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Comparative Study of Ziegler-Natta and Metallocene Based Polypropylenes in Injection Molding

Simulation and Experiment
  • A. I. Isayev , Y. Churdpunt and X. Guo
Published/Copyright: June 6, 2013
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International Polymer Processing
From the journal International Polymer Processing Volume 15 Issue 1

Abstract

Injection molding of the isotactic polypropylenes polymerized using metallocene and Ziegler-Natta catalysts and having the same molecular weights was performed. Rheological properties and shear-induced crystallization kinetics were measured and their comparative analysis is made. These data are fitted to the equations necessary for simulation of the injection molding process. Numerous injection molding runs were carried out and pressure measurements during molding were performed. The gapwise distribution of crystallinity, spherulite size and thickness of flow-induced crystallized layer in moldings were measured. The effect of various processing conditions on these values was determined. The measured values were compared with the results obtained from the simulation of injection molding process using unified theory of crystallization proposed earlier. Comparative analysis is made between flow conditions and crystallization behavior of these polymers and their effect on the pressure development and structural characteristics of the moldings.

* Mail address: Prof. Dr. A. I. Isayev, Institute of Polymer Engineering, University of Akron, Akron, Ohio 44325-0301, USA
Received: 1999-6-14
Accepted: 1999-10-12
Published Online: 2013-06-06
Published in Print: 2000-03-01

© 2000, Carl Hanser Verlag, Munich

Articles in the same Issue

  1. Editorial
  2. Sixth of a Series: Pioneer of Man-Made Fibers and Solution Spinning Louis-Marie-Hilaire Bernigaud, Comte de Chardonnet
  3. Screw Extrusion
  4. A Network Analysis of a Screw Mixing Zone
  5. Experimental and Numerical Study of Rhomboidal Mixing Sections
  6. Reactive Extrusion
  7. Bulk Polymerization of ∊-Caprolactone in Twin Screw Extruder
  8. Die Extrusion
  9. Computer Aided Optimisation of Profile Extrusion Dies
  10. Fibers and Films
  11. An Investigation of Venturi and Coanda Effects in Blown Film Cooling
  12. Blends
  13. Solidification Behaviour of PA6/iPP Blends at High Cooling Rates
  14. Polymer Blends with Fibrillar Phase Morphology Prepared by Self-Reinforcing Technique
  15. Molding
  16. Compressive Squeeze Flow of Generalized Newtonian Fluids with Apparent Wall Slip
  17. Comparative Study of Ziegler-Natta and Metallocene Based Polypropylenes in Injection Molding
  18. The Pressure-Volume-Temperature Behavior Polyethylene Melts
  19. Evaluation of the Thermal Behaviour of Injection Moulds
  20. Polymer Solidification under Pressure and High Cooling Rates
https://doi.org/10.3139/217.1571

Articles in the same Issue

  1. Editorial
  2. Sixth of a Series: Pioneer of Man-Made Fibers and Solution Spinning Louis-Marie-Hilaire Bernigaud, Comte de Chardonnet
  3. Screw Extrusion
  4. A Network Analysis of a Screw Mixing Zone
  5. Experimental and Numerical Study of Rhomboidal Mixing Sections
  6. Reactive Extrusion
  7. Bulk Polymerization of ∊-Caprolactone in Twin Screw Extruder
  8. Die Extrusion
  9. Computer Aided Optimisation of Profile Extrusion Dies
  10. Fibers and Films
  11. An Investigation of Venturi and Coanda Effects in Blown Film Cooling
  12. Blends
  13. Solidification Behaviour of PA6/iPP Blends at High Cooling Rates
  14. Polymer Blends with Fibrillar Phase Morphology Prepared by Self-Reinforcing Technique
  15. Molding
  16. Compressive Squeeze Flow of Generalized Newtonian Fluids with Apparent Wall Slip
  17. Comparative Study of Ziegler-Natta and Metallocene Based Polypropylenes in Injection Molding
  18. The Pressure-Volume-Temperature Behavior Polyethylene Melts
  19. Evaluation of the Thermal Behaviour of Injection Moulds
  20. Polymer Solidification under Pressure and High Cooling Rates
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