Home Technology Effect of La3+ on microwave dielectric properties of (Pb1−xCax)(Fe0.5Nb0.5)O3 (x = 0.5–0.6) ceramics
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Effect of La3+ on microwave dielectric properties of (Pb1−xCax)(Fe0.5Nb0.5)O3 (x = 0.5–0.6) ceramics

  • Qiuhong Yang , Shenzhou Lu , Eung Soo Kim , Yongchang Jiang and Ying Gu
Published/Copyright: June 11, 2013

Abstract

Microwave dielectric properties of La3+-doped (Pb1−xCax)(Fe0.5Nb0.5)O3 (x = 0.5–0.6) ceramics were investigated, and a superstructure was detected in these ceramics. The dielectric constant (∊r) and the temperature coefficient of the resonant frequency (TCF) decreased, while the Qf value of the specimens increased with the increase in Ca2+ content. At the same Ca2+ content, the ∊r and Qf values of La3+-doped specimens were much higher than those of undoped ones. This is attributed to the elimination of oxygen vacancies by the solid solution of surplus La3+ with (Pb, Ca)2+. Excellent microwave dielectric properties of Qf= 6795 GHz, ∊r = 96.41 with TCF = −4.99 ppm · K−1 were obtained at x = 0.55.


1 Correspondence address: Prof. Qiuhong Yang, No 149 Yanchang Road, Shanghai 200072, China, Tel.: +86 21 56331687, Fax: +86 21 56332694, E-mail:

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Received: 2010-11-11
Accepted: 2012-1-25
Published Online: 2013-06-11
Published in Print: 2012-08-01

© 2012, Carl Hanser Verlag, Munich

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