Startseite A Comparative Spectral Study on the Interaction of Organic Dye Congo-Red with Selective Aqueous Micellar Media of CPC, Rhamnolipids and Saponin
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A Comparative Spectral Study on the Interaction of Organic Dye Congo-Red with Selective Aqueous Micellar Media of CPC, Rhamnolipids and Saponin

  • Aniruddha Pal , Amit Garain , Deep Chowdhury , Monohar Hossain Mondal und Bidyut Saha
Veröffentlicht/Copyright: 7. September 2020
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Tenside Surfactants Detergents
Aus der Zeitschrift Tenside Surfactants Detergents Band 57 Heft 5

Abstract

The present study is an investigation of the solubilising ability of natural and conventional surfactants saponin (sapindus saponin or reetha saponin), Rhamnolipids (RLs) and N-cetylpyridinium chloride (CPC) respectively via dye-surfactant interaction. The ionic dye Congo Red was examined by absorption spectroscopy method for the study. The dye interacted strongly with oppositely charged surfactant N-cetylpyridinium chloride in the pre-micellar concentration range and formed a stable dye-surfactant complex. The thermodynamic parameter, free energy change for all the systems was calculated at a constant temperature of 25°C. The ΔG0 value for N-cetylpyridinium chloride is found to be −33.269 kJ/mol while for saponin and rhamnolipids the values were −16.084 kJ/mol and −26.006 kJ/mol respectively. The values clearly indicate the efficiency of N-cetylpyridinium chloride surfactant compared to the other two surfactants. The present study aims to understand the dye solubilization in surfactant media in order to develop environmentally friendly, green and cost effective techniques.

Kurzfassung

Die vorliegende Studie ist eine Untersuchung zur Fähigkeit der natürlichen und konventionellen Tenside Saponin (Sapindus-Saponin oder Reetha-Saponin), Rhamnolipide (RL) und N-Cetylpyridiniumchlorid (CPC), einen organischen Farbstoff, aufgrund der Tensid-Farbstoff-Wechselwirkung zu solubilisieren. Für die Studie wurde der anionische Farbstoff Kongorot mittels Absorptionsspektroskopie untersucht. Der Farbstoff hatte starke Wechselwirkungen mit dem entgegengesetzt geladenen Tensid N-Cetylpyridiniumchlorid im vor-mizellaren Konzentrationsbereich und bildete einen stabilen Farbstoff-Tensid-Komplex. Der thermodynamische Parameter, die Änderung der Gibbs-Energie ΔG0, wurde für alle Systeme bei einer konstanten Temperatur von 25°C berechnet. Der ΔG0 Wert für N-Cetylpyridiniumchlorid beträgt −33,269 kJ/mol, die Werte für Saponin und Rhamnolipide sind −16,084 kJ/mol und −26,006 kJ/mol. Die Werte zeigen deutlich die Effizienz des N-Cetylpyridiniumchlorids im Vergleich zu den beiden anderen Tensiden. Die vorliegende Studie zielt darauf ab, die Farbstoff-Solubilisierung in Tensidmedien zu verstehen, um umweltfreundliche, grüne und kosteneffektive Techniken zu entwickeln.

Key words: Dye-surfactant interaction; congo red; bio-surfactant; saponin; rhamnolipids
Stichwörter: Farbstoff-Tensid-Wechselwirkung; Kongorot; Bio-Tensid; Saponin; Rhamnolipide
∗ Correspondence address, Prof. B. Saha, Homogeneous Catalysis Laboratory, Department of Chemistry, The University of Burdwan, Burdwan-713104, WB, India, Mobile: +919476341691, Tel.: +91-342-2533913 (O), E-Mail:
∗∗ Correspondence address, Dr. Monohar Hossain Mondal, Chemical Sciences Laboratory, Government General degree College, Singur, Hooghly 712409, WB, India, Mobile: +919475337890, Tel.: +91-33-2630-0126 (O)., E-Mail:

Aniruddha Pal was born in Burdwan, India in 1996. He is currently working as a JRF in the department of chemistry Burdwan University, WB, India.

Amit Garain was born in Birbhum, India in 1995. He is currently working as Chemist in the NTPC, Govt. of India.

