PLLA Morphology Controlled by Dry-cast Process
-
B. Meng
Abstract
The influence of solvent evaporation rate, in the dry-casting process, on crystallinity and morphology of crystallizable polymeric membrane was studied. Poly-l-lactic acid (PLLA) was taken as an example. The membranes were characterized by scanning electron microscopy (SEM) and differential scanning calorimetry (DSC). By controlling the solvent evaporation rate, samples with various crystallinities were prepared. From higher to lower crystallinity the membranes exhibit three types of surface morphology in sequence: granule, stripe and smooth.
References
1Kesting, R. E.: Synthetic Polymeric Membrane. Wiley, New York (1985)Suche in Google Scholar
2Li, D. P., Wang, X. H., Meng, B., Cui, F. Z.: Mater. Sci. Forum. 423, p. 347 (2003)10.4028/www.scientific.net/MSF.423-425.347Suche in Google Scholar
3Huda, M. S., Yasui, M., Mohri, N., Fujimura, T., Kimura, Y.: Mater. Sci. Eng. 333, p. 98 (2002)10.1016/S0921-5093(01)01834-2Suche in Google Scholar
4Sasaki, T., Yamamoto, Y., Takahashi, T.: Polym. J. 32, p. 263 (2000)10.1295/polymj.32.263Suche in Google Scholar
5Castellari, C., Ottani, S.: J. Membr. Sci. 9, p. 29 (1981)10.1016/S0376-7388(00)85115-7Suche in Google Scholar
6Zeman, L., Fraser, T.: J. Membr. Sci. 87, p. 267 (1994)10.1016/0376-7388(94)87033-0Suche in Google Scholar
7Huang, R. Y. M., Feng, X.: J. Appl. Polym. Sci. 57, p. 613 (1995)10.1002/app.1995.070570511Suche in Google Scholar
8Young, T. H., Huang, J. H., Chuang, W. Y.: Eur. Polym. J. 38: 63 (2002)10.1016/S0014-3057(01)00183-5Suche in Google Scholar
9Field, R. J., Burger, M. (Eds.): Oscillations and Traveling Waves in Chemical Systems. Wiley Interscience, New York (1985)Suche in Google Scholar
10Nicolis, G., Prigogine, I.: Self-Organization in Non-Equilibrium Systems. New York, Wiley Interscience (1977)Suche in Google Scholar
11Christopher, H., Douglas, H. A., Cheng, Z. D., Sebastian, J. M., Srinivasan, S., David, A. H., Richard, A. R., Chaikin, P. M.: Science290, p. 1558 (2000)10.1126/science.290.5496.1558Suche in Google Scholar PubMed
12Krausch, G., Kramer, E. J., Rafailovich, M. H., Sokolov, J.: Appl. Phys. Lett. 64, p. 2655 (1994)10.1063/1.111482Suche in Google Scholar
13Kimishima, I., Jinnai, H., Hashimoto, T.: Macromolecules32, p. 2585 (1994)10.1021/ma981892eSuche in Google Scholar
14Oshida, K., Nakazawa, T., Miyazaki, T., Endo, M.: Synthetic. Met. 125, p. 223 (2001)10.1016/S0379-6779(01)00535-5Suche in Google Scholar
15Ouyang, Q., Swinney, H. L.: Transition to Chemical Turbulence, Chaos1, p. 411 (1991)10.1063/1.165851Suche in Google Scholar PubMed
16Strawhecker, K. E., Kumar, S. K.: Macromolecules34, p. 4669 (2000)10.1021/ma001440dSuche in Google Scholar
17De Gennesa, P. G.: Eur. Phys. J. E7, p. 31 (2002)10.1007/s10189-002-8214-1Suche in Google Scholar
© 2006, Hanser Publishers, Munich
Artikel in diesem Heft
- Contents
- Contents
- Regular Contributed Articles
- Pressure and Temperature Dependence of LDPE Viscosity and Free Volume: The Effect of Molecular Structure
- Correlations between Injection Molding Parameters, Morphology and Mechanical Properties of PPS Using Artificial Neural Networks
- Investigations into Kinematic Reversal in Non-isothermal Flows in Single-screw Machines
- The Effect of Post-extrusion Conditions in Ribbon Extrusion of Polymer Blends
- Effect of the Chemical and Morphological Conditions of the Die Wall on the Extrusion of Linear Polyolefins
- Investigation of the Heat Affected Zone of Hot-gas Welded PP Joints
- Method for the Optimisation of Screw Elements for Tightly Intermeshing, Co-rotating Twin Screw Extruders
- Rheology and Processing of Molten Poly(methyl methacrylate) Resins
- PLLA Morphology Controlled by Dry-cast Process
- Two Component Injection Molding of Phase Separating Blends
- A Low Force Valve for Dynamic Control of Molten Plastics in a Mold
- Influence of Drawing and Temperature on the Optical and Structural Properties of Monofilament PP Sutures
- Mechanical Properties of Rubber-toughened Post-industrial Glass-fiber-reinforced PA66
- Thermal Flow Instability in Metal Injection Molding: Experiment and Simulation
- Review Paper
- State of the Art: Recycling of EPDM Rubber Vulcanizates
- PPS News
- PPS News
- Seikei-Kakou Abstracts
- Seikei-Kakou Abstracts
Artikel in diesem Heft
- Contents
- Contents
- Regular Contributed Articles
- Pressure and Temperature Dependence of LDPE Viscosity and Free Volume: The Effect of Molecular Structure
- Correlations between Injection Molding Parameters, Morphology and Mechanical Properties of PPS Using Artificial Neural Networks
- Investigations into Kinematic Reversal in Non-isothermal Flows in Single-screw Machines
- The Effect of Post-extrusion Conditions in Ribbon Extrusion of Polymer Blends
- Effect of the Chemical and Morphological Conditions of the Die Wall on the Extrusion of Linear Polyolefins
- Investigation of the Heat Affected Zone of Hot-gas Welded PP Joints
- Method for the Optimisation of Screw Elements for Tightly Intermeshing, Co-rotating Twin Screw Extruders
- Rheology and Processing of Molten Poly(methyl methacrylate) Resins
- PLLA Morphology Controlled by Dry-cast Process
- Two Component Injection Molding of Phase Separating Blends
- A Low Force Valve for Dynamic Control of Molten Plastics in a Mold
- Influence of Drawing and Temperature on the Optical and Structural Properties of Monofilament PP Sutures
- Mechanical Properties of Rubber-toughened Post-industrial Glass-fiber-reinforced PA66
- Thermal Flow Instability in Metal Injection Molding: Experiment and Simulation
- Review Paper
- State of the Art: Recycling of EPDM Rubber Vulcanizates
- PPS News
- PPS News
- Seikei-Kakou Abstracts
- Seikei-Kakou Abstracts