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Polymer Blends with Fibrillar Phase Morphology Prepared by Self-Reinforcing Technique

I. Blends of Isotactic Polypropylene and Polyamide-12
  • J. Varga , A. Breining and G. W. Ehrenstein
Published/Copyright: June 6, 2013
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International Polymer Processing
From the journal International Polymer Processing Volume 15 Issue 1

Abstract

High-strength, high-modulus products with a characteristic phase morphology were prepared via the injection molding of blends of isotactic polypropylene (PP) and polyamide-12 (PA-12) under special processing conditions (low melt temperature, high holding pressure, and a convergent sprue design). These conditions generated a situation in which the dispersed phase can be distributed in the self-reinforced matrix as oriented fibrils. Optical (polarized light optical and phase contrast) microscopic and SEM investigations revealed a uniform distribution of the dispersed phase within the matrix. These products can be regarded as in situ thermoplastic composites. The strength level of the self-reinforced blends is approximately twice as high as that of the products processed under conventional conditions. The PA-12 phase dispersed as ultrathin fibrils enhances the flexural impact strength of the blends, decreases their notch sensitivity, and alters its fracture mechanism.

* Mail address: Prof. Dr. J. Varga, Friedrich-Alexander-Universität, Erlangen-Nürnberg, Lehrstuhl für Kunststofftechnik, Am Weichselgarten 9, D-91058 Erlangen, Germany
Received: 1999-9-20
Accepted: 1999-12-20
Published Online: 2013-06-06
Published in Print: 2000-03-01

© 2000, Carl Hanser Verlag, Munich

Articles in the same Issue

  1. Editorial
  2. Sixth of a Series: Pioneer of Man-Made Fibers and Solution Spinning Louis-Marie-Hilaire Bernigaud, Comte de Chardonnet
  3. Screw Extrusion
  4. A Network Analysis of a Screw Mixing Zone
  5. Experimental and Numerical Study of Rhomboidal Mixing Sections
  6. Reactive Extrusion
  7. Bulk Polymerization of ∊-Caprolactone in Twin Screw Extruder
  8. Die Extrusion
  9. Computer Aided Optimisation of Profile Extrusion Dies
  10. Fibers and Films
  11. An Investigation of Venturi and Coanda Effects in Blown Film Cooling
  12. Blends
  13. Solidification Behaviour of PA6/iPP Blends at High Cooling Rates
  14. Polymer Blends with Fibrillar Phase Morphology Prepared by Self-Reinforcing Technique
  15. Molding
  16. Compressive Squeeze Flow of Generalized Newtonian Fluids with Apparent Wall Slip
  17. Comparative Study of Ziegler-Natta and Metallocene Based Polypropylenes in Injection Molding
  18. The Pressure-Volume-Temperature Behavior Polyethylene Melts
  19. Evaluation of the Thermal Behaviour of Injection Moulds
  20. Polymer Solidification under Pressure and High Cooling Rates
https://doi.org/10.3139/217.1580

Articles in the same Issue

  1. Editorial
  2. Sixth of a Series: Pioneer of Man-Made Fibers and Solution Spinning Louis-Marie-Hilaire Bernigaud, Comte de Chardonnet
  3. Screw Extrusion
  4. A Network Analysis of a Screw Mixing Zone
  5. Experimental and Numerical Study of Rhomboidal Mixing Sections
  6. Reactive Extrusion
  7. Bulk Polymerization of ∊-Caprolactone in Twin Screw Extruder
  8. Die Extrusion
  9. Computer Aided Optimisation of Profile Extrusion Dies
  10. Fibers and Films
  11. An Investigation of Venturi and Coanda Effects in Blown Film Cooling
  12. Blends
  13. Solidification Behaviour of PA6/iPP Blends at High Cooling Rates
  14. Polymer Blends with Fibrillar Phase Morphology Prepared by Self-Reinforcing Technique
  15. Molding
  16. Compressive Squeeze Flow of Generalized Newtonian Fluids with Apparent Wall Slip
  17. Comparative Study of Ziegler-Natta and Metallocene Based Polypropylenes in Injection Molding
  18. The Pressure-Volume-Temperature Behavior Polyethylene Melts
  19. Evaluation of the Thermal Behaviour of Injection Moulds
  20. Polymer Solidification under Pressure and High Cooling Rates
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