Deep Chowdhury is an ex-student he recently obtained his MSc. degree from Burdwan university. Deep was also a project student of Homogeneous Catalysis Laboratory of Burdwan University.

Dr. Monohar Hossain Mondal was born in Kalna, Burdwan in 1991. He has completed his PhD degree from The University of Burdwan in 2017 at the Bioremediation Laboratory (The University of Burdwan), he has been appointed as WBES Officer by the Government of West Bengal and presently working as Assistant Professor in Chemistry at Govt. General Degree College at Singur, Hooghly, WB, India. He has published more than 15 international peer reviewed scientific articles.

Bidyut Saha was born in Birbhum, WB, India in 1975. He obtained his Ph.D. degree from Visva Bharati University, India in 2007. He was a visiting scientist between 2009–2010 in the Department of Chemistry, UBC, Vancouver, Canada. Dr Saha is presently working as an Associate Professor in the Department of Chemistry, The University of Burdwan, India. His area of interests is bioremediation of toxic metals, micellar catalysis and inorganic reaction mechanisms. He has published 80 papers in international journals.

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Received: 2019-10-05
Accepted: 2020-06-08
Published Online: 2020-09-07
Published in Print: 2020-09-16

© 2020, Carl Hanser Publisher, Munich

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Hygiene
  4. The Antimicrobial Activity of Herbal Soaps Against Selected Human Pathogens
  5. Detergent Properties of Coconut Oil Derived N-Acyl Prolinate Surfactant and the In silico Studies on its Effectiveness Against SARS-CoV-2 (COVID-19)
  6. Novel Surfactants
  7. Cationic Bola Form Metallosurfactants Based on Isothiouronium, Synthesis and Anti-Microbial Activity
  8. Application
  9. Effect of Inorganic Salt on Foam Properties of Nanoparticle and Surfactant Systems
  10. Effects of Surfactant Compounding on the Wettability Characteristics of Zhaozhuang Coal: Experiment and Molecular Simulation
  11. A Comparative Spectral Study on the Interaction of Organic Dye Congo-Red with Selective Aqueous Micellar Media of CPC, Rhamnolipids and Saponin
  12. Synthesis
  13. Development of a Gypsum Foaming Agent Based on Alkyl Polyglucosides
  14. Synthesis and Properties of Amide Gemini Surfactants
  15. Study of the Synthesis of Branched Chain Alkyl Polyglucosides from Guerbet Alcohol in an Acid/Phase Transfer Catalyst System and Their Properties
  16. Short Communication/Physical Chemistry
  17. Study of Methionine and Cumene Hydroperoxide Reaction Kinetics in the Presence of Nonionic Surfactant
https://doi.org/10.3139/113.110700
Schlagwörter für diesen Artikel
Dye-surfactant interaction; congo red; bio-surfactant; saponin; rhamnolipids

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Hygiene
  4. The Antimicrobial Activity of Herbal Soaps Against Selected Human Pathogens
  5. Detergent Properties of Coconut Oil Derived N-Acyl Prolinate Surfactant and the In silico Studies on its Effectiveness Against SARS-CoV-2 (COVID-19)
  6. Novel Surfactants
  7. Cationic Bola Form Metallosurfactants Based on Isothiouronium, Synthesis and Anti-Microbial Activity
  8. Application
  9. Effect of Inorganic Salt on Foam Properties of Nanoparticle and Surfactant Systems
  10. Effects of Surfactant Compounding on the Wettability Characteristics of Zhaozhuang Coal: Experiment and Molecular Simulation
  11. A Comparative Spectral Study on the Interaction of Organic Dye Congo-Red with Selective Aqueous Micellar Media of CPC, Rhamnolipids and Saponin
  12. Synthesis
  13. Development of a Gypsum Foaming Agent Based on Alkyl Polyglucosides
  14. Synthesis and Properties of Amide Gemini Surfactants
  15. Study of the Synthesis of Branched Chain Alkyl Polyglucosides from Guerbet Alcohol in an Acid/Phase Transfer Catalyst System and Their Properties
  16. Short Communication/Physical Chemistry
  17. Study of Methionine and Cumene Hydroperoxide Reaction Kinetics in the Presence of Nonionic Surfactant
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