Abstract
The size distribution of pigeonite and diopside exsolution lamellae on “001,” obtained at temperatures of 1100, 1200, and 1300 °C and annealing times between 2 and 4320 h, was studied by transmission electron microscopy. A total of 5192 pigeonite and 5286 diopside lamellae was studied. At all three temperatures, the size distributions of pigeonite and diopside lamellae are smaller during exsolution compared to the subsequent coarsening process. The final size distributions are time invariant, indicating that a steady-stage distribution is reached. The theory of Ardell (1972a), which assumes volume diffusion as rate-limiting process and takes into account the non-zero volume fraction of the precipitates, describes the experimental size distributions quite well and also leads to the observed exponent of three in the rate law
© 2015 by Walter de Gruyter Berlin/Boston
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Articles in the same Issue
- Structural model for the biogenic Mn oxide produced by Pseudomonas putida
- Electron-beam (5–10 keV) damage in triplite-group phosphates: Consequences for electron-microprobe analysis of fluorine
- Vacancy defects in MgO at high pressure
- Plastic flow of pyrope at mantle pressure and temperature
- Parvo-mangano-edenite, parvo-manganotremolite, and the solid solution between Ca and Mn2+ at the M4 site in amphiboles
- Reinvestigation of the MgSiO3 perovskite structure at high pressure
- The mechanism and kinetics of α-NiS oxidation in the temperature range 670–700°C
- Influence of charge location on 29Si NMR chemical shift of 2:1 phyllosilicates
- The size distribution of exsolution lamellae in iron-free clinopyroxene
- The high-pressure phase transformation and breakdown of MgFe2O4
- Elastic behavior, phase transition, and pressure induced structural evolution of analcime
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- Poppiite, the V3+ end-member of the pumpellyite group: Description and crystal structure
- Cation redistribution in the octahedral sheet during diagenesis of illite-smectites from Jurassic and Cambrian oil source rock shales
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- Influence of dehydration kinetics on T-O-T bridge breaking in zeolites with framework type STI: The case of stellerite
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