Françoisite-(Ce), a new mineral species from La Creusaz uranium deposit (Valais, Switzerland) and from Radium Ridge (Flinders Ranges, South Australia): Description and genesis
Abstract
The new mineral françoisite-(Ce), (Ce,Nd,Ca)[(UO2)3O(OH)(PO4)2]·6H2O is the Ce-analog of françoisite-(Nd). It has been discovered simultaneously at the La Creusaz uranium deposit near Les Marécottes in Valais, Switzerland, and at the Number 2 uranium Workings, Radium Ridge near Mt. Painter, Arkaroola area, Northern Flinders Ranges in South Australia. Françoisite-(Ce) is a uranylbearing supergene mineral that results from the alteration under oxidative conditions of REE- and U4+- bearing hypogene minerals: allanite-(Ce), monazite-(Ce), ±uraninite at Les Marécottes; monazite-(Ce), ishikawaite-samarskite, and an unknown primary U-mineral at Radium Ridge. The REE composition of françoisite-(Ce) results from a short aqueous transport of REE leached out of primary minerals [most likely monazite-(Ce) at Radium Ridge and allanite-(Ce) at La Creusaz], with fractionation among REE resulting mainly from aqueous transport, with only limited Ce loss due to oxidation to Ce4+ during transport.
© 2015 by Walter de Gruyter Berlin/Boston
Articles in the same Issue
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Articles in the same Issue
- Ti-Al zoning of experimentally grown titanite in the system CaO-Al2O3-TiO2-SiO2-NaCl-H2O-(F): Evidence for small-scale fluid heterogeneity
- A new method for quantitative petrography based on image processing of chemical element maps: Part I. Mineral mapping applied to compacted bentonites
- A new method for quantitative petrography based on image processing of chemical element maps: Part II. Semi-quantitative porosity maps superimposed on mineral maps
- Enhancement of solid-state reaction rates by non-hydrostatic stress effects on polycrystalline diffusion kinetics
- (H3O)Fe(SO4)2 formed by dehydrating rhomboclase and its potential existence on Mars
- Crystal chemistry and low-temperature behavior of datolite: A single-crystal X-ray diffraction study
- Density and seismic velocities of chromitite body in oceanic mantle peridotite
- Packing schemes of cavities in selected clathrasils and zeolites and the analogous packings of atoms in crystal structures
- Temperature dependence of IR absorption of OH species in clinopyroxene
- Thermal behavior of vibrational phonons and hydroxyls of muscovite in dehydroxylation: In situ high-temperature infrared spectroscopic investigations
- Kinetics of Fe-oxidation/deprotonation process in Fe-rich phlogopite under isothermal conditions
- On the crystal chemistry of londonite [(Cs,K,Rb)Al4Be5B11O28]: A single-crystal neutron diffraction study at 300 and 20 K
- High-pressure melting of wüstite
- Primary Nb-Ta minerals in the Szklary pegmatite, Poland: New insights into controls of crystal chemistry and crystallization sequences
- Evolution of the interlayer space of hydrated montmorillonite as a function of temperature
- Morphology of pyrite in particulate matter from shallow submarine hydrothermal vents
- Influence of the fluid composition on diamond dissolution forms in carbonate melts
- Far infrared spectroscopy of carbonate minerals
- Assessment of the diamond-trap method for studying high-pressure fluids and melts and an improved freezing stage design for laser ablation ICP-MS analysis
- Françoisite-(Ce), a new mineral species from La Creusaz uranium deposit (Valais, Switzerland) and from Radium Ridge (Flinders Ranges, South Australia): Description and genesis
- Crystal chemistry and origin of grandidierite, ominelite, boralsilite, and werdingite from the Bory Granulite Massif, Czech Republic
- Lead-tellurium oxysalts from Otto Mountain near Baker, California: III. Thorneite, Pb6(Te26+O10)(CO3)Cl2(H2O), the first mineral with edge-sharing octahedral tellurate dimers
- Lead-tellurium oxysalts from Otto Mountain near Baker, California: IV. Markcooperite, Pb(UO2)Te6+O6, the first natural uranyl tellurate
- Lead-tellurium oxysalts from Otto Mountain near Baker, California: V. Timroseite, Pb2Cu52+(Te6+O6)2(OH)2, and paratimroseite, Pb2Cu42+(Te6+O6)2(H2O)2, two new tellurates with Te-Cu polyhedral sheets
- Lead-tellurium oxysalts from Otto Mountain near Baker, California: VI. Telluroperite, Pb3Te4+O4Cl2, the Te analog of perite and nadorite
- The determination of sulfate and sulfide species in hydrous silicate glasses using Raman spectroscopy
- The structure of crystals, glasses, and melts along the CaO-Al2O3 join: Results from Raman, Al L- and K-edge X-ray absorption, and 27Al NMR spectroscopy
- Ordering of iron vacancies in monoclinic jarosites