuel, H. J.: Rubber Chemistry and Technology72, p. 731 (1999)10.5254/1.3538830Suche in Google Scholar
13 EP 0690091 A1 (1995), Sekhar, B. C.Suche in Google Scholar
14Otsuka, S., Owaki, M., Suzuki, Y., Honda, H., Nakashima, K., Mouri, M., Sato, N.: SAE Technical Paper Series 2000-01-0015 (2000)Suche in Google Scholar
15Fukumori, K., Matsushita, M., Okamoto, H., Sato, N., Suzuki, Y., Takeuchi, K., in: JSAE Review23, p. 259 (2002)10.1016/S0389-4304(02)00173-XSuche in Google Scholar
16Yun, J., Isayev, A. I.: Paper presented at the Rubber Division Meeting of American Chemical Society, 16–19 October (2001)Suche in Google Scholar
17Tukachinsky, A., Schworm, D., Isayev, A. I.: Rubber Chemistry and Technology69, p. 92 (1996)10.5254/1.3538362Suche in Google Scholar
18Suryanarayanan, B.: Chemical Engineering World29, p. 57 (1994)Suche in Google Scholar
19US Patent 4104205 (1978) Novotny, D., Marsh, R.Suche in Google Scholar
20Levin, V. Y., Kim, S. H., Isayev, A. I., Massey, J., von Meerwall, E.: Rubber Chemistry and Technology69, p. 104 (1996)10.5254/1.3538350Suche in Google Scholar
21Fix, S. R.: Elastomerics112, p. 38 (1980)Suche in Google Scholar
22Isayev, A. I., Chen, J., Tukachinsky, A.: Rubber Chemistry and Technology68, p. 267 (1995)10.5254/1.3538741Suche in Google Scholar
23US Patent 5284625 (1998) Isayev, A. I., Chen, J.Suche in Google Scholar
24US Patent 5258413 (1993) Isayev, A. I.Suche in Google Scholar
25Yashin, V. V., Isayev, A. I.: Rubber Chemistry and Technology72, p. 741 (1999)10.5254/1.3538831Suche in Google Scholar
26Adhikari, B., De, D., Maiti, S.: Progress in Polymer Science25, p. 909 (2000)10.1016/S0079-6700(00)00020-4Suche in Google Scholar
27Heideman, G.: Amines as Devulcanization Chemicals for EPDM Rubber. Thesis/Dissertation. Faculty of Chemical Technology, University of Twente, The Netherlands (1999)Suche in Google Scholar
28Mouri, M., Okamoto, H., Matsushita, M., Honda, H., Nakashima, K., Takeushi, K., Suzuki, Y., Owaki, M.: International Polymer Science and Technology27 p.T/23 (2000)Suche in Google Scholar
29Mouri, M., Sato, N., Okamoto, H., Matsushita, M., Honda, H., Nakashima, K., Takeushi, K., Suzuki, Y., Owaki, M.: International Polymer Science and Technology27 p.T/17 (2000)Suche in Google Scholar
30Mouri, M., Sato, N., Okamoto, H., Matsushita, M., Honda, H., Nakashima, K., Suzuki, Y., Owaki, M.: International Polymer Science and Technology27 p.T/12–T/16 (2000)Suche in Google Scholar
31Sato, N.: Paper presented at the International Rubber Conference (IRC) proceeding. Seoul, Korea (1999)Suche in Google Scholar
32SuzukiY., Owaki, M., Mouri, M., Sato, N., Honda, H., Nakashima, K.: Toyota Technical Review481, p. 53 (1998)Suche in Google Scholar
33 European Patent 0931809 A2 (7-28-1999) Matsushita, M., Mouri, M., Okamoto, H., Sato, N., Suzuki, Y., Owaki, M., Suzuki, N., Nakashima, K., Honda, H., Yoshida, T., Takeuchi, K.Suche in Google Scholar
34Yun, J., Yashin, V. V., Isayev, A. I.: Paper presented at the Rubber Division Meeting, ACS, Pitsburgh (October 8–11, 2002) (2002)Suche in Google Scholar
35Jacob, C., De, P. P., Bhowmick, A. K., De, S. K.: Journal of Applied Polymer Science82, p. 3293–3303 (2001)10.1002/app.2188Suche in Google Scholar
36Jacob, C., De, P. P., Bhowmick, A. K., De, S. K.: Journal of Applied Polymer Science87, p. 2204 (2003)10.1002/app.11474Suche in Google Scholar
