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The Dynamic Apparent Viscosity of Polymer Melts During Pulsatile Extrusion Flow with Vibration Force Field

Theory and Experiment
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Published/Copyright: April 6, 2013
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Abstract

The dynamic apparent viscosity of polymer melts during pulsatile extruding flow with a vibration force field was studied on a self-made dynamic capillary rheometer (DCR). A theory that could reflect the vibration influence on the dynamic apparent viscosity was proposed. Due to the superposition of the vibration force field upon the steady shear flow, the phase difference between the shear stress and the shear rate could be chosen as a parameter to reflect the effect of vibration on the dynamic apparent viscosity. According to this theory, the average shear rate during pulsatile extrusion increased because of the existence of the phase difference, which caused the decrease of the dynamic apparent viscosity. The experimental results proved that the phase difference was reduced with the increase of vibration frequency, which resulted in a decrease in the dynamic apparent viscosity during the pulsatile extrusion.


Mail address: GuangJiang He, National Engineering Research Center of Novel Equipment For Polymer Processing, South China University of Technology, Guangzhou 510640, PRC. E-mail:

References

Booij, H. C., “Influence of Superimposed Steady Shear Flow on the Dynamic Properties of Non-Newtonian Fluids”, Rheol Acta, 5 (3), 215221 (1966)10.1007/BF01982430Search in Google Scholar

Giacomin, A. J., et al., “Validity of Separable BKZ Model for Large Amplitude Oscillatory Shear”, J. Rheol., 37(5), 811826 (1993)10.1122/1.550396Search in Google Scholar

Hyun, K., et al., “Large Amplitude Oscillatory Shear as a Way to Classify the Complex Fluids”, J. Non-Newt. Fluid. Mech., 107, 5165 (2002)10.1016/S0377-0257(02)00141-6Search in Google Scholar

HyunK., et al., “Nonlinear Response of Complex Fluids under LAOS Flow”, Korea-Australia Rheology Journal, 15 (2), 97105 (2003)Search in Google Scholar

Ibar, J. P., “Control of Polymer Properties by Melt Vibration Technology: A Review”, Polym. Eng. Sci., 38 (1), 120 (1998)10.1002/pen.10161Search in Google Scholar

Ibar, J. P., “Vibromolding: A New Process to Mold Polymeric Materials”, ACS Polym. Prep., 21(1), 215 (1980)Search in Google Scholar

Isayev, A. I., Wong, C. M., “Parallel Superposition of Small- and Large-Amplitude Oscillations upon Steady Shear Flow of Polymer Fluids”, J. Polym. Sci. Part B: Polym. Phys., 26, 23032327 (1988)10.1002/polb.1988.090261110Search in Google Scholar

Isayev, A. I., et al., “Effect of Oscillations during Extrusion on Rheology and Mechanical Properties of Polymers”, Adv. Polym. Tech., 10(1), 3145 (1990a)10.1002/adv.1990.060100104Search in Google Scholar

Isayev, A. I., et al., “Flow of Thermoplastics in an Annular Die under Orthogonal Oscillations”, J. Non-Newt. Fluid. Mech., 34, 375397 (1990b)10.1016/0377-0257(90)80030-4Search in Google Scholar

Kalay, G., Bevis, M. J., “Processing and Physical Property Relationships in Injection Molded Isotactic Polypropylene 1. Mechanical Properties”, J. Polym. Sci. Polym. Phys., 35(2), 241263 (1997a)10.1002/(SICI)1099-0488(19970130)35:2<241::AID-POLB5>3.0.CO;2-VSearch in Google Scholar

Kalay, G., Bevis, M. J., “The Effect of Shear Controlled Orientation in Injection Moulding on the Mechanical Properties of an Aliphatic Polyketone”, J. Polym. Sci. Polym. Phys., 35(3), 415430 (1997b)10.1002/(SICI)1099-0488(199702)35:3<415::AID-POLB2>3.0.CO;2-RSearch in Google Scholar

Mewis, J., et al., “Determining Relaxation Modes in Flowing Associative Polymers using Superposition Flows”, Macromolecules, 34, 13761383 (2001)10.1021/ma000987pSearch in Google Scholar

Qu, J. P., et al., “Effect of the Vibration Shear Flow Field in Capillary Dynamic Rheometer on the Crystallization Behavior of Polypropylene”, Eur. Polym. J., 40, 18491855 (2004)10.1016/j.eurpolymj.2004.03.023Search in Google Scholar

Qu, J. P., “Study on the Pulsating Extrusion Characteristics of Polymer Melt Through Round-Sectioned Die”, Polym.-Plast. Technol., 41(1), 115132 (2002a)10.1081/PPT-120002064Search in Google Scholar

Qu, J. P., et al., “Performance of Filled Polymer Systems under Novel Dynamic Extrusion Processing Conditions”, Plastics Rubber and Composites, 31 (10), 432435 (2002b)10.1179/146580102225008330Search in Google Scholar

Sim, H. G., et al., “Large Amplitude Oscillatory Shear Behavior of Complex Fluids Investigated by a Network Model: A Guideline for Classification”, J. Non-Newt. Fluid Mech., 112, 237250 (2003)10.1016/S0377-0257(03)00102-2Search in Google Scholar

Tirtaatmadja, V., et al., “Superposition of Oscillations on Steady Shear Flow as a Technique for Investigating the Structure of Associative Polymers”, Macromolecules, 30, 14261433 (1997)10.1021/ma960098vSearch in Google Scholar

Wilhelm, M., “Fourier-Transform Rheology”, Macromol. Mater. Eng., 287(2), 83105 (2002)10.1002/1439-2054(20020201)287:2<83::AID-MAME83>3.0.CO;2-BSearch in Google Scholar

Wong, C. M., Isayev, A. I., “Orthogonal Superposition of Small and Large Amplitude Oscillations upon Steady Shear Flow of Polymer Fluids”, Rheol. Acta, 28(2), 176189 (1989)10.1007/BF01356978Search in Google Scholar

Yosick, J. A., Giacomin, A. J., “Can Nonlinear Deformation Amplify Subtitle Differences in Linear Viscoelasticity?”, J. Non-Newt. Fluid Mech., 66, 193212 (1996)10.1016/S0377-0257(96)01477-2Search in Google Scholar

Zhang, A. Y., et al., “Enhancement in Micro-Fatigue Resistance of UHMWPE and HDPE Processed by SCORIM”, J. Mater. Sci., 37(15), 31893198 (2002)10.1023/A:1016114513003Search in Google Scholar

Zheng, Y.et al., “Effect Of Vibration on Rheology of Polymer Melt”, J. Appl. Polym. Sci., 85, 15871592 (2002)10.1002/app.10649Search in Google Scholar

Received: 2006-1-7
Accepted: 2007-8-26
Published Online: 2013-04-06
Published in Print: 2008-03-01

© 2008, Carl Hanser Verlag, Munich

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