Home Experimental investigation of the Zn–Fe–V system at 450°C
Article
Licensed
Unlicensed Requires Authentication

Experimental investigation of the Zn–Fe–V system at 450°C

  • Changjun Wu , Xuping Su , Daniel Liu , Xinming Wang , Fucheng Yin , Zhongxi Zhu and Zhi Li
Published/Copyright: June 11, 2013
Become an author with De Gruyter Brill
Author Information
International Journal of Materials Research
From the journal International Journal of Materials Research Volume 101 Issue 12

Abstract

The 450°C isothermal section of the ZnüFeüV ternary phase diagram has been determined experimentally using X-ray diffraction and scanning electron microscopy coupled with energy/wave dispersive spectroscopy. A new ternary compound T, containing 1.4 to 4.5 at.% V, 5.6 to 15.5 at.% Fe and 82.3 to 92.2 at.% Zn, was positively identified for the first time in this study. The existence of the rphase, together with two ZnüV compounds, VZn3 and V4Zn5, at 450°C has been confirmed. Fe has no detectable solubility in ZnüV compounds. But it was proved that about 3.0 at.% Zn can dissolve into α-V at 450°C. Experimental results indicated that the maximum solubility of V in d, γ1, and γ was 0.5 at.%, 1.3 at.% and 1.8 at.% respectively, whereas that in ζ was less than 0.2 at.%.

Keywords: Zn-Fe-V; Phase diagram; Intermetallic compound; Thermodynamic equilibrium
* Correspondence address, Prof. Xuping Su, School of Materials Science and Engineering, Changzhou University, Changzhou 213164, Jiangsu, P. R. China. Tel.: +86 519 8633 0982, Fax: +86 519 8633 0095. E-mail:

References

[1] R.W.Sandelin: Wire and Wire Products15 (1940) 655.Search in Google Scholar

[2] J.Foct, P.Perrot, G.Reumont: Scr. Metall.28 (1993) 1195.10.1016/0956-716X(93)90453-YSearch in Google Scholar

[3] H.Guttman, P.Niessen: Can. Metall. Q.11 (1972) 609.Search in Google Scholar

[4] J.Zervoudis, G.R.Adams, V.M.Duarte, M.Gilles, R.Sokolowski: Cominco, Ltd. (Vancouver, CA), United States, 2001, 1–11.Search in Google Scholar

[5] J.Mackowiak, N.R.Short: Int. Met. Rev.24 (1979) 1–19.10.1179/095066079790136327Search in Google Scholar

[6] H.M.Jin, Y.Li, H.L.Liu, P.Wu: Chem. Mater.12 (2000) 1879.10.1021/cm990790fSearch in Google Scholar

[7] M.Bernal, P.Tierra, J.Billiet: EP 0951575 B1, 2002.Search in Google Scholar

[8] M.G.Chasanov, R.Schablaske, P.D.Hunt, B.Tani: Trans. Met. Soc., AIME227 (1963) 485.Search in Google Scholar

[9] R.Schablaske, B.Tani, M.Homa, R.Larsen: USAEC Rep. ANL-6687 (1963) 84.Search in Google Scholar

[10] K.Schubert, H.G.Meissner, A.Raman, W.Rossteutscher: Naturwiss.51 (1964) 287.Search in Google Scholar

[11] W.Rossteutscher, K.Schubert: Z. Metallkd.55 (1964) 617.Search in Google Scholar

[12] W.Piotrowski: Hutnik32 (1965) 135.Search in Google Scholar

[13] E.M.Savitskii, V.V.Baron, Y.V.Efimov: Dokl. Akad. Nauk SSSR171 (1966) 331.Search in Google Scholar

[14] J.F.Smith: J. Alloy Phase Diagrams5 (1989) 136.Search in Google Scholar

[15] X.Su, N.-Y.Tang, J.M.Toguri: J. Alloys Compd.325 (2001) 129.10.1016/S0925-8388(01)01273-7Search in Google Scholar

[16] J.Nakano, D.V.Malakhov, G.R.Purdy: Calphad.29 (2005) 276.10.1016/j.calphad.2005.08.005Search in Google Scholar

[17] G.Reumont, P.Perrot, J.Fiorani, J.Hertz: J Phase Equilib.21 (2000) 371.10.1361/105497100770339905Search in Google Scholar

[18] W.Xiong, Y.Kong, Y.Du, Z.-K.Liu, M.Selleby, W.-H.Sun: Calphad.33 (2009) 433.10.1016/j.calphad.2009.01.002Search in Google Scholar

[19] D.Cook, R.Grant: International Lead Zinc Research Organization, Technical Report #ODUDCC 0193, 1993, 1–108.Search in Google Scholar

[20] Kubaschewski: Springer-Verlag, Berlin, Heidelberg and Verlag Stahleisen mbH, Dusseldorf. (1982) 160.Search in Google Scholar

[21] J.F.Smith: Bull. Alloy Phase Diagrams5 (1984) 184.10.1007/BF02868958Search in Google Scholar

[22] K.C. HariKumar, V.Raghavan: Calphad.15 (1991) 307.10.1016/0364-5916(91)90008-8Search in Google Scholar

[23] Y.Ustinovshikov, B.Pushkarev, I.Sapegina: J. Alloys Compd.398 (2005) 133.10.1016/j.jallcom.2005.02.030Search in Google Scholar

