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Preparation and Characteristics of Reactive Blends of Phosphate-containing Maleimide and Epoxy

  • W. J. Shu , K. C. Hoang und H. J. Chiu
Veröffentlicht/Copyright: 30. April 2013
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International Polymer Processing
Aus der Zeitschrift International Polymer Processing Band 20 Heft 1

Abstract

Three kinds of phosphate-containing maleimide(PMI) monomers, namely diethyl (4-(N-maleimido) phenyl) phosphate (4P) diphenyl (4-(N-maleimido) phenyl) phosphate (PP) and diethyl (2,6-dibromo-4-(N-maleimido)phenyl) phosphate (BrP), were synthesized and blended with a phenol-novolac type of epoxy so as to study their potential as reactive flame retardants. Thermal reaction of these blending systems had been discussed. Mechanical and thermal properties of blends had also been analysed. It was expected that with an increase in the PMI content in the blending system, the Michael-addition reaction would take place more and easily. Increasing the PMI contents reduced the storage modulus, the Tg and the tensile strength, however good thermal stability was maintained. The flame retardancy of all the phosphate-containing epoxy systems was promoted significantly by increasing the PMI content. Besides, the PMI with halogen atom may combine the flame retarding mechanism of gas-phase and solid-phase to promote their flame retardancy.

∗ Mail address: W. J. Shu, Department of Chemical Engineering, Ta-Hwa Inst. of Technology, Chiung-Lin, Hsinchu 30703, Taiwan, ROC E-mail:

References

1 Japan Patent JP06322119 (1994) Takeda, T., Enoki, H., Onami, K., Mayake, S..Suche in Google Scholar

2 Japan Patent 06025 504 (1994) Muramoto, H., Kimura, K..Suche in Google Scholar

3 Japan Patent 05 306 359 (1993) Nichiza, M., Tomoi, M., Iijima, T..Suche in Google Scholar

4 Matsumoto, A., Hasegawa, K., Fukuda, A.: Polym. Int.31, p. 275 (1993).10.1002/pi.4990310310Suche in Google Scholar

5 Japan Patent 2 001 019 744 (2001) Kuo, Y. H., Chuo, C. S., Chang, J. K., Wu, F. M., Kuo, W. J., Chou, W. H., Yang, F. T..Suche in Google Scholar

6 U. S. Patent 5 081 167 (1992) Jackson, R. J..Suche in Google Scholar

7 Gouri, C., Nair, C. P. R., Ramaswamy, R.: J. Appl. Polym. Sci.73, p. 695 (1999).10.1002/(SICI)1097-4628(19990801)73:5<695::AID-APP10>3.0.CO;2-XSuche in Google Scholar

8 Ohtsuka, K., Hasegawa, K., Matsumoto, A., Kimura, H., Fukuda, A., Yoshioka, F., Hayashi, H.: Nippon Setchaku Gakkaishi33, p. 128 (1997).Suche in Google Scholar

9 Bernard, B., Abderrahim, E. B.: Eur. Polym. J.32, p. 1463 (1996).10.1016/S0014-3057(96)00100-0Suche in Google Scholar

10 Liang, G., Gu, A.: Polym. Compos.18, p. 237 (1997).10.1002/pc.10278Suche in Google Scholar

11 U. S. Patent 5 310 830 (1994) Okitsu, T., Sato, S..Suche in Google Scholar

12 Japan Patent JP11124488 (1999), Ikeguchi, N., Kato, T., Aoto, H..Suche in Google Scholar

13 Japan Patent 03 331 350 (1993) Watanabe, A., Maeda, K..Suche in Google Scholar

14 Japan Patent 03 269 047 (1991) Muramoto, H., Kimura, K., Matsumoto, H..Suche in Google Scholar

15 Japan Patent 10 168 261 (1998) Ota, T., Yamaguchi, N..10.3156/jfuzzy.10.2_81_2Suche in Google Scholar

16 Iijima, T., Tomoi, M.: Network Polymer18, p. 85 (1997).Suche in Google Scholar

17 Japan Patent 11 060 909 (1999) Ito, M., Miyake, S., Kobeta, K., Tobisawa, A..Suche in Google Scholar

18 Japan Patent 10 007 770 (1998) Shibahara, S., Ota, M..10.1088/1126-6708/1998/10/007Suche in Google Scholar

19 Gu, A., Liang, G., Lan, L.: J. Appl. Polym. Sci.62(5), p. 799 (1996).10.1002/(SICI)1097-4628(19961031)62:5<799::AID-APP12>3.0.CO;2-OSuche in Google Scholar

20 Shah, V. J., Partch, R.: Int. J. Polym. Mater.39, p. 151(1998).10.1080/00914039808041040Suche in Google Scholar

21 Wang, C. S., Lin, C. H.: Polymer40, p. 5665 (1999).10.1016/S0032-3861(98)00786-1Suche in Google Scholar

22 Lin, C. H., Wang, C. S.: J. Polym. Sci. Part A: Polym. Chem.38, p. 2260 (2000).10.1002/(SICI)1099-0518(20000615)38:12<2260::AID-POLA150>3.0.CO;2-RSuche in Google Scholar

23 Japan Patent 2 000 248 169 (2000) Yorisue, T., Katayori, T..Suche in Google Scholar

24 Vanaja, A., Rao, R. M. V. G. K.: Eur. Polym. J.38, p. 187 (2002).10.1016/S0014-3057(01)00094-5Suche in Google Scholar

25 Jeng, R. J., Lo, G. S., Chen, C. P., Liu, Y. L., Hsiue, G. H., Su, W. C.: Polym. Adv. Technol.14, p. 147 (2003).10.1002/pat.343Suche in Google Scholar

