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Preparation and Characterization of a Phosphorous Free and Non-Nitrogen Antiscalant in Industrial Cooling Systems

  • C. Fu , Y. Zhou , J. Huang , H. Xie , G. Liu , W. Wu and W. Sun
Published/Copyright: April 5, 2013
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 48 Issue 1

Abstract

A novel nonpolluting type of calcium phosphate and iron(III) antiscalant MCn was synthesized. The observation shows that MCn causes a disordered calcium phosphate. Furthermore, both calcium phosphate and iron(III) inhibition increase with increasing degree of polymerization of MCn from 5 to 13, and the dosage of MCn plays an important role on calcium phosphate and iron(III) inhibition. Inhibition mechanism is proposed the interactions between calcium or iron ions and polyethylene glycol (PEG) are the fundamental impetus to restrain the formation of the scale in cooling water systems.

Kurzfassung

Ein neuer umweltfreundlicher Typ eines Calciumphosphat- und Eisen(III)-Inhibitors MCn wurde synthetisiert. Die Untersuchung zeigte, dass MCn fehlgeordnetes Calciumphosphat verursacht. Darüberhinaus steigt sowohl die Calciumphosphat- als auch die Eisen(III)-Inhibierung mit zunehmender Polymersiation von MCn mit n = 5 bis 13. Die Dosierung von MCn ist für die Calciumphosphat- und Eisen(III)-Inhibierung auch sehr wichtig. Für den Inhibierungsmechanismus wird vorgeschlagen, dass die Wechselwirkung zwischen Calcium- oder Eisenionen mit Polyethylengylkol der entscheidende Impuls für die Beschränkung der Kesselsteinbildung in Kühlwassersystemen ist.

Key words:: Phosphorous free antiscalant; calcium phosphate; disperse iron(III)
Stichwörter:: Phosphorfreier Kesselsteininhibitor; Calciumphosphat; disperses Eisen(III)
∗ Prof. Yuming Zhou, School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China, Tel.: 86-25-52090617. E-Mail:

Change Fu was born in 1971. She is a doctoral student at Southeast University. She obtained her master degree in Hunan University. Her main field of research is applications of water soluble polymers in industrial water systems and green chemical.

Prof. Yuming Zhou was born in 1964. He graduated from Nanjing University in 1986. He obtained his PhD in Department of Biomedical Southeast University. His research interests lie in organic material, fine chemicals and environmental protection. At the moment is associate dean of the School of Chemistry and Chemical Engineering Southeast University.

Jingyi Huang was born in 1976. She received his bachelor degree in applied chemical from Southeast University in 2006. Her main scientific interest has been the synthesis and properties of environment friendly materials.

Hongtao Xie was born in 1983. He received his bachelor degree in applied chemical from Southeast University in 2008. His main scientific interest has been the synthesis and properties of environment friendly materials.

Guangqing Liu was born in 1979. He received his bachelor degree in applied chemical from Northeast University in 2007. His main scientific interest has been the synthesis and properties of environment friendly materials.

Wei Sun was born in 1981. He received his bachelor degree in applied chemical from Nanjing University in 2004. He is now working at Jiangsu Jianghai Chemical Co., Ltd., Changzhou China. His main field of research is synthesis and application of surfactants.

Wendao Wu was born in 1985. He received his bachelor degree in applied chemical from Southeast University in 2008. He is now working at Jiangsu Jianghai Chemical Co., Ltd., Changzhou. His field of research is synthesis and application of surfactants.

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Received: 2010-06-20
Published Online: 2013-04-05
Published in Print: 2011-01-01

© 2011, Carl Hanser Publisher, Munich

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  18. Environmental Chemistry
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  21. Preparation and Characterization of a Phosphorous Free and Non-Nitrogen Antiscalant in Industrial Cooling Systems
  22. Preparation and Characterization of Pillared Derivatives from δ-Layered Sodium Disilicate and their Tribological Properties in Liquid Paraffin
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https://doi.org/10.3139/113.110105
Keywords for this article
Phosphorous free antiscalant; calcium phosphate; disperse iron(III)

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Editorial
  6. Rückblick auf zwei erfolgreiche Jahre 2009/2010
  7. Application
  8. Surface Activity and Adsorption Properties of New Perfluorinated Carbohydrate Surfactants
  9. Novel Surfactants
  10. Study of Glycerol Residue as a Carbon Source for Production of Rhamnolipids by Pseudomonas aeruginosa (ATCC 10145)
  11. Study of CLSI-M44-A Disk Diffusion Method for Determining the Susceptibility of Candida Species against Novel Complexes Derived from Copper Stearate with 2-Amino Benzothiazoles
  12. European Detergents Conference
  13. Bicontinuous Microemulsion as Reaction Medium for ω-Transaminase Catalysed Biotransformations
  14. Physical Chemistry
  15. SAXS Study on Azithromycin Loaded Nonionic Microemulsions
  16. Effects of Alkaline Cations on Self-assembly of Cetylpyridinium Surfactants
  17. Influence of Surfactants on Release of Chlorhexidine from Hydrogels
  18. Environmental Chemistry
  19. Influence of Surfactants on the Performance of Calcium Phosphate Scale Inhibitors
  20. Technical Chemistry
  21. Preparation and Characterization of a Phosphorous Free and Non-Nitrogen Antiscalant in Industrial Cooling Systems
  22. Preparation and Characterization of Pillared Derivatives from δ-Layered Sodium Disilicate and their Tribological Properties in Liquid Paraffin
  23. Synthesis
  24. An Efficient and Mild Procedure for the Preparation of Aldonic Acids via Oxidation of D-Sucrose by Employing N-Bromophthalimide Oxidant and Micellar System
  25. Synthesis and Properties of Some N-Acylethylenediamine Triacetic Acid Chelating Surfactants
  26. Conference and Meeting Report
  27. Sixth European Detergents Conference Report
  28. GDCh-Intensive Course Surfactants: Detergents, Cosmetics, Technical Applications
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