Micellar Encapsulation of Some Polycyclic Aromatic Hydrocarbons by Glucose Derived Non-Ionic Gemini Surfactants in Aqueous Medium
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Lalit Sharma
Abstract
Novel glucose-based non-ionic gemini surfactants consisting of two sugar head groups, two hydrophobic tails having chain length of C8, C10, C12, C14, C16, C18 and –CH2-C6H4-CH2– as a rigid spacer were synthesized and investigated for their micellar encapsulation properties. The head groups of the geminis consist of glucose entities (with reducing function blocked in cyclic acetal group) connected through C-6 to tertiary amines. These surfactants were explored for micellar encapsulation of some polynuclear aromatic hydrocarbons (PAHs) viz. fluorene, anthracene, triptycene and pyrene in 20% ethanol–water mixture. Micellar studies revealed that PAHs were encapsulated in the sequence fluorene > anthracene > triptycene > pyrene and the better efficiency of gemini surfactant was dependent on longer alkyl tail but lesser HLB value.
Kurzfassung
Neue, auf Glukose basierende, nichtionische Gemini-Tenside wurden synthetisiert und hinsichtlich ihrer mizellaren Verkapselung untersucht. Die neuen Gemini-Tenside bestehen aus zwei Zucker-Kopfgruppen und zwei hydrophoben Alkylketten der Längen C8, C10, C12, C14, C16, C18, die über einen –CH2-C6H4-CH2– -Spacer verbunden sind. Die Kopfgruppen der Gemini-Tenside bestehen aus Glucose-Einheiten (mit reduzierter Funktion blockiert in der cyclischen Acetal-Gruppe), die über C-6 an die tertiären Amine gebunden sind. Diese Tenside wurden untersucht hinsichtlich der Verkapselung von bestimmten polyzyklischen aromatischen Kohlenwasserstoffen [PAKs] (Fluoren, Anthracen, Triptycen und Pyren) in Mizellen aus einer wässrigen Lösung mit 20% Ethanol. Die PAKs ließen sich in der Reihenfolge Fluoren > Anthracen > Triptycen > Pyren verkapseln. Die höhere Wirksamkeit der Gemini-Tenside hing mehr von der Länge der Alkylketten ab als von dem geringeren HLB-Wert.
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© 2014, Carl Hanser Publisher, Munich
Artikel in diesem Heft
- Contents/Inhalt
- Contents
- Abstracts
- Abstracts
- Special Theme: Green Surfactants – Synthesis, Properties, Performance and Application
- Novel Cationic Gemini Surfactants and Methods for Determination of Their Antimicrobial Activity – Review
- Sophorolipids Synthesized Using Non-Traditional Oils with Glycerol and Studies on Their Surfactant Properties with Synthetic Surfactant
- Rhamnolipids Production by a Pseudomonas eruginosa LBI Mutant: Solutions and Homologs Characterization
- Application of Biosurfactant Surfactin on Copper Ion Removal from Sand Surfaces with Continuous Flushing Technique
- Synthesis and Properties of a Series of CO2 Switchable Gemini Imidazolium Surfactants
- Phase Behavior and Solubilization of Microemulsion Systems Containing Imidazolium Type Surfactant CnmimBr and Butyric Acid as Cosurfactant
- Synthesis and Solution Properties of New Polysiloxane Bola Surfactants Containing Carbohydrate
- Syntheses and Properties of Novel Ionic Twin-tail Trisiloxane Surfactants
- Micellar Encapsulation of Some Polycyclic Aromatic Hydrocarbons by Glucose Derived Non-Ionic Gemini Surfactants in Aqueous Medium
- Environmental Chemistry
- Removal of Non-Ionic Surfactants in an Activated Sludge Sewage Treatment Plant
- Cleaning Technology
- Impact of Artificial UV-Light on Optical and Protective Effects of Cotton After Washing with Detergent Containing Fluorescent Compounds
- Simulating Consumer-Like Air Drying of Dishes via Thermal Drying Process
Artikel in diesem Heft
- Contents/Inhalt
- Contents
- Abstracts
- Abstracts
- Special Theme: Green Surfactants – Synthesis, Properties, Performance and Application
- Novel Cationic Gemini Surfactants and Methods for Determination of Their Antimicrobial Activity – Review
- Sophorolipids Synthesized Using Non-Traditional Oils with Glycerol and Studies on Their Surfactant Properties with Synthetic Surfactant
- Rhamnolipids Production by a Pseudomonas eruginosa LBI Mutant: Solutions and Homologs Characterization
- Application of Biosurfactant Surfactin on Copper Ion Removal from Sand Surfaces with Continuous Flushing Technique
- Synthesis and Properties of a Series of CO2 Switchable Gemini Imidazolium Surfactants
- Phase Behavior and Solubilization of Microemulsion Systems Containing Imidazolium Type Surfactant CnmimBr and Butyric Acid as Cosurfactant
- Synthesis and Solution Properties of New Polysiloxane Bola Surfactants Containing Carbohydrate
- Syntheses and Properties of Novel Ionic Twin-tail Trisiloxane Surfactants
- Micellar Encapsulation of Some Polycyclic Aromatic Hydrocarbons by Glucose Derived Non-Ionic Gemini Surfactants in Aqueous Medium
- Environmental Chemistry
- Removal of Non-Ionic Surfactants in an Activated Sludge Sewage Treatment Plant
- Cleaning Technology
- Impact of Artificial UV-Light on Optical and Protective Effects of Cotton After Washing with Detergent Containing Fluorescent Compounds
- Simulating Consumer-Like Air Drying of Dishes via Thermal Drying Process
