Startseite Structure and properties of 2-[(E)-2-(4-dipropylaminophenyl)-1-ethenyl]-1,3,3-trimethyl-3H-indolium chloride
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Structure and properties of 2-[(E)-2-(4-dipropylaminophenyl)-1-ethenyl]-1,3,3-trimethyl-3H-indolium chloride

  • Martina Lešková EMAIL logo , Yaroslav Bazel , Marcel Torok und Yaroslav Studenyak
Veröffentlicht/Copyright: 9. Januar 2013
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Chemical Papers
Aus der Zeitschrift Chemical Papers Band 67 Heft 4

Abstract

The structure of styryl dye, 2-[(E)-2-(4-dipropylaminophenyl)-1-ethenyl]-1,3,3-trimethyl-3H-indolium chloride (I), was investigated using methods such as UV-VIS, fluorescence spectroscopy, and NMR (1H, 13C, APT, HMQC, COSY) and also by examining its electrochemical properties. A study of the acid-base properties revealed the existence of three different forms of the dye. The mechanisms of protolysis and hydrolysis are discussed. The reagent exists in a reactive single-charged form I + over a wide range of acidity (pH 4–11). The optimum analytical wavelength of the singlecharged form is 550 nm, where the molar absorptivity is 5.51 × 104 L mol−1 cm−1. The values of the optimum analytical wavelength and molar absorptivity of the protolysed and hydrolysed forms are: λ max(I-H2+) = 380 nm, ɛ(I-H2+) = 2.01 × 104 L mol−1 cm−1; λ max(I-OH) = 320 nm, ɛ(I-OH) = 1.12 × 104 L mol−1 cm−1. A theoretical study of the spectral and chemical properties of I was carried out by performing quantum chemical calculations.

Keywords: 2-[(E)-2-(4-dipropylaminophenyl)-1-ethenyl]-1,3,3-trimethyl-3H-indolium chloride; structure; properties

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Published Online: 2013-1-9
Published in Print: 2013-4-1

© 2012 Institute of Chemistry, Slovak Academy of Sciences

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https://doi.org/10.2478/s11696-012-0290-8
Schlagwörter für diesen Artikel
2-[(E)-2-(4-dipropylaminophenyl)-1-ethenyl]-1,3,3-trimethyl-3H-indolium chloride; structure; properties

Artikel in diesem Heft

  1. Identification of carbohydrate isomers in flavonoid glycosides after hydrolysis by hydrophilic interaction chromatography
  2. Preparation of a new metallomicelle catalyst for the hydrolysis of bis(4-nitrophenyl) phosphate
  3. Synthesis and catalytic performance of MCM-41 modified with tetracarboxylphthalocyanine
  4. Comparison of polymeric and ceramic membranes performance in the process of micellar enhanced ultrafiltration of cadmium(II) ions from aqueous solutions
  5. Pertraction of cadmium and zinc ions using a supported liquid membrane impregnated with different carriers
  6. Effect of lentil and bean flours on rheological and baking properties of wheat dough
  7. Preparation, structural characterisation, and magnetic properties of [Cu(men)2][Cu2Cd2Cl2(CN)6] (men = N-methylethane-1,2-diamine)
  8. Structure and properties of 2-[(E)-2-(4-dipropylaminophenyl)-1-ethenyl]-1,3,3-trimethyl-3H-indolium chloride
  9. Properties of water-soluble carboxymethyl chitosan film modified by hydrophobic poly(propylene glycol)
  10. Characterisation of hydroxyapatite surface modified by poly(ethylene glycol) and poly(hydroxyethyl methacrylate) grafting
  11. Synthesis and keto-enol tautomerism of ethyl 4-oxo-3,4-dihydro-1H-pyrano[3,4-b]quinoline-3-carboxylate
  12. An efficient method for the preparation of benzyl γ-ketohexanoates
  13. Micelle nano-reactors as mediators of water-insoluble ligand complexation with Cu(II) ions in aqueous medium
  14. Reactivity of base catalysed hydrolysis of 2-pyridinylmethylene-8-quinolinyl-Schiff base iron(II) iodide complexes: solvent effects
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