Abstract
In this paper, I demonstrate that the complex structure observed in natural dendritic zircon, which crystallized from a mafic magma, can be approximated by a simple model of deterministic volumefilling fractal growth. The model comprises a novel dendritic growth process that reveals a previously unrecognized underlying structure to complex dendritic crystals, and provides an ideal way of maximizing surface area at the crystal-melt interface during dendritic crystal growth. This addresses the important kinetic effect of creating interfacial area. In turn, this relates to dissipation of the latent heat of fusion from the moving crystal-melt interface, which, in addition to chemical diffusion, is known to be a fundamental rate-controlling process in dendritic crystal growth.
A new mechanism of tip-splitting branch formation in dendritic crystals is proposed. Although both types of branch formation seem to occur simultaneously, the newly proposed mechanism operates at larger length scales and independently of classical side-branching linked with periodic perturbations caused by thermal noise. It is shown that this type of modeling potentially has applications in metallurgical engineering; and in predicting the relative lengths, orientations, and spacings of branches in mathematical modeling studies of natural and experimentally grown dendritic crystals.
© 2015 by Walter de Gruyter Berlin/Boston
Articles in the same Issue
- TEM-assisted dynamic scanning force microscope imaging of (001) antigorite: Surfaces and steps on a modulated silicate
- PH₂O-dependent structural phase transitions in the zeolite mesolite: Real- and reciprocal-space crystal structure refinements
- The crystal structure of esperite, with a revised chemical formula, PbCa2(ZnSiO4)3, isostructural with beryllonite
- Dendritic zircon formation by deterministic volume-filling fractal growth: Implications for the mechanisms of branch formation in dendrites
- Enthalpies of formation of pyrrhotite Fe1–0.125xS (0 ≤ x ≤ 1) solid solutions
- Crystal chemistry of synthetic lawsonite solid-solution series CaAl2[(OH)2/Si2O7]·H2O– SrAl2[(OH)2/Si2O7]·H2O and the Cmcm–P21/m phase transition
- Coulsellite, CaNa3AlMg3F14, a rhombohedral pyrochlore with 1:3 ordering in both A and B sites, from the Cleveland Mine, Tasmania, Australia
- Synthesis and characterization of zeolite 4A-type desiccant from kaolin
- Effect of iron on the compressibility of hydrous ringwoodite
- Kapundaite, (Na,Ca)2Fe4 3+(PO4)4(OH)3·5H2O, a new phosphate species from Toms quarry, South Australia: Description and structural relationship to mélonjosephite
- Rate of antigorite dehydration at 2 GPa applied to subduction zones
- IR absorption coefficients for water in nominally anhydrous high-pressure minerals
- Experimental techniques for determining tin solubility in silicate melts using silica capsules in 1 atm furnaces and rhenium capsules in the piston cylinder
- Cassiterite-saturated minimum melting behavior within Sn-SnO2-SiO2 at 1 atm and 10 kbar
- Cr-bearing tourmaline associated with emerald deposits from Swat, NW Pakistan: Genesis and its exploration significance
- Mechanism and kinetics of reduction of a FeO-Fe2O3-CaO-MgO aluminosilicate melt in a high-CO-activity environment
- Biodurability of chrysotile and tremolite asbestos in simulated lung and gastric fluids
- High-pressure behavior of Ca/Na clinopyroxenes: The effect of divalent and trivalent 3d-transition elements
- Uvarovite from chromite-bearing ultramafic intrusives, Orissa, India, a crystal-chemical characterization using 57Fe Mössbauer spectroscopy
- An X-ray Rietveld and infrared spectral study of the Na2(Mn1–xM2+x )Fe2+Fe3+(PO4)3 (x = 0 to 1 and M2+ = Mg, Cd) alluaudite-type solid solutions
- Dissolution kinetics of anorthite in a supercritical CO2–water system
- Evaluation of the elasticity normal to the basal plane of non-expandable 2:1 phyllosilicate minerals by nanoindentation
