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Thermophysical properties of solid phase palladium over a wide temperature range

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Published/Copyright: August 22, 2013
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 104 Issue 5

Abstract

This paper presents experimental results of a range of thermophysical properties of pure polycrystalline palladium samples over a wide temperature range. Specific heat capacity was measured from 250 to 1 770 K, specific electrical resistivity from 250 to 1 800 K, hemispherical total emissivity from 1 100 to 1 800 K, normal spectral emissivity from 1 340 to 1 720 K, and thermal diffusivity in the range from 200 to 1 540 K. From the measured data, the thermal conductivity and Lorentz function were computed in the range from 250 to 1 540 K. Specific heat capacity, electrical resistivity, and both emissivities were measured by means of subsecond pulse calorimetry, while the thermal diffusivity was obtained using the laser flash technique. The first method used specimens in the form of a thin rod, of about 2 mm in diameter and 200 mm in length, and the second disk specimens of about 3 mm in thickness and 10 mm in diameter. For necessary corrections, literature data on thermal linear expansion have been used. All the results are compared with available literature data and discussed.

Keywords: High-temperature transition metals; Palladium; Thermophysical properties
* Correspondence address, Dr. Nenad Milošević P.O. Box 522, 11001 Belgrade, Serbia, Tel.: +381 11 80 66 609, Fax: +381 11 24 53 670, E-mail:

References

[1] G.Grube, R.Knabe: Z. Electrochem. Angew. Phys. Chem.42 (1936) 793.Search in Google Scholar

[2] B.Dupree, J.Van Zytveld, J.Enderby: J. Phys. F5 (1975) 200. 10.1088/0305-4608/5/11/007Search in Google Scholar

[3] H.Güntherodt, E.Hauser, H.Künzi, R.Muller: Phys. Lett. A54 (1975) 291. 10.1016/0375-9601(75)90263-7Search in Google Scholar

[4] V.Zinoviev, R.Krentsis, P.Geld: Soviet Phys. Solid State11 (1969) 685.Search in Google Scholar

[5] Y.Touloukian, R.Powell, C.Ho, M.Nicolaou: Thermophysical Properties of Matter, Vol. 10: Thermal Diffusivity, IFI/Plenum, New York (1973) 131.10.1007/978-1-4757-1625-2Search in Google Scholar

[6] W.Jaeger, H.Diesselhorst: Wiss. Abhandl. Physik.-tech. Reichs3 (1900) 269.Search in Google Scholar

[7] T.Barratt: Proc. Roy. Soc. (London)26 (1914) 347.10.1088/1478-7814/26/1/335Search in Google Scholar

[8] R.Powell, R.Tye, M.Woodman: J. Less-Common Metals12 (1967) 1. 10.1016/0022-5088(67)90062-8Search in Google Scholar

[9] S.Jain, V.Sinha, B.Reddy: Brit. J. Appl. Phys.2 (1969) 1283.Search in Google Scholar

[10] M.Laubitz, T.Matsumura: Can. J. Phys.50 (1972) 196. 10.1139/p72-031Search in Google Scholar

[11] L.Binkele, M.Brunen: Thermal Conductivity, Electrical Resistivity and Lorentz Function Data for Metallic Elements in the Range 273 to 1500 K, Report Jül-3006, Forschungszentrum Jülich GmbH (1994).Search in Google Scholar

[12] C.Ho, R.Powell, P.Liley: J. Phys. Chem. Ref. Data1 (1972) 279. 10.1063/1.3253100Search in Google Scholar

[13] N.Milošević, K.Maglić: Int. J. Thermophys.27 (2006) 530. 10.1007/s10765-006-0045-2Search in Google Scholar

[14] N.Milošević, K.Maglić: Int. J. Thermophys.27 (2006) 1140. 10.1007/s10765-006-0045-2Search in Google Scholar

[15] N.Milošević, K.Maglić: High Temp. High Press.37 (2008) 187.Search in Google Scholar

[16] N.Milošević, I.Aleksić: Int. J. Mater. Res.103 (2012) 707. 10.3139/146.110678Search in Google Scholar

[17] A.Cezairliyan, in: K.Maglić, A.Cezairliyan, V.Peletsky (Eds.), Compendium of Thermophysical Property Measurement Methods, Vol. 2 - Recommended Measurement Techniques and Practices, Plenum Press, New York, (1992) 483.Search in Google Scholar

[18] A.Dobrosavljević, K.Maglić: High Temp. High Press.21 (1989) 411.Search in Google Scholar