37Jacob, C., De, P. P., Bhowmick, A. K., De, S. K.: Journal of Applied Polymer Science82, p. 3304 (2001)10.1002/app.2189Suche in Google Scholar
38International Institute of Synthetic Rubber Producers. http://www.azom.com/details.asp?ArticleID=1822Suche in Google Scholar
39Olmsted III, J., Williams, G. M.: Chemistry: the molecular science, Wm. C. Brown (1997)Suche in Google Scholar
© 2006, Hanser Publishers, Munich
Artikel in diesem Heft
- Contents
- Contents
- Regular Contributed Articles
- Pressure and Temperature Dependence of LDPE Viscosity and Free Volume: The Effect of Molecular Structure
- Correlations between Injection Molding Parameters, Morphology and Mechanical Properties of PPS Using Artificial Neural Networks
- Investigations into Kinematic Reversal in Non-isothermal Flows in Single-screw Machines
- The Effect of Post-extrusion Conditions in Ribbon Extrusion of Polymer Blends
- Effect of the Chemical and Morphological Conditions of the Die Wall on the Extrusion of Linear Polyolefins
- Investigation of the Heat Affected Zone of Hot-gas Welded PP Joints
- Method for the Optimisation of Screw Elements for Tightly Intermeshing, Co-rotating Twin Screw Extruders
- Rheology and Processing of Molten Poly(methyl methacrylate) Resins
- PLLA Morphology Controlled by Dry-cast Process
- Two Component Injection Molding of Phase Separating Blends
- A Low Force Valve for Dynamic Control of Molten Plastics in a Mold
- Influence of Drawing and Temperature on the Optical and Structural Properties of Monofilament PP Sutures
- Mechanical Properties of Rubber-toughened Post-industrial Glass-fiber-reinforced PA66
- Thermal Flow Instability in Metal Injection Molding: Experiment and Simulation
- Review Paper
- State of the Art: Recycling of EPDM Rubber Vulcanizates
- PPS News
- PPS News
- Seikei-Kakou Abstracts
- Seikei-Kakou Abstracts
Artikel in diesem Heft
- Contents
- Contents
- Regular Contributed Articles
- Pressure and Temperature Dependence of LDPE Viscosity and Free Volume: The Effect of Molecular Structure
- Correlations between Injection Molding Parameters, Morphology and Mechanical Properties of PPS Using Artificial Neural Networks
- Investigations into Kinematic Reversal in Non-isothermal Flows in Single-screw Machines
- The Effect of Post-extrusion Conditions in Ribbon Extrusion of Polymer Blends
- Effect of the Chemical and Morphological Conditions of the Die Wall on the Extrusion of Linear Polyolefins
- Investigation of the Heat Affected Zone of Hot-gas Welded PP Joints
- Method for the Optimisation of Screw Elements for Tightly Intermeshing, Co-rotating Twin Screw Extruders
- Rheology and Processing of Molten Poly(methyl methacrylate) Resins
- PLLA Morphology Controlled by Dry-cast Process
- Two Component Injection Molding of Phase Separating Blends
- A Low Force Valve for Dynamic Control of Molten Plastics in a Mold
- Influence of Drawing and Temperature on the Optical and Structural Properties of Monofilament PP Sutures
- Mechanical Properties of Rubber-toughened Post-industrial Glass-fiber-reinforced PA66
- Thermal Flow Instability in Metal Injection Molding: Experiment and Simulation
- Review Paper
- State of the Art: Recycling of EPDM Rubber Vulcanizates
- PPS News
- PPS News
- Seikei-Kakou Abstracts
- Seikei-Kakou Abstracts