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Thermodynamic properties of liquid copper–antimony–tin alloys determined from e.m.f. measurements

  • Dominika Jendrzejczyk-Handzlik , Wojciech Gierlotka and Krzysztof Fitzner
Published/Copyright: June 11, 2013
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 103 Issue 8

Abstract

The thermodynamics properties of liquid Cu–Sn–Sb alloys were determined using solid-oxide galvanic cells with zirconia electrolyte:

(1)Re+kanthal,Cux−Sby−Sn(1−x−y),SnO2//ZrO2+(Y2O3)//NiO,Ni,Pt

in the temperature range from 998 to 1223 K.

The Gibbs free energy of formation of pure solid SnO2 from pure elements was derived. Using electromotive force values measured for the cell with xSn = 1.0, the following temperature dependence was obtained:

ΔGf,SnO20=−567903+200.33T(±1000J)[Jmol−1]

Activities of tin were determined along three sections of the ternary system specified by the ratio of mole fractions xCu/xSb = 1:3, 1:1, and 3:1. Thermodynamic properties of the liquid phase were described by the Redlich–Kister–Muggianu formula. Using commercial software, phase relations in the ternary system were calculated. The results of the calculations are compared with experimental data available from literature.

Keywords: High-temperature alloys; Electromotive force; Thermodynamic properties; Activity; Cu–Sb–Sn alloys
1 Correspondence address: Dominika Jendrzejczyk-Handzlik, AGH University of Science and Technology, Ave Mickiewicza 30, 30-695 Krakow, Poland, Tel.: +48 12 617 41 25, E-mail:

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Received: 2011-1-25
Accepted: 2012-1-30
Published Online: 2013-06-11
Published in Print: 2012-08-01

© 2012, Carl Hanser Verlag, Munich

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https://doi.org/10.3139/146.110746
Keywords for this article
High-temperature alloys; Electromotive force; Thermodynamic properties; Activity; Cu–Sb–Sn alloys

Articles in the same Issue

  1. Contents
  2. Contents
  3. Editorial
  4. A new editor for IJMR and other changes
  5. ECAA 2011
  6. Proceeding Papers
  7. A model for co-clusters and their strengthening in Al–Cu–Mg based alloys: a comparison with experimental data
  8. Effect of room temperature storage time on precipitation in Al–Mg–Si(–Cu) alloys with different Mg/Si ratios
  9. Influence of Mg/Si ratio on the clustering kinetics in Al–Mg–Si alloys
  10. Effect of simultaneous deformation and artificial ageing on the mechanical properties of an Al–Mg–Si alloy
  11. Ab-initio modeling of metastable precipitation processes in aluminum 7xxx alloys
  12. The kinetics of clustering in Al–Mg–Si alloys studied by Monte Carlo simulation
  13. Regular Articles
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  16. Direct preparation of ferrite magnetic material from Jinchuan nickel sulfide concentrate by acid leaching
  17. Effect of La3+ on microwave dielectric properties of (Pb1−xCax)(Fe0.5Nb0.5)O3 (x = 0.5–0.6) ceramics
  18. Thermodynamic properties of liquid copper–antimony–tin alloys determined from e.m.f. measurements
  19. Modelling of metal nano-particle condensation and growth in a reactive atmosphere
  20. Characterization and catalytic behavior of CuO@SiO2 nanocomposites towards NO oxidation and N2O decomposition
  21. Manufacturing process and electrochemical properties of an Mg–Ga–Hg anode sheet
  22. Effect of strain rate and dynamic strain ageing on work-hardening for aluminium alloy AA5182-O
  23. Steady-state creep analysis of a functionally graded thick cylinder subjected to internal pressure and thermal gradient
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  25. Strength and water permeability of concrete containing various types of fly ashes and filler material
  26. Comment to the paper “Re-evaluation of activities of magnesium and zinc components in the magnesium–zinc binary system from very low to high temperature”
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