[19] K.Maglić, R.Taylor, in: K.Maglić, A.Cezairliyan, V.Peletsky (Eds.), Compendium of Thermophysical Property Measurement Methods Vol. 2: Recommended measurement techniques and measurement practices, Plenum Press, New York (1992) 281.10.1007/978-1-4615-3286-6_10Search in Google Scholar

[20] N.Milošević, M.Raynaud, M.Laurent, K.Maglić: Thermal Science3 (1999) 71.Search in Google Scholar

[21] Y.Touloukian, Y.Kirby, R.Taylor, P.Desai: Thermophysical Properties of Matter, Vol. 12: Thermal expansion-metallic elements and alloys, IFI/Plenum Press, New York (1975).Search in Google Scholar

[22] F.Jaeger, T.Poppema: Rec. Trav. Chim.55 (1936) 492. 10.1002/recl.19360550606Search in Google Scholar

[23] O.Vollmer, R.Kohlhaas: Z. Naturforsch.24a (1969) 1669.10.1515/zna-1969-1036Search in Google Scholar

[24] E.Cordfunke, R.Konings: Thermochimica Acta139 (1989) 99. 10.1016/0040-6031(89)87013-3Search in Google Scholar

[25] A.P.Miiller, A.Cezairliyan: Int. J. Thermophys.1 (1980) 217. 10.1007/BF00504522Search in Google Scholar

[26] C.Cagran, G.Pottlacher: Platinum Metals Rev.50 (2006) 144. 10.1595/147106706X129079Search in Google Scholar

[27] R.Matula: J. Phys. Chem. Ref. Data8 (1979) 1147. 10.1063/1.555614Search in Google Scholar

[28] J.Conybeare: Proc. Phys. Soc.49 (1937) 29. 10.1088/0959-5309/49/1/306Search in Google Scholar

[29] A.Schindler, R.Smith, E.Salkovitz: NRL Rept. No.4974 (1957).Search in Google Scholar

[30] I.Epelboin, A.Vapaille: Compt. Rend.244 (1957) 314.Search in Google Scholar

[31] R.Powell, R.Tye, M.Woodman: Platinum Metals Rev.6 (1962) 138.Search in Google Scholar

[32] W.Landensperger, D.Stark: Z. Physik180 (1964) 178. 10.1007/BF01380688Search in Google Scholar

[33] H.Betz, O.Olsen, B.Schurin, J.Morris: ARF WADC-TR-56-222 II (1957).Search in Google Scholar

[34] G.Burgess, R.Waltenberg: Natl. Bur. Stand. Bull.11 (1915) 591.Search in Google Scholar

Received: 2012-7-5
Accepted: 2012-8-27
Published Online: 2013-08-22
Published in Print: 2013-05-10

© 2013, Carl Hanser Verlag, München

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https://doi.org/10.3139/146.110889
Keywords for this article
High-temperature transition metals; Palladium; Thermophysical properties

Articles in the same Issue

  1. Contents
  2. Contents
  3. Original Contributions
  4. Martensite transformation of sub-micron retained austenite in ultra-fine grained manganese transformation-induced plasticity steel
  5. Isothermal transformation of β-phase in Cu-rich Cu-Al-Sn alloys
  6. The effect of nitrogen on the coarsening rate of precipitate phases in iron-based alloys with chromium and vanadium: experimental and theoretical investigations
  7. Phase diagram investigation of the Sn-InxAgyCuz (x:y:z = 7:2:1) section in the Ag-In-Sn-Cu system
  8. Grain refinement and mechanical properties of low-carbon steel by means of equal channel angular pressing and annealing
  9. Thermophysical properties of solid phase palladium over a wide temperature range
  10. Magnetic properties of Nd-Fe-Co-Al rapid solidification alloys
  11. Synthesis of Ir1-xRex (0.15 ≤ x ≤ 0.40) solid solutions under high-pressure and high-temperature
  12. Preparation and magnetic characterization of Fe/metal oxide nanocomposite particles by means of hydrogen reduction assisted ultrasonic spray pyrolysis (USP-HR)
  13. Biofilm formation and corrosion resistance of Ni/SiC nanocomposite layers
  14. Characterization of electrospun fibrous scaffold produced from Indian eri silk fibroin
  15. Hydrothermal synthesis of nano nickel phosphides and investigation of their thermal stability
  16. Effects of PVP and CTAB surfactants on the morphology of cerium oxide nanoparticles synthesized via co-precipitation method
  17. DGM News
  18. DGM News
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