Home Thermally stable oligomer—Metal complexes based on oligo-ortho-aminophenol and oligophenylazomethinephenol
Article
Licensed
Unlicensed Requires Authentication

Thermally stable oligomer—Metal complexes based on oligo-ortho-aminophenol and oligophenylazomethinephenol

  • H. Mart EMAIL logo , M. Koç , V. Muradoğlu and H. Yürük
Published/Copyright: August 1, 2006
Become an author with De Gruyter Brill
Author Information
Chemical Papers
From the journal Chemical Papers Volume 60 Issue 4

Abstract

The oligo-ortho-aminophenol was synthesized by the oxidative polycondensation of ortho-aminophenol with air oxygen. The oligophenylazomethinephenol was synthesized by the condensation of aniline with oligosalicylaldehyde. Metal complexes of these oligomers with Cu(II), Co(II), Zn(II), and Ni(II) were synthesized and characterized. Based on the results of thermogravimetric analysis, synthesized oligomer—metal complexes were more stable against heat and thermooxidative decomposition than some polymeric Schiff bases and polymer—metal complexes. Additionally, the presence of metal ions increased the thermal stability of oligo-ortho-aminophenol, while the thermal stability of oligophenylazomethinephenol was lowered.

Keywords: oligomer—metal complexes; oligophenols; thermal stability; polymer

[1] Kaliyappan, T. and Kannan, P., Prog. Polym. Sci. 25, 343 (2000). http://dx.doi.org/10.1016/S0079-6700(00)00005-810.1016/S0079-6700(00)00005-8Search in Google Scholar

[2] Gupta, K. C., Abdulkadir, H. K., and Chand, S., J. Macromol. Sci., Part A: Pure Appl. Chem. 40, 475 (2003). http://dx.doi.org/10.1081/MA-12001988710.1081/MA-120019887Search in Google Scholar

[3] Kaliyappan, T., Raman, A., and Kannan, P., J. Macromol. Sci., Part A: Pure Appl. Chem. 36, 517 (1999). http://dx.doi.org/10.1081/MA-10010154610.1081/MA-100101546Search in Google Scholar

[4] Kaya, I., Demir, H. Ö., and Vilayetoğlu, A. R., Synth. Met. 126, 183 (2002). http://dx.doi.org/10.1016/S0379-6779(01)00501-X10.1016/S0379-6779(01)00501-XSearch in Google Scholar

[5] Kaya, I., Vilayetoğlu, A. R., and Topak, H., J. Appl. Polym. Sci. 85, 2004 (2002). http://dx.doi.org/10.1002/app.1081510.1002/app.10815Search in Google Scholar

[6] Gad, A. M., El-Dissouky, A., Mansour, E. M., and El-Maghraphy, A., Polym. Degrad. Stab. 68, 153 (2000). http://dx.doi.org/10.1016/S0141-3910(99)00178-010.1016/S0141-3910(99)00178-0Search in Google Scholar

[7] Gad, A. M., El-Dissouky, A., Mansour, E. M., and El-Maghraphy, A., Polym. Degrad. Stab. 71, 267 (2001). http://dx.doi.org/10.1016/S0141-3910(00)00172-510.1016/S0141-3910(00)00172-5Search in Google Scholar

[8] Nicemol, S., Bini, G., and Beena, M., Polym. Degrad. Stab. 60, 371 (1998). http://dx.doi.org/10.1016/S0141-3910(97)00095-510.1016/S0141-3910(97)00095-5Search in Google Scholar

[9] Thamizharasi, S., Reddy, A. V. R., and Balasubramanian, S., Eur. Polym. J. 34, 503 (1998). http://dx.doi.org/10.1016/S0014-3057(97)00120-110.1016/S0014-3057(97)00120-1Search in Google Scholar

[10] Mart, H. and Vilayetoğlu, A. R., Polym. Degrad. Stab. 83, 255 (2004). http://dx.doi.org/10.1016/S0141-3910(03)00270-210.1016/S0141-3910(03)00270-2Search in Google Scholar

[11] Kaya, I. and Cihangiroğlu, N., J. Polym. Res. 1, 37 (2004). http://dx.doi.org/10.1023/B:JPOL.0000021746.50347.3410.1023/B:JPOL.0000021746.50347.34Search in Google Scholar

[12] Kaya, I. and Koyuncu, S., Polymer 44, 7299 (2003). http://dx.doi.org/10.1016/j.polymer.2003.09.01110.1016/j.polymer.2003.09.011Search in Google Scholar