- 57Fe Mössbauer spectroscopy and electrical resistivity studies on naturally occurring native iron under high pressures up to 9.1 GPa
- Letter. Discreditation of paraspurrite
- Letter. High-pressure magnetic transition in hcp-Fe
- Letter. Reduced As components in highly oxidized environments: Evidence from full spectral XANES imaging using the Maia massively parallel detector
- Letter. FTIR spectroscopy with a focal plane array detector: A novel tool to monitor the spatial OH-defect distribution in single crystals applied to synthetic enstatite
- Letter. Akaogiite: An ultra-dense polymorph of TiO2 with the baddeleyite-type structure, in shocked garnet gneiss from the Ries Crater, Germany
Articles in the same Issue
- TEM-assisted dynamic scanning force microscope imaging of (001) antigorite: Surfaces and steps on a modulated silicate
- PH₂O-dependent structural phase transitions in the zeolite mesolite: Real- and reciprocal-space crystal structure refinements
- The crystal structure of esperite, with a revised chemical formula, PbCa2(ZnSiO4)3, isostructural with beryllonite
- Dendritic zircon formation by deterministic volume-filling fractal growth: Implications for the mechanisms of branch formation in dendrites
- Enthalpies of formation of pyrrhotite Fe1–0.125xS (0 ≤ x ≤ 1) solid solutions
- Crystal chemistry of synthetic lawsonite solid-solution series CaAl2[(OH)2/Si2O7]·H2O– SrAl2[(OH)2/Si2O7]·H2O and the Cmcm–P21/m phase transition
- Coulsellite, CaNa3AlMg3F14, a rhombohedral pyrochlore with 1:3 ordering in both A and B sites, from the Cleveland Mine, Tasmania, Australia
- Synthesis and characterization of zeolite 4A-type desiccant from kaolin
- Effect of iron on the compressibility of hydrous ringwoodite
- Kapundaite, (Na,Ca)2Fe4 3+(PO4)4(OH)3·5H2O, a new phosphate species from Toms quarry, South Australia: Description and structural relationship to mélonjosephite
- Rate of antigorite dehydration at 2 GPa applied to subduction zones
- IR absorption coefficients for water in nominally anhydrous high-pressure minerals
- Experimental techniques for determining tin solubility in silicate melts using silica capsules in 1 atm furnaces and rhenium capsules in the piston cylinder
- Cassiterite-saturated minimum melting behavior within Sn-SnO2-SiO2 at 1 atm and 10 kbar
- Cr-bearing tourmaline associated with emerald deposits from Swat, NW Pakistan: Genesis and its exploration significance
- Mechanism and kinetics of reduction of a FeO-Fe2O3-CaO-MgO aluminosilicate melt in a high-CO-activity environment
- Biodurability of chrysotile and tremolite asbestos in simulated lung and gastric fluids
- High-pressure behavior of Ca/Na clinopyroxenes: The effect of divalent and trivalent 3d-transition elements
- Uvarovite from chromite-bearing ultramafic intrusives, Orissa, India, a crystal-chemical characterization using 57Fe Mössbauer spectroscopy
- An X-ray Rietveld and infrared spectral study of the Na2(Mn1–xM2+x )Fe2+Fe3+(PO4)3 (x = 0 to 1 and M2+ = Mg, Cd) alluaudite-type solid solutions
- Dissolution kinetics of anorthite in a supercritical CO2–water system
- Evaluation of the elasticity normal to the basal plane of non-expandable 2:1 phyllosilicate minerals by nanoindentation
- 57Fe Mössbauer spectroscopy and electrical resistivity studies on naturally occurring native iron under high pressures up to 9.1 GPa
- Letter. Discreditation of paraspurrite
- Letter. High-pressure magnetic transition in hcp-Fe
- Letter. Reduced As components in highly oxidized environments: Evidence from full spectral XANES imaging using the Maia massively parallel detector
- Letter. FTIR spectroscopy with a focal plane array detector: A novel tool to monitor the spatial OH-defect distribution in single crystals applied to synthetic enstatite
- Letter. Akaogiite: An ultra-dense polymorph of TiO2 with the baddeleyite-type structure, in shocked garnet gneiss from the Ries Crater, Germany