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Preparing of Homogeneous Solution of Ultrahigh Molecular Weight PAN

  • B. Zhang , J. Zhao , Y. Zhang , N. Yang and C. Wu
Published/Copyright: April 30, 2013
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Abstract

Based on torque measurement via a device specially developed by our group, the shearing torque of the mixture of UHMWPAN with swelling agent or solvent during shearing process at various temperatures could be recorded as torque-temperature diagram in the swelling and dissolution process. The temperature where the torque of the mixture began to rise as showed in the torque-temperature diagram was considered as key parameter. UHMWPAN could be swollen fully and the homogeneous solution could be easily prepared if the mixture was heated progressively and was kept for a certain period of time at the every constant temperature. In the case of UHMWPAN (content ≥ 5 %), the parameters of the swelling and dissolution process were finally obtained.


Mail address: C. Wu, The Modification of Chemical Fibers and Materials Key State Laboratory, DongHua University, 1882 Yanan West Road, Shanghai 200051, China Email:

References

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Received: 2003-5-15
Accepted: 2004-10-25
Published Online: 2013-04-30
Published in Print: 2005-03-01

© 2005, Carl Hanser Verlag, Munich

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