[13] Ragimov, A. V., Mamedov, B. A., and Gasanova, S. G., Polym. Int. 43, 343 (1997). http://dx.doi.org/10.1002/(SICI)1097-0126(199708)43:4<343::AID-PI749>3.0.CO;2-310.1002/(SICI)1097-0126(199708)43:4<343::AID-PI749>3.0.CO;2-3Search in Google Scholar

[14] Kaya, I., Vilayetoğlu, A. R., and Mart, H., Polymer 42, 4859 (2001). http://dx.doi.org/10.1016/S0032-3861(00)00883-110.1016/S0032-3861(00)00883-1Search in Google Scholar

[15] Kaliyappan, T., Swaminathan, C. S., and Kannan, P., Eur. Polym. J. 33, 59 (1997). http://dx.doi.org/10.1016/S0014-3057(96)00118-810.1016/S0014-3057(96)00118-8Search in Google Scholar

[16] Stuart, B., Modern Infrared Spectroscopy, p. 71. Wiley, England, 1996. Search in Google Scholar

Published Online: 2006-8-1
Published in Print: 2006-8-1

© 2006 Institute of Chemistry, Slovak Academy of Sciences

Articles in the same Issue

  1. Influence of medium on the kinetics of oxidation of iron(II) ion with t-butyl hydroperoxide
  2. Synthesis of new thiazolo[2,3-b]pyrimidine derivatives of pharmaceutical interest
  3. Enthalpic analysis of the CaTiSiO5 system
  4. Kinetic, spectrophotometric determination of nanogram levels of manganese(II) using catalytic azo dye—potassium periodate—1,10-phenanthroline system
  5. Application of a ternary complex of tungsten(VI) with 4-nitrocatechol and thiazolyl blue for extraction-spectrophotometric determination of tungsten
  6. Determination of risperidone at picogram level in human urine by luminol—H2O2 chemiluminescence
  7. Electrochemical dissolution of chalcopyrite studied by voltammetry of immobilized microparticles
  8. Colon tissue concentrations of copper, iron, selenium, and zinc in colorectal carcinoma patients
  9. Structure of tetrakis(pyridinioacetate) neodymium(III) tetrahydrate perchlorate
  10. Thermally stable oligomer—Metal complexes based on oligo-ortho-aminophenol and oligophenylazomethinephenol
  11. Adsorption of SO2 on alumina
  12. One-pot, three-component synthesis of secondary amines and trisubstituted hydrazines from ketones
  13. Synthesis of α,α′-bis(R-benzylidene)cycloalkanones catalyzed by potassium hydrogen sulfate under solvent-free conditions
  14. Electrical conductivity of the molten KF—K2TaF7 system
  15. New substituted mono-and bis(imidazolyl)pyridines and their application in nitroaldolisation reaction
https://doi.org/10.2478/s11696-006-0054-4
Keywords for this article
oligomer—metal complexes; oligophenols; thermal stability; polymer

Articles in the same Issue

  1. Influence of medium on the kinetics of oxidation of iron(II) ion with t-butyl hydroperoxide
  2. Synthesis of new thiazolo[2,3-b]pyrimidine derivatives of pharmaceutical interest
  3. Enthalpic analysis of the CaTiSiO5 system
  4. Kinetic, spectrophotometric determination of nanogram levels of manganese(II) using catalytic azo dye—potassium periodate—1,10-phenanthroline system
  5. Application of a ternary complex of tungsten(VI) with 4-nitrocatechol and thiazolyl blue for extraction-spectrophotometric determination of tungsten
  6. Determination of risperidone at picogram level in human urine by luminol—H2O2 chemiluminescence
  7. Electrochemical dissolution of chalcopyrite studied by voltammetry of immobilized microparticles
  8. Colon tissue concentrations of copper, iron, selenium, and zinc in colorectal carcinoma patients
  9. Structure of tetrakis(pyridinioacetate) neodymium(III) tetrahydrate perchlorate
  10. Thermally stable oligomer—Metal complexes based on oligo-ortho-aminophenol and oligophenylazomethinephenol
  11. Adsorption of SO2 on alumina
  12. One-pot, three-component synthesis of secondary amines and trisubstituted hydrazines from ketones
  13. Synthesis of α,α′-bis(R-benzylidene)cycloalkanones catalyzed by potassium hydrogen sulfate under solvent-free conditions
  14. Electrical conductivity of the molten KF—K2TaF7 system
  15. New substituted mono-and bis(imidazolyl)pyridines and their application in nitroaldolisation reaction
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 27.11.2025 from https://www.degruyterbrill.com/document/doi/10.2478/s11696-006-0054-4/pdf
Scroll to top button