Startseite Studies on NBR-ZDMA-OMMT Nanocomposites Prepared by Reactive Mixing Intercalation Method
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Studies on NBR-ZDMA-OMMT Nanocomposites Prepared by Reactive Mixing Intercalation Method

  • L. Liu , Y. Luo , D. Jia und B. Guo
Veröffentlicht/Copyright: 2. Mai 2013
Veröffentlichen auch Sie bei De Gruyter Brill
Manuskript einreichen Informationen für Autor*innen
International Polymer Processing
Aus der Zeitschrift International Polymer Processing Band 19 Heft 4

Abstract

Two kinds of nanocomposites of nitrile-butadiene rubber (NBR), zinc methacrylate (ZDMA) and organomontmorillonite (OMMT), NBR-ZDMA-HMMTand NBR-ZDMA-USMMT, were prepared by the reactive mixing intercalation method with ZDMA and two kinds of organomontmorillonite, hexadecyltrimethylammonium bromide modified montmorillonite (HMMT) and unsaturated chemical modified montmorillonite (USMMT). The structure and properties of the nanocomposites were investigated by X-ray diffraction, transmission electron microscopy, differential scanning calorimetry and determination of crosslinking density and mechanical properties. The results showed that the interlayer galleries of HMMT and USMMT were enlarged as ZDMA polymerized in situ in rubber matrix and between the interlayer of the silicates. The layered silicates were dispersed disorderly in rubber matrix at a nanometer level. The crosslinking density of the NBR vulcanizates was increased by the addition of ZDMA and HMMT or USMMT. The glass transition temperatures of the NBR-ZDMA-OMMT nanocomposites were higher than that of the neat NBR. The mechanical properties of the NBR-ZDMA-HMMTand NBR-ZDMA-USMMT nanocomposites are remarkably superior to those of the neat NBR vulcanizate.

∗ Mail address: D. Jia, College of Material Science and Engineering, South China University of Technology, Guangzhou, 510640 China E-mail:

References

1 Nishimura, K., Saito, T., Asada, M.: Paper presented at the SAE Int. Cong. & Exp., Detroit, MI (1989).Suche in Google Scholar

2 Costin, R., Nagel, W., Ekwall, R.: Rubb. Chem. Technol.64, p. 152 (1991).10.5254/1.3538548Suche in Google Scholar

3 Medalia, A. I., Alesi, A. L., Mead, J. L.: Rubb Chem Technol.65, p. 154 (1992).10.5254/1.3538597Suche in Google Scholar

4 Nagata, N., Sato, T., Fujii, T., Saito, Y.: J. Appl. Polym. Sci. Appl. Polym. Symp.53, p. 103 (1994).Suche in Google Scholar

5 Yuan, X. H., Zhang, Y., Peng, Z. L., Zhang, Y. X.: J. Appl. Polym. Sci.84, p. 1403 (2002).10.1002/app.10323Suche in Google Scholar

6 Nagata, N., Sato, K., Fujii, T., Saito, Y.: J. Appl. Polym. Sci.53, p. 103 (1994).Suche in Google Scholar

7 Kojima, Y., Fukumori, K., Okada, A., Kurachi, T.: J. Mater. Sci. Lett.12, p. 889 (1993).10.1007/BF00455608Suche in Google Scholar

8 Wang, Y. Z., Zhang, L. Q., Tang, C. H., Yu, D. S.: J. Appl. Polym. Sci.78, p. 1879 (2000).10.1002/1097-4628(20001209)78:11<1879::AID-APP50>3.0.CO;2-1Suche in Google Scholar

9 Zhang, L. Q., Wang, Y. Z., Wang, Y. Q., Sui, Y., Yu, D. S.: J. Appl. Polym. Sci.78, p. 1873 (2000).10.1002/1097-4628(20001209)78:11<1873::AID-APP40>3.0.CO;2-8Suche in Google Scholar

