The effect of cooling rate on the microstructure and mechanical properties of Mg–Zn–Gd-based alloys
-
Yong Liu
, Guangyin Yuan , Jian Yin , Chen Lu , Wenjiang Ding and J. Z. Jiang
Abstract
The microstructure and mechanical properties of Mg3.5Zn0.6Gd and Mg3.5Zn0.6Gd1.5Cu alloys were investigated under different solidification conditions. The microstructure and phase constitutions of alloys were characterized using optical microscopy, scanning electron microscopy, X-ray diffraction and differential thermal analysis. The results indicate that the cooling rate plays an important role in grain refinement and phase constitutions of Mg – Zn – Gd alloys. In the cooling rate range from 4.8 K s− 1 to 18.5 K s− 1 for the Mg – Zn – Gd system, higher content of the icosahedral phase (I-phase) was obtained under the condition of higher cooling rate which accelerated the nucleation and growth of the I-phase. Under the cooling rate of 18.5 K s− 1, the mechanical properties of the Mg3.5Zn0.6Gd alloy were further improved by the high I-phase content due to its unique icosahedral structure, in addition to the contribution of grain refinement.
References
[1] Z.P.Luo, S.Q.Zhang, Y.L.Tang: Scripta Metall. Mater.28(1993)1513.10.1016/0956-716X(93)90584-FSearch in Google Scholar
[2] Z.P.Luo, S.Q.Zhang: J. Mater. Sci. Lett.12(1993)1490.10.1007/BF00277074Search in Google Scholar
[3] A.Singh, M.Watanabe, A.Kato, A.P.Tsai: Mater. Sci. Eng. A385(2004)382.10.1016/S0921-5093(04)00903-7Search in Google Scholar
[4] A.Singh, A.P.Tsai, M.Nakamura, M.Watanabe, A.Kato: Phil. Mag. Let.83(2003)543.10.1080/09500830310001597027Search in Google Scholar
[5] A.Singh, M.Watanabe, A.Kato, A.P.Tsai: Acta mater.53(2005)4733.10.1016/j.actamat.2005.06.026Search in Google Scholar
[6] D.H.Bae, S.H.Kim, D.H.Kim, W.T.Kim: Acta mater.50(2002)2343.10.1016/S1359-6454(02)00067-8Search in Google Scholar
[7] D.H.Bae, M.H.Lee, K.T.Kim, W.T.Kim, D.H.Kim: J. Alloys Compd.342(2002)44510.1016/S0925-8388(02)00273-6Search in Google Scholar
[8] M.Y.Zheng, X.G.Qiao, S.W.Xu, K.Wu, S.Kamado, Y.Kojima: J. Mater. Sci.40(2005)2587.10.1007/s10853-005-2081-xSearch in Google Scholar
[9] A.Muller, G.Garces, P.Perez, P.Adeva: J. Alloys Compd.443(2007)L1.10.1016/j.jallcom.2006.10.006Search in Google Scholar
[10] G.Y.Yuan, H.Kato, K.Amiya, A.Inoue: J. Mater. Res.20(2005)1278.10.1557/JMR.2005.0156Search in Google Scholar
[11] Y.Liu, G.Y.Yuan, C.Lu, W.J.Ding: J. Alloys Compd.427(2007)160.10.1016/j.jallcom.2006.03.027Search in Google Scholar
[12] Y.Liu, G.Y.Yuan, C.Lu, W.J.Ding: Scripta mater.55(2006)919.10.1016/j.scriptamat.2006.07.035Search in Google Scholar
[13] Y.Liu, G.Y.Yuan, C.Lu, W.J.Ding: Mater. Sci. Forum546–549(2007)323.10.4028/www.scientific.net/MSF.546-549.323Search in Google Scholar
[14] A.Singh, H.Somekawa, T.Mukai: Scripta Mater.56(2007)935.10.1016/j.scriptamat.2007.02.015Search in Google Scholar
[15] A. Singh, H. Somekawa, T. Mukai: M.O. Pekguleryuz, L.W.F. Mackenzie (Eds.), Magnesium Technology in the Global Age. Canadian (2006)453.Search in Google Scholar
[16] A.Singh, M.Watanabe, A.Kato, A.P.Tsai: Phil. Mag.86(2006)951.10.1080/14786430500253901Search in Google Scholar
[17] A.Halstead, R. D.Rawlings: J. Mater. Sci.20(1985)1248.10.1007/BF01026320Search in Google Scholar
[18] D.Shechtman, I.Blech, D.Gratias, J.W.Cahn: Phys. Rev. Lett.53(1984)1951.10.1103/PhysRevLett.53.1951Search in Google Scholar
[19] J.B.Lin, Q.D.Wang, L.M.Peng, Y.Zhou, W.J.Ding: Mater. Sci. Forum546–549(2007)319.10.4028/www.scientific.net/MSF.546-549.319Search in Google Scholar
[20] G.V.S.Sastry, P.Ramachandrarao: J. Mater. Res.1(1986)246.10.1557/JMR.1986.0247Search in Google Scholar
[21] P.A.Bancel, P.A.Heiney, P.N.Stephens, A.I.Goldman, P.M.Horn: Phys. Rev. Lett.54(1985)2422.10.1103/PhysRevLett.54.2422Search in Google Scholar PubMed
[22] C.H.Shek, G.He, Z.Bian, G.L.Chen, J.K.L.Lai: Mater. Sci. Eng. A357(2003)20.10.1016/S0921-5093(02)00869-9Search in Google Scholar