26 Shu, W. J., Perng, L. H., Chin, W. K.: Polym. J.33, p. 676 (2001).10.1295/polymj.33.676Suche in Google Scholar

27 Shu, W. J., Perng, L. H., Chin, W. K., Hsu, C. Y.: J. Macromol. Sci., Pure Appl. Chem. A40, 9, p. 897 (2003).10.1081/MA-120023526Suche in Google Scholar

28 Bergmann, E. D., Ginsburg, D., Pappo, R.: Org. React.10, p. 179 (1959).Suche in Google Scholar

29 Satoshi, O., Shinichi, Y.: J. Org. Chem.65, p. 1544 (2000).10.1021/jo9905773Suche in Google Scholar

30 Crivello, J. V.: J. Polym. Sci. Chem. Ed.111, p. 1185 (1973).10.1002/pol.1973.170110607Suche in Google Scholar

31 Varma, I. K., Guptam, A. K.: J. Polym. Lett. Ed.20, p. 621 (1982).10.1002/pol.1982.130201203Suche in Google Scholar

32 Tung, C. M., Lung, C. L., Liar, T. T.: Polym. Mat. Sci. Eng.52, p. 139 (1985).Suche in Google Scholar

33 Golding, B. T., Bleasdale, C., McGinnis, J., Muller, S., Rees, H. T., Rees, N. H., Farmer, P. B., Watson, W. P.: Tetrahedron53, p. 4063 (1997).10.1016/S0040-4020(97)00018-5Suche in Google Scholar

34 Skibo, E. B.Xing, C. G.: Biochem.37, p. 15199 (1998).10.1021/bi981204jSuche in Google Scholar PubMed

35 Park, J. O.Jang, S. H.: J. Polym. Sci., Polym. Chem.30, p. 723 (1992).10.1002/pola.1992.080300504Suche in Google Scholar

36 Lee, H.Neville, K.: Handbook of Epoxy Resin. McGraw-Hill, New York (1972).Suche in Google Scholar

37 LiuY. L., Hsiue, G. H., Chiu, Y. S., Jeng, R. J., Ma, C. C.: J. Appl. Polym. Sci.59, p. 1619 (1996).10.1002/(SICI)1097-4628(19960307)59:10<1619::AID-APP14>3.0.CO;2-RSuche in Google Scholar

38 Van Krevelen, D. W.: Polymer16, p. 615 (1975).10.1016/0032-3861(75)90157-3Suche in Google Scholar

Received: 2004-11-3
Accepted: 2005-1-4
Published Online: 2013-04-30
Published in Print: 2005-03-01

© 2005, Carl Hanser Verlag, Munich

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Editorial
  4. New at International Polymer Processing
  5. Regular Contributed Articles
  6. Preparing of Homogeneous Solution of Ultrahigh Molecular Weight PAN
  7. Non-linear Viscoelastic Behavior of PVC Plastisol
  8. Algorithms for Two Gate Optimization in Injection Molding
  9. Viscoelastic Properties of Flexible Organic Fiber Composites
  10. Mold for Manipulation Microstructure Development
  11. Simultaneous Biaxial Stretching of PP Resins of Varying Tacticity
  12. Rotational Moulding of PVC Plastisol
  13. Drawability of As-spun PP Fibres
  14. Melt Fracture of Linear PE
  15. Investigation of the Cooling Jets Used in the Blown Film Process
  16. Non-linear Crystalline Spherulitic Growth Behavior for LLDPE
  17. Design Sensitivity Analysis for the Optimization of the Injection Molding Process
  18. Preparation and Characteristics of Reactive Blends of Phosphate-containing Maleimide and Epoxy
  19. Easy Tear Multilayer Film of Biaxially Oriented PA6/MXD6 by Double Bubble Tubular Film Process
  20. PPS News
  21. PPS News
  22. Seikei-Kakou Abstracts
  23. Seikei-Kakou Abstracts
https://doi.org/10.3139/217.1865

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Editorial
  4. New at International Polymer Processing
  5. Regular Contributed Articles
  6. Preparing of Homogeneous Solution of Ultrahigh Molecular Weight PAN
  7. Non-linear Viscoelastic Behavior of PVC Plastisol
  8. Algorithms for Two Gate Optimization in Injection Molding
  9. Viscoelastic Properties of Flexible Organic Fiber Composites
  10. Mold for Manipulation Microstructure Development
  11. Simultaneous Biaxial Stretching of PP Resins of Varying Tacticity
  12. Rotational Moulding of PVC Plastisol
  13. Drawability of As-spun PP Fibres
  14. Melt Fracture of Linear PE
  15. Investigation of the Cooling Jets Used in the Blown Film Process
  16. Non-linear Crystalline Spherulitic Growth Behavior for LLDPE
  17. Design Sensitivity Analysis for the Optimization of the Injection Molding Process
  18. Preparation and Characteristics of Reactive Blends of Phosphate-containing Maleimide and Epoxy
  19. Easy Tear Multilayer Film of Biaxially Oriented PA6/MXD6 by Double Bubble Tubular Film Process
  20. PPS News
  21. PPS News
  22. Seikei-Kakou Abstracts
  23. Seikei-Kakou Abstracts
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