10 Wang, S. J., Long, C. F., Wang, X. Y., Li, Q., Qi, Z. N.: J. Appl. Polym. Sci.69. p. 1557 (1998).10.1002/(SICI)1097-4628(19980822)69:8<1557::AID-APP10>3.0.CO;2-SSuche in Google Scholar

11 Wu, Y. P., Zhang, L. Q., Wang, Y. Q., Liang, Y., Yu, D. S.: J. Appl. Polym. Sci.82, p. 2842 (2001).10.1002/app.2138Suche in Google Scholar

12 China Patent CN 1397572A (2003) Jia, D. M., Luo, Y. F., Liu, L., Zheng, Z. Y..Suche in Google Scholar

13 Liu, L., Luo, Y. F., Zhang, F., Huang, M. Y., Jia, D. M.: China Synth. Rubb. Ind.25, p. 262 (2002).Suche in Google Scholar

Received: 2004-2-27
Accepted: 2004-10-25
Published Online: 2013-05-02
Published in Print: 2004-12-01

© 2004, Carl Hanser Verlag, Munich

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Editorial
  4. Polymer Processing Society at 20
  5. Mixing and Screw Extrusion
  6. Index for Simultaneous Dispersive and Distributive Mixing Characterization in Processing Equipment
  7. Determination of the Residence Time Distribution in Twin Screw Extruders via Free Radical Modification of PE
  8. On-line Visualization of PS/PP Melting Mechanisms in a Co-rotating Twin Screw Extruder
  9. Die Extrusion
  10. Influence of Filler Particle Geometry on Die Swell
  11. Reactive Processing
  12. Side Chain Extension of Maleated Polypropylene with Diamine
  13. Reactive Batch Mixing for Improved Silica-Silane Coupling
  14. Studies on NBR-ZDMA-OMMT Nanocomposites Prepared by Reactive Mixing Intercalation Method
  15. Fiber and Film
  16. High-speed Melt Spinning of Polyethylene terephthalate with Periodic Oscillation of Take-up Velocity
  17. A Constitutive Analysis of Extensional Flow of EVA Nanocomposites
  18. Laser Sintering
  19. Laser Sintering of High Temperature Resistant Polymers with Carbon Black Additives
  20. Molding
  21. Flow Visualization of Filling with Aid of Colored Billets During Impact Micro-Injection Molding
  22. Modelling of Cyclic 3-Dimensional Heat Transfer in Injection Moulding
  23. PPS News
  24. PPS News
https://doi.org/10.3139/217.1851

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Editorial
  4. Polymer Processing Society at 20
  5. Mixing and Screw Extrusion
  6. Index for Simultaneous Dispersive and Distributive Mixing Characterization in Processing Equipment
  7. Determination of the Residence Time Distribution in Twin Screw Extruders via Free Radical Modification of PE
  8. On-line Visualization of PS/PP Melting Mechanisms in a Co-rotating Twin Screw Extruder
  9. Die Extrusion
  10. Influence of Filler Particle Geometry on Die Swell
  11. Reactive Processing
  12. Side Chain Extension of Maleated Polypropylene with Diamine
  13. Reactive Batch Mixing for Improved Silica-Silane Coupling
  14. Studies on NBR-ZDMA-OMMT Nanocomposites Prepared by Reactive Mixing Intercalation Method
  15. Fiber and Film
  16. High-speed Melt Spinning of Polyethylene terephthalate with Periodic Oscillation of Take-up Velocity
  17. A Constitutive Analysis of Extensional Flow of EVA Nanocomposites
  18. Laser Sintering
  19. Laser Sintering of High Temperature Resistant Polymers with Carbon Black Additives
  20. Molding
  21. Flow Visualization of Filling with Aid of Colored Billets During Impact Micro-Injection Molding
  22. Modelling of Cyclic 3-Dimensional Heat Transfer in Injection Moulding
  23. PPS News
  24. PPS News
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 30.10.2025 von https://www.degruyterbrill.com/document/doi/10.3139/217.1851/html?lang=de
Button zum nach oben scrollen