Non-linear Viscoelastic Behavior of PVC Plastisol
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N. Nakajima
Abstract
Rheology of PVC plastisol is usually conducted with steady state flow. It is inadequate, because plastisol is viscoelastic, so that deformational experiment is also required. In the viscoelastic measurements, when either frequency or amplitude is increased, dynamic viscosity decreases first (pseudo-plastic), reaching a minimum and then, increases (dilatant). It is because the shear rate during the oscillation is a product of frequency and amplitude. The pseudo-plastic behavior is explained with stress-induced phase separation into an immobilized layer of packed particles and mobile phase of reduced particle concentration. The viscosity minimum corresponds to the yield point of the immobilized layer. The yielding obeys Coulomb's criterion. After yielding the immobilized layer dilates with the further increase of shear rate. Two different modes of fracture are observed; one without yielding occurs at rather low shear stress, slightly higher than the cohesive strength of the immobilized layer. After yielding and dilation, the fracture occurs when shear stress becomes higher than normal stress. Before yielding the deformation of the immobilized layer is very small and accompanied with small fraction of particles moving over the neighboring particles. After yielding, deformation involves entire particles of the immobilized layer.
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© 2005, Carl Hanser Verlag, Munich
Artikel in diesem Heft
- Contents
- Contents
- Editorial
- New at International Polymer Processing
- Regular Contributed Articles
- Preparing of Homogeneous Solution of Ultrahigh Molecular Weight PAN
- Non-linear Viscoelastic Behavior of PVC Plastisol
- Algorithms for Two Gate Optimization in Injection Molding
- Viscoelastic Properties of Flexible Organic Fiber Composites
- Mold for Manipulation Microstructure Development
- Simultaneous Biaxial Stretching of PP Resins of Varying Tacticity
- Rotational Moulding of PVC Plastisol
- Drawability of As-spun PP Fibres
- Melt Fracture of Linear PE
- Investigation of the Cooling Jets Used in the Blown Film Process
- Non-linear Crystalline Spherulitic Growth Behavior for LLDPE
- Design Sensitivity Analysis for the Optimization of the Injection Molding Process
- Preparation and Characteristics of Reactive Blends of Phosphate-containing Maleimide and Epoxy
- Easy Tear Multilayer Film of Biaxially Oriented PA6/MXD6 by Double Bubble Tubular Film Process
- PPS News
- PPS News
- Seikei-Kakou Abstracts
- Seikei-Kakou Abstracts
Artikel in diesem Heft
- Contents
- Contents
- Editorial
- New at International Polymer Processing
- Regular Contributed Articles
- Preparing of Homogeneous Solution of Ultrahigh Molecular Weight PAN
- Non-linear Viscoelastic Behavior of PVC Plastisol
- Algorithms for Two Gate Optimization in Injection Molding
- Viscoelastic Properties of Flexible Organic Fiber Composites
- Mold for Manipulation Microstructure Development
- Simultaneous Biaxial Stretching of PP Resins of Varying Tacticity
- Rotational Moulding of PVC Plastisol
- Drawability of As-spun PP Fibres
- Melt Fracture of Linear PE
- Investigation of the Cooling Jets Used in the Blown Film Process
- Non-linear Crystalline Spherulitic Growth Behavior for LLDPE
- Design Sensitivity Analysis for the Optimization of the Injection Molding Process
- Preparation and Characteristics of Reactive Blends of Phosphate-containing Maleimide and Epoxy
- Easy Tear Multilayer Film of Biaxially Oriented PA6/MXD6 by Double Bubble Tubular Film Process
- PPS News
- PPS News
- Seikei-Kakou Abstracts
- Seikei-Kakou Abstracts
