Preparation of a new metallomicelle catalyst for the hydrolysis of bis(4-nitrophenyl) phosphate
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Jia-Qing Xie
,
Ci Li
Abstract
A new metallomicellar system containing cerium(III), a macrocylic polyamine ligand, and the nonionic surfactant Brij35(polyoxyethylene(23) lauryl ether) was prepared and used as a catalyst in the hydrolysis of bis(4-nitrophenyl) phosphate (BNPP). Catalytic rate of the BNPP hydrolysis was measured kinetically using the UV-VIS spectrophotometric method. The results indicate that the metallomicellar system has relatively high stability and excellent catalytic function in the BNPP hydrolysis; also, the reaction rate of the BNPP catalytic hydrolysis increased by a factor of ca. 1 × 1010 compared to the BNPP spontaneous hydrolysis due to the catalytic effect of the active species and the local concentration effect of the micelles in the metallomicellar system. Experimental results also showed that the mono-hydroxy complex containing the macrocyclic polyamine ligand and cerium(III) is the real active species in the BNPP catalytic hydrolysis, and that the micelles provide a useful catalytic environment for the reaction. On basis of the research results, the reaction mechanism of BNPP catalytic hydrolysis has been proposed.
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© 2012 Institute of Chemistry, Slovak Academy of Sciences
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Articles in the same Issue
- Identification of carbohydrate isomers in flavonoid glycosides after hydrolysis by hydrophilic interaction chromatography
- Preparation of a new metallomicelle catalyst for the hydrolysis of bis(4-nitrophenyl) phosphate
- Synthesis and catalytic performance of MCM-41 modified with tetracarboxylphthalocyanine
- Comparison of polymeric and ceramic membranes performance in the process of micellar enhanced ultrafiltration of cadmium(II) ions from aqueous solutions
- Pertraction of cadmium and zinc ions using a supported liquid membrane impregnated with different carriers
- Effect of lentil and bean flours on rheological and baking properties of wheat dough
- Preparation, structural characterisation, and magnetic properties of [Cu(men)2][Cu2Cd2Cl2(CN)6] (men = N-methylethane-1,2-diamine)
- Structure and properties of 2-[(E)-2-(4-dipropylaminophenyl)-1-ethenyl]-1,3,3-trimethyl-3H-indolium chloride
- Properties of water-soluble carboxymethyl chitosan film modified by hydrophobic poly(propylene glycol)
- Characterisation of hydroxyapatite surface modified by poly(ethylene glycol) and poly(hydroxyethyl methacrylate) grafting
- Synthesis and keto-enol tautomerism of ethyl 4-oxo-3,4-dihydro-1H-pyrano[3,4-b]quinoline-3-carboxylate
- An efficient method for the preparation of benzyl γ-ketohexanoates
- Micelle nano-reactors as mediators of water-insoluble ligand complexation with Cu(II) ions in aqueous medium
- Reactivity of base catalysed hydrolysis of 2-pyridinylmethylene-8-quinolinyl-Schiff base iron(II) iodide complexes: solvent effects
