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Study of Methionine and Cumene Hydroperoxide Reaction Kinetics in the Presence of Nonionic Surfactant

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Published/Copyright: September 7, 2020
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 57 Issue 5

Abstract

The kinetics of the reaction methionine+cumene hydroperoxide in the presence of nonionic surfactant was studied both in the pre-micellar and post-micellar regions at different temperatures by iodometry. It was established that the rate of the methionine + cumene hydroperoxide reaction depends on the molecular/ionic/micellar form of surfactant in the reaction system. In the post-micellar region the rate of methionine+cumene hydroperoxide reaction slows down due to solubilization of the reacting substances in the micelles. Quantification of solubilization of cumene hydroperoxide and methionine in the micelles has been studied by HPLC analysis. It was obtained that about 30% of cumene hydroperoxide, which is more hydrophobic than methionine, is solubilized in the micelles, as a result the concentration of cumene hydroperoxide in the reaction environment decreases and the rate of reaction in the post-micellar region also decreases. Based on the kinetic studies the reaction rate constant was determined and the value of activation energy was obtained.

Kurzfassung

Die Kinetik der Reaktion von Methionin und Cumolhydroperoxid in Gegenwart von nichtionischem Tensid wurde sowohl im prä- als auch im post-mizellaren Bereich bei unterschiedlichen Temperaturen iodometrisch untersucht. Es wurde festgestellt, dass die Geschwindigkeit der Reaktion von Methionin und Cumolhydroperoxid von der molekularen/ionischen/micellaren Form des Tensids im Reaktionssystem abhängt. Im post-mizellaren Bereich verlangsamt sich die Geschwindigkeit der Methionin- und Cumolhydroperoxid-Reaktion aufgrund der Solubilisierung der reagierenden Substanzen in den Mizellen. Die Quantifizierung der Solubilisierung von Cumolhydroperoxid und Methionin in den Mizellen wurde mittels HPLC-Analyse untersucht. Es wurde festgestellt, dass etwa 30% des Cumolhydroperoxids, das hydrophober als Methionin ist, in den Micellen gelöst werden, wodurch die Konzentration von Cumolhydroperoxid in der Reaktionsumgebung abnimmt und die Reaktionsgeschwindigkeit im post-micellaren Bereich ebenfalls abnimmt. Auf der Grundlage der kinetischen Studien wurde die Reaktionsgeschwindigkeitskonstante bestimmt und der Wert der Aktivierungsenergie ermittelt.

Key words: Micellar catalysis; nonionic surfactant; cumene hydroperoxide; methionine; kinetics
Stichwörter: Mizellare Katalyse; nichtionisches Tensid; Cumolhydroperoxid; Methionin; Kinetik
∗ Correspondence address, Dr. Lusine Harutyunyan, Department of Chemistry, Armenian National Agrarian University, Teryan 74, 0009 Yerevan, Armenia, Tel.: +37491519144, E-Mail:

Lusine R. Harutyunyan – Doctor of Chemistry, working in the field of surfactants solutions. The aim of her scientific interests includes investigation of colloidal and physicochemical properties of surfactant solutions in the presence of biologically active additives, as well as studies the unique behavior of micellar systems.

Gohar G. Petrosyan – PhD, Associate Professor in Department of Chemistry of Yerevan State University. During many years she has working in establishing of kinetic behavior and mechanism of different reactions.

Romik S. Harutyunyan – Prof., Doctor of Chemistry. His scientific interest includes all aspects of surfactants chemistry- physicochemical and colloidal studies of properties, adsorption at interface, synthesis of surfactant-modified sorbents and study of their applicability, micellar catalysis, application aspects of surfactants et al.

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Received: 2020-04-30
Accepted: 2020-06-23
Published Online: 2020-09-07
Published in Print: 2020-09-16

© 2020, Carl Hanser Publisher, Munich

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https://doi.org/10.3139/113.110703
Keywords for this article
Micellar catalysis; nonionic surfactant; cumene hydroperoxide; methionine; kinetics

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Hygiene
  4. The Antimicrobial Activity of Herbal Soaps Against Selected Human Pathogens
  5. Detergent Properties of Coconut Oil Derived N-Acyl Prolinate Surfactant and the In silico Studies on its Effectiveness Against SARS-CoV-2 (COVID-19)
  6. Novel Surfactants
  7. Cationic Bola Form Metallosurfactants Based on Isothiouronium, Synthesis and Anti-Microbial Activity
  8. Application
  9. Effect of Inorganic Salt on Foam Properties of Nanoparticle and Surfactant Systems
  10. Effects of Surfactant Compounding on the Wettability Characteristics of Zhaozhuang Coal: Experiment and Molecular Simulation
  11. A Comparative Spectral Study on the Interaction of Organic Dye Congo-Red with Selective Aqueous Micellar Media of CPC, Rhamnolipids and Saponin
  12. Synthesis
  13. Development of a Gypsum Foaming Agent Based on Alkyl Polyglucosides
  14. Synthesis and Properties of Amide Gemini Surfactants
  15. Study of the Synthesis of Branched Chain Alkyl Polyglucosides from Guerbet Alcohol in an Acid/Phase Transfer Catalyst System and Their Properties
  16. Short Communication/Physical Chemistry
  17. Study of Methionine and Cumene Hydroperoxide Reaction Kinetics in the Presence of Nonionic Surfactant
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