Startseite Raman spectroscopy of the ilmenite–geikielite solid solution
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Raman spectroscopy of the ilmenite–geikielite solid solution

  • Laura B. Breitenfeld ORCID logo EMAIL logo , M. Darby Dyar , Leif Tokle und Kevin Robertson
Veröffentlicht/Copyright: 9. September 2024
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Abstract

Ilmenite (Fe2+TiO3) and geikielite (MgTiO3) are important terrestrial minerals relevant to the geology of the Earth, the Moon, Mars, and meteorite samples. Raman spectroscopy is a powerful technique that allows for mineral cation determination for the ilmenite–geikielite solid solution. We report on a suite of nine samples within the ilmenite–geikielite solid solution and provide context for their quantitative interpretation. We compare a univariate Raman peak position model for predicting ilmenite composition with a multivariate machine learning model. The univariate model is currently recommended, though the multivariate model may become superior if the data set size is increased. This study lays the groundwork for quantifying Fe (ilmenite) and Mg (geikielite) within oxide minerals using a cheap, portable, and efficient technology like Raman spectroscopy.

Acknowledgments and Funding

We are grateful to the NASA SSERVI RIS4E and RISE2 nodes for their support. We thank Steven Jaret and the other reviewer for their insightful feedback that improved the quality of this work. Data Availability: The Raman spectral data are archived in an external data repository at https://zenodo.org/records/10210991 (Breitenfeld et al. 2023).

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Received: 2023-11-27
Accepted: 2024-03-15
Published Online: 2024-09-09
Published in Print: 2024-09-25

© 2024 by Mineralogical Society of America

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