Startseite Simulation and Experimental Verification of Crystallization and Birefringence in Melt Spinning of PET
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Simulation and Experimental Verification of Crystallization and Birefringence in Melt Spinning of PET

  • K. H. Kim , A. I. Isayev und K. Kwon
Veröffentlicht/Copyright: 1. März 2013
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International Polymer Processing
Aus der Zeitschrift International Polymer Processing Band 21 Heft 1

Abstract

A novel approach for the numerical simulation of the development of crystallinity and birefringence on the spinline was proposed. The approach was based on the calculation of elastic recovery and crystalline and amorphous orientation functions without making any assumption about freezing. To model crystallization, the amorphous orientation function and the flow effect on the equilibrium melting temperature elevation due to the entropy reduction between the oriented and unoriented melts were incorporated. The crystalline orientation function was calculated from the frozen-in elastic recovery. The entropy change and frozen-in elastic recovery calculation were based on a nonlinear viscoelastic constitutive Eq. with the crystallinity and temperature dependent viscosity and relaxation time. The crystalline and amorphous contributions to the overall birefringence were obtained from the crystalline orientation function and the flow birefringence, respectively. The temperature, diameter, density, and birefringence profile in both low- and high-speed spun PET fibers were predicted and compared with the experimental data from literature. Theoretical predictions were found to be in agreement with the published experimental data.

This paper is dedicated to honor Professor James L. White, the founder of the Polymer Processing Society and the founding editor of the International Polymer Processing Journal

2∗ Mail address: A. I. Isayev, Institute of Polymer Engineering, University of Akron, Akron, Ohio 44325-0301, U.S.A.E-mail:

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Received: 2005-12-04
Accepted: 2005-12-17
Published Online: 2013-03-01
Published in Print: 2006-03-01

© 2006, Hanser Publishers, Munich

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Editorial
  4. Dedication of the Special Issue of International Polymer Processing in Honor of Prof. James Lindsay White, Editor Emeritus and Founding Editor
  5. Invited Papers
  6. Melt Compounding of Polymeric Nanocomposites
  7. Experiments and Analysis of Effect of Calender Gaps on Melting of PVC Powders in an Intermeshing Counter-rotating Twin-screw Extruder
  8. Quantitative Analysis for Polymer Degradation in the Extrusion Process
  9. Visualization of Flow Instabilities for High Density Polyethylene
  10. Heat Transfer through Metal Walls of Finite Thickness
  11. Simulation and Experimental Verification of Crystallization and Birefringence in Melt Spinning of PET
  12. Structural Development and Properties of Melt Spun Poly(butylene succinate) and Poly(butylene terephthalate-co-succinate-co-adipate) Biodegradable Fibers
  13. External Calibration in PA12 Tube Extrusion
  14. Tubular Film Extrusion Stability of Metallocene Linear Low Density Polyethylene
  15. Multilayer Barrier Film of Biaxially Oriented PA6/EVOH by Double Bubble Tubular Film Process
  16. PPS News
  17. PPS News
  18. Seikei-Kakou Abstracts
  19. Seikei-Kakou Abstracts
https://doi.org/10.3139/217.0058

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Editorial
  4. Dedication of the Special Issue of International Polymer Processing in Honor of Prof. James Lindsay White, Editor Emeritus and Founding Editor
  5. Invited Papers
  6. Melt Compounding of Polymeric Nanocomposites
  7. Experiments and Analysis of Effect of Calender Gaps on Melting of PVC Powders in an Intermeshing Counter-rotating Twin-screw Extruder
  8. Quantitative Analysis for Polymer Degradation in the Extrusion Process
  9. Visualization of Flow Instabilities for High Density Polyethylene
  10. Heat Transfer through Metal Walls of Finite Thickness
  11. Simulation and Experimental Verification of Crystallization and Birefringence in Melt Spinning of PET
  12. Structural Development and Properties of Melt Spun Poly(butylene succinate) and Poly(butylene terephthalate-co-succinate-co-adipate) Biodegradable Fibers
  13. External Calibration in PA12 Tube Extrusion
  14. Tubular Film Extrusion Stability of Metallocene Linear Low Density Polyethylene
  15. Multilayer Barrier Film of Biaxially Oriented PA6/EVOH by Double Bubble Tubular Film Process
  16. PPS News
  17. PPS News
  18. Seikei-Kakou Abstracts
  19. Seikei-Kakou Abstracts
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