[23] N.J.Petch: J. Iron Steel Inst.174(1953)25.Search in Google Scholar
[24] G.Neite, K.Kubota, K.Higashi, F.Hehmann: K.H.Matucha (Ed.), Structure and Properties of Nonferrous Alloys, Vol. 8, Weinheim, New York(1996)113.Search in Google Scholar
[25] F.S.Pierce, S.J.Poon, Q, Guo: Science261(1993)737.10.1126/science.261.5122.737Search in Google Scholar PubMed
[26] C.Janot. Quasicrystals. Clarendon Press: Oxford, 1994.10.1007/978-3-662-22223-2_9Search in Google Scholar
[27] S.Q.Lu, B.Huang: Materials Review (In chinese)17(2003)11.Search in Google Scholar
© 2008, Carl Hanser Verlag, München
Articles in the same Issue
- Contents
- Contents
- Basic
- Critical temperature for massive transformation in ultra-low-carbon Fe–C alloys
- Are data correctly fitted by the sin2 ψ and similar methods?
- Liquidus surface projection of the Fe–Co–C ternary system in the iron-rich corner
- Prediction of thermodynamic activities in binary iron-based alloys using two-point Padé approximants
- Study of fatigue dislocation structures in [233] coplanar double-slip-oriented copper single crystals using SEM electronic channelling contrast
- Microstructures at high temperature of Fe-30 wt.% Cr-xC Alloys with x varying from 0 to 2 wt.%
- The effect of cooling rate on the microstructure and mechanical properties of Mg–Zn–Gd-based alloys
- The effect of thermal exposure on the microstructure and hardness of as-cast Mg–Zn–Al alloys with Sn addition
- Applied
- Deformation and fracture of Ti-base nanostructured composite
- Microstructure and some properties of FeCr25Co15 alloy subjected to plastic deformation by complex load
- Determination of the concentration dependent diffusion coefficient of nitrogen in expanded austenite
- Suitability of maraging steel weld cladding for repair of die casting tooling
- Catalytic performance of Fe-, Pd-, and Pd–Fe- mordenites in simulated hydrocarbon-selective catalytic reduction of N2O by methane in a model flue-gas from nitric acid plants
- Thermodynamic consideration and experimental study on the preparation of heat-treated hollow nickel fibres
- A model for the intrinsic kinetic parameters of the direct reduction of MoS2 with hydrogen
- Notification
- DGM News
Articles in the same Issue
- Contents
- Contents
- Basic
- Critical temperature for massive transformation in ultra-low-carbon Fe–C alloys
- Are data correctly fitted by the sin2 ψ and similar methods?
- Liquidus surface projection of the Fe–Co–C ternary system in the iron-rich corner
- Prediction of thermodynamic activities in binary iron-based alloys using two-point Padé approximants
- Study of fatigue dislocation structures in [233] coplanar double-slip-oriented copper single crystals using SEM electronic channelling contrast
- Microstructures at high temperature of Fe-30 wt.% Cr-xC Alloys with x varying from 0 to 2 wt.%
- The effect of cooling rate on the microstructure and mechanical properties of Mg–Zn–Gd-based alloys
- The effect of thermal exposure on the microstructure and hardness of as-cast Mg–Zn–Al alloys with Sn addition
- Applied
- Deformation and fracture of Ti-base nanostructured composite
- Microstructure and some properties of FeCr25Co15 alloy subjected to plastic deformation by complex load
- Determination of the concentration dependent diffusion coefficient of nitrogen in expanded austenite
- Suitability of maraging steel weld cladding for repair of die casting tooling
- Catalytic performance of Fe-, Pd-, and Pd–Fe- mordenites in simulated hydrocarbon-selective catalytic reduction of N2O by methane in a model flue-gas from nitric acid plants
- Thermodynamic consideration and experimental study on the preparation of heat-treated hollow nickel fibres
- A model for the intrinsic kinetic parameters of the direct reduction of MoS2 with hydrogen
- Notification
- DGM News