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Preparation and magnetic characterization of Fe/metal oxide nanocomposite particles by means of hydrogen reduction assisted ultrasonic spray pyrolysis (USP-HR)

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Published/Copyright: August 22, 2013
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 104 Issue 5

Abstract

Fe/metal oxide nanocomposite particles were produced by means of hydrogen reduction assisted ultrasonic spray pyrolysis. Fe/Fe0.761Mg0.239O and Fe/MgO nanocomposite particles were obtained at 600 and 800 °C, respectively. The thermodynamics of the formation reactions were investigated. Increasing the reaction temperature allowed efficient reduction of the precursor to metallic iron that induces the formation of pure MgO phase. The crystallite sizes of the Fe in the composite structures slightly increased, and also the crystallite sizes of the oxides decreased with elevating temperature. The nanocomposite particles exhibited spherical morphology and their particle sizes were slightly different. All of the samples showed ferromagnetic characteristics and the results indicate that the amount of metal and metal oxide phases most affected the saturation magnetizations of the composite particles which were lower than pure iron.

Keywords: Metal/metal oxide composites; Nanocomposite particles; Ultrasonic spray pyrolysis; Magnetic properties
* Correspondence address, Prof. Dr. Sebahattin Gürmen, Istanbul Technical University, Metallurgical and Materials Eng. Dept., Ayazaga Campus, 34469 Sarıyer, Istanbul, Turkey, Tel.: +90 212 285 34 82, Fax: +90 212 285 34 27, E-mail:

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Received: 2012-4-4
Accepted: 2012-8-23
Published Online: 2013-08-22
Published in Print: 2013-05-10

© 2013, Carl Hanser Verlag, München

Articles in the same Issue

  1. Contents
  2. Contents
  3. Original Contributions
  4. Martensite transformation of sub-micron retained austenite in ultra-fine grained manganese transformation-induced plasticity steel
  5. Isothermal transformation of β-phase in Cu-rich Cu-Al-Sn alloys
  6. The effect of nitrogen on the coarsening rate of precipitate phases in iron-based alloys with chromium and vanadium: experimental and theoretical investigations
  7. Phase diagram investigation of the Sn-InxAgyCuz (x:y:z = 7:2:1) section in the Ag-In-Sn-Cu system
  8. Grain refinement and mechanical properties of low-carbon steel by means of equal channel angular pressing and annealing
  9. Thermophysical properties of solid phase palladium over a wide temperature range
  10. Magnetic properties of Nd-Fe-Co-Al rapid solidification alloys
  11. Synthesis of Ir1-xRex (0.15 ≤ x ≤ 0.40) solid solutions under high-pressure and high-temperature
  12. Preparation and magnetic characterization of Fe/metal oxide nanocomposite particles by means of hydrogen reduction assisted ultrasonic spray pyrolysis (USP-HR)
  13. Biofilm formation and corrosion resistance of Ni/SiC nanocomposite layers
  14. Characterization of electrospun fibrous scaffold produced from Indian eri silk fibroin
  15. Hydrothermal synthesis of nano nickel phosphides and investigation of their thermal stability
  16. Effects of PVP and CTAB surfactants on the morphology of cerium oxide nanoparticles synthesized via co-precipitation method
  17. DGM News
  18. DGM News
https://doi.org/10.3139/146.110883
Keywords for this article
Metal/metal oxide composites; Nanocomposite particles; Ultrasonic spray pyrolysis; Magnetic properties

Articles in the same Issue

  1. Contents
  2. Contents
  3. Original Contributions
  4. Martensite transformation of sub-micron retained austenite in ultra-fine grained manganese transformation-induced plasticity steel
  5. Isothermal transformation of β-phase in Cu-rich Cu-Al-Sn alloys
  6. The effect of nitrogen on the coarsening rate of precipitate phases in iron-based alloys with chromium and vanadium: experimental and theoretical investigations
  7. Phase diagram investigation of the Sn-InxAgyCuz (x:y:z = 7:2:1) section in the Ag-In-Sn-Cu system
  8. Grain refinement and mechanical properties of low-carbon steel by means of equal channel angular pressing and annealing
  9. Thermophysical properties of solid phase palladium over a wide temperature range
  10. Magnetic properties of Nd-Fe-Co-Al rapid solidification alloys
  11. Synthesis of Ir1-xRex (0.15 ≤ x ≤ 0.40) solid solutions under high-pressure and high-temperature
  12. Preparation and magnetic characterization of Fe/metal oxide nanocomposite particles by means of hydrogen reduction assisted ultrasonic spray pyrolysis (USP-HR)
  13. Biofilm formation and corrosion resistance of Ni/SiC nanocomposite layers
  14. Characterization of electrospun fibrous scaffold produced from Indian eri silk fibroin
  15. Hydrothermal synthesis of nano nickel phosphides and investigation of their thermal stability
  16. Effects of PVP and CTAB surfactants on the morphology of cerium oxide nanoparticles synthesized via co-precipitation method
  17. DGM News
  18. DGM News
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