[24] X.P.Su, N.-Y.Tang, J.M.Toguri: Can. Metall. Q.40 (2001) 377.Search in Google Scholar

[25] X.Tang, F.Yin, X.Wang, J.Wang, X.Su, N.-Y.Tang: J. Phase Equilib. Diff.28 (2007) 355.10.1007/s11669-007-9092-zSearch in Google Scholar

[26] N.Y.Tang, X.P.SuX.B.Yu: Z. Metallkd.94 (2003) 116.Search in Google Scholar

[27] N.-Y.Tang, X.Su, J.M.Toguri: Calphad.25 (2001) 267.10.1016/S0364-5916(01)00048-7Search in Google Scholar

[28] H.Tu, X.Su, F.Yin, X.Wang, J.Wang: J Alloys Compd. J. Alloys Compd.485 (2009) 270.10.1016/j.jallcom.2009.06.073Search in Google Scholar

[29] C.H.E.Belin, R.C.H.Belin: J. Solid State Chem.151 (2000) 85.10.1006/jssc.2000.8626Search in Google Scholar

[30] C.Wu, X.Su, D.Liu: Unpublished research work.Search in Google Scholar

Received: 2009-10-26
Accepted: 2010-10-4
Published Online: 2013-06-11
Published in Print: 2010-12-01

© 2010, Carl Hanser Verlag, München

Articles in the same Issue

  1. Basic
  2. High-temperature in-situ microscopy during stress-induced phase transformations in Co49Ni21Ga30 shape memory alloy single crystals
  3. Contents
  4. contents
  5. Editorial
  6. Editorial December 2010
  7. Basic
  8. Atomic mobilities and diffusivities in the fcc, L12 and B2 phases of the Ni-Al system
  9. Experimental investigation of the Zn–Fe–V system at 450°C
  10. Time resolved X-ray imaging of eutectic cellular patterns evolving during solidification of ternary Al–Cu–Ag alloys
  11. Reassessment of the Mg–Ge binary system using CALPHAD supported by first-principles calculation
  12. A quantitative modeling of the unloading behavior of metals during a tensile test
  13. A technique for diameter enlargement in SiC crystal growth
  14. Applied
  15. Thermal and chemical stability of Cr2AlC in contact with α-Al2O3 and NiAl
  16. Microstructure and mechanical properties of Zn25Al3Cu based composites with large Al2O3 particles at room and elevated temperatures
  17. An investigation on Incoloy800-SS304 clad plate by explosive welding
  18. Effect of grain boundary precipitates on vibration damping of FeüCrüMgüAl/Si alloy
  19. Adsorption of metal ions on magnetic carbon nanomaterials bearing chitosan-functionalized silica
  20. Tensile and in-vitro degradation study of electro spun fibrous mat produced from eri silk fibroin
  21. Study of the influence of UV-irradiation on the photodegradation of plasticized poly(para-tert-butylstyrene) films
  22. Enhanced photocatalytic activity of beryllium doped titania in visible light on the degradation of methyl orange dye
  23. Progress in chemistry modelling for vapour and aerosol transport analyses
  24. DGM News
  25. Personal
https://doi.org/10.3139/146.110433
Keywords for this article
Zn-Fe-V; Phase diagram; Intermetallic compound; Thermodynamic equilibrium

Articles in the same Issue

  1. Basic
  2. High-temperature in-situ microscopy during stress-induced phase transformations in Co49Ni21Ga30 shape memory alloy single crystals
  3. Contents
  4. contents
  5. Editorial
  6. Editorial December 2010
  7. Basic
  8. Atomic mobilities and diffusivities in the fcc, L12 and B2 phases of the Ni-Al system
  9. Experimental investigation of the Zn–Fe–V system at 450°C
  10. Time resolved X-ray imaging of eutectic cellular patterns evolving during solidification of ternary Al–Cu–Ag alloys
  11. Reassessment of the Mg–Ge binary system using CALPHAD supported by first-principles calculation
  12. A quantitative modeling of the unloading behavior of metals during a tensile test
  13. A technique for diameter enlargement in SiC crystal growth
  14. Applied
  15. Thermal and chemical stability of Cr2AlC in contact with α-Al2O3 and NiAl
  16. Microstructure and mechanical properties of Zn25Al3Cu based composites with large Al2O3 particles at room and elevated temperatures
  17. An investigation on Incoloy800-SS304 clad plate by explosive welding
  18. Effect of grain boundary precipitates on vibration damping of FeüCrüMgüAl/Si alloy
  19. Adsorption of metal ions on magnetic carbon nanomaterials bearing chitosan-functionalized silica
  20. Tensile and in-vitro degradation study of electro spun fibrous mat produced from eri silk fibroin
  21. Study of the influence of UV-irradiation on the photodegradation of plasticized poly(para-tert-butylstyrene) films
  22. Enhanced photocatalytic activity of beryllium doped titania in visible light on the degradation of methyl orange dye
  23. Progress in chemistry modelling for vapour and aerosol transport analyses
  24. DGM News
  25. Personal
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 16.11.2025 from https://www.degruyterbrill.com/document/doi/10.3139/146.110433/html?lang=en
Scroll to top button