Structure of tetrakis(pyridinioacetate) neodymium(III) tetrahydrate perchlorate
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Y. Song
,
X. Yao
Abstract
The structure of tetrakis(pyridinioacetate) neodymium(III) tetrahydrate perchlorate, [Nd(pyBET)4 · 4H2O](ClO4)3, is reported. The neodymium atom is eight-coordinate dodecahedrally distorted polyhedron. The molecule consists of discrete [Nd(pyBET)4 · 4H2O]3+ cation and perchlorate anions held by ionic electrostatic force.
[1] Jiao, T. Q., Wu, J. G., Zeng, F. L., Fu, Y. L., and Deng, R. W., Synth. React. Inorg. Met.-Org. Chem. 29, 725 (1999). Search in Google Scholar
[2] Wu, J. Q., Song, Y. M., Deng, R. W., and Chen, Z. N., Chem. Pap. 53, 210 (1999). Search in Google Scholar
[3] Jin, T. Z., Gao, S., Huang, C. H., Xu, G. X., and Yang, G. D., J. Chin. Rare Earth Soc. 5, 1 (1987). Search in Google Scholar
[4] Jin, T. Z., Sheng, X. T., Xu, G. X., Ma, Z. S., and Si, N. C., J. Chin. Rare Earth Soc. 8, 193 (1990). Search in Google Scholar
[5] Csöregh, I., Czugler, M., Kierkegaard, P., Legendziewicz, J., and Huskowska, E., Acta Chem. Scand. 43, 735 (1989). http://dx.doi.org/10.3891/acta.chem.scand.43-073510.3891/acta.chem.scand.43-0735Search in Google Scholar
[6] Csöregh, I., Kierkegaard, P., Legendziewicz, J., and Huskowska, E., Acta Chem. Scand. 41, 453 (1987). Search in Google Scholar
[7] Chen, X. M. and Mak, T. C. W., Polyhedron 11, 2567 (1992). http://dx.doi.org/10.1016/S0277-5387(00)83579-210.1016/S0277-5387(00)83579-2Search in Google Scholar
[8] Chen, X. M. and Mak, T. C. W., J. Chem. Soc., Dalton Trans. 1991, 3253. 10.1039/DT9910003253Search in Google Scholar
[9] Chen, X. M. and Mak, T. C. W., Inorg. Chim. Acta 182, 139 (1991). http://dx.doi.org/10.1016/S0020-1693(00)90147-610.1016/S0020-1693(00)90147-6Search in Google Scholar
[10] Chen, X. M. and Mak, T. C. W., J. Chem. Soc., Dalton Trans. 1992, 1585. 10.1039/DT9920001585Search in Google Scholar
[11] Cromer, D. T. and Waber, J. T., International Tables for X-Ray Crystallography, Vol. IV, Table 2.2.B. Kynoch Press, Birmingham, 1974. Search in Google Scholar
[12] Cromer, D. T., International Tables for X-Ray Crystallography, Vol. IV, Table 2.3.1. Kynoch Press, Birmingham,1974. Search in Google Scholar
[13] Frenz, B. A. and Associates, Inc., SDP-Plus, Version 1.0, Enraf-Nonius, Delft, The Netherlands, 1980. Search in Google Scholar
[14] Huang, C. H., Coordination Chemistry of Rare Earths, p. 89. Science in China Press, Beijing, 1997. Search in Google Scholar
[15] Legendziewicz, J., Glowiak, T., Huskowska, E., and Ngoan, D. C., Polyhedron 7, 2495 (1988). http://dx.doi.org/10.1016/S0277-5387(00)83864-410.1016/S0277-5387(00)83864-4Search in Google Scholar
© 2006 Institute of Chemistry, Slovak Academy of Sciences
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Articles in the same Issue
- Influence of medium on the kinetics of oxidation of iron(II) ion with t-butyl hydroperoxide
- Synthesis of new thiazolo[2,3-b]pyrimidine derivatives of pharmaceutical interest
- Enthalpic analysis of the CaTiSiO5 system
- Kinetic, spectrophotometric determination of nanogram levels of manganese(II) using catalytic azo dye—potassium periodate—1,10-phenanthroline system
- Application of a ternary complex of tungsten(VI) with 4-nitrocatechol and thiazolyl blue for extraction-spectrophotometric determination of tungsten
- Determination of risperidone at picogram level in human urine by luminol—H2O2 chemiluminescence
- Electrochemical dissolution of chalcopyrite studied by voltammetry of immobilized microparticles
- Colon tissue concentrations of copper, iron, selenium, and zinc in colorectal carcinoma patients
- Structure of tetrakis(pyridinioacetate) neodymium(III) tetrahydrate perchlorate
- Thermally stable oligomer—Metal complexes based on oligo-ortho-aminophenol and oligophenylazomethinephenol
- Adsorption of SO2 on alumina
- One-pot, three-component synthesis of secondary amines and trisubstituted hydrazines from ketones
- Synthesis of α,α′-bis(R-benzylidene)cycloalkanones catalyzed by potassium hydrogen sulfate under solvent-free conditions
- Electrical conductivity of the molten KF—K2TaF7 system
- New substituted mono-and bis(imidazolyl)pyridines and their application in nitroaldolisation reaction
