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Heavy halogen compositions of lamprophyres derived from metasomatized lithospheric mantle beneath eastern North China Craton

  • Yixin Zheng , Zaicong Wang ORCID logo , Tao He , Ray Burgess ORCID logo , Zhaoxian Zhu , Lian-Xun Wang , Xiang Wang , Zhaochu Hu and Yongsheng Liu
Published/Copyright: October 4, 2023
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Abstract

Halogens and other volatiles are widely recycled into the deep mantle by subduction and are key components to metasomatize the sub-continental lithospheric mantle (SCLM). Lamprophyres are well known to be rich in volatiles and are important for understanding the halogen characteristics of the metasomatized SCLM and/or the mobilization of halogens during the ascent of such volatile-rich, low-degree partial melts. The North China Craton (NCC) hosts lamprophyre dikes coeval with extensive thinning of the eastern NCC in the Mesozoic and generated from lithosphere metasomatized by multiple-stage subduction components. Here we report bulk-rock heavy halogens (Cl, Br, and I) of 16 lamprophyres from the eastern NCC. The bulk-rock halogen concentrations are overall very low (Cl = 58–170 μg/g, Br = 285–559 ng/g, and I <5 ng/g), comparable with depleted Mid-Ocean ridge basalts (N-MORBs). Volatile-rich minerals (e.g., amphibole and biotite) are abundant (20–30 vol%) in these lamprophyres, however, electron probe microanalyses (EPMA) data indicate that amphiboles are mainly rich in OH and F but display very low Cl concentrations (0.01–0.04 wt%). The bulk rock and amphibole data consistently indicate low abundances of heavy halogens in the lamprophyres, which is dificult to reconcile with the remarkable enrichment of fluid-mobile large ion lithophile elements such as Ba, Rb, and K. Based on low Cl/Nb and Br/Nb but high Ba/Nb and K/Nb ratios, the low halogen concentrations likely resulted from extensive volatile loss (>90%) during melt ascent. The low Cl concentrations in early-stage amphiboles (Mg# 60–64) further indicate that such loss would have occurred before amphibole crystallization at a depth of ~15 km. We thus propose that crystallization of early olivines and pyroxenes and reaction with surrounding mantle rocks likely induced volatile saturation and exsolution, leading to strong partitioning of the halogens into the exsolved aqueous volatile phases and thus the extensive loss of halogens from the rising melt. These results reveal that significant volatile loss of halogens not only occurs during surficial low-pressure eruption but also at much deeper levels in the crust, as also identified for some kimberlites. Consequently, it would be dificult to constrain the primitive halogen components of the mantle sources via lamprophyres or similar magmas.

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Received: 2022-07-06
Accepted: 2022-11-16
Published Online: 2023-10-04
Published in Print: 2023-10-26

© 2023 by Mineralogical Society of America

Articles in the same Issue

  1. Heavy halogen compositions of lamprophyres derived from metasomatized lithospheric mantle beneath eastern North China Craton
  2. Compositional trends in Ba-, Ti-, and Cl-rich micas from metasomatized mantle rocks of the Gföhl Unit, Bohemian Massif, Austria
  3. Experimental determination of quartz solubility in H2O-CaCl2 solutions at 600–900 °C and 0.6–1.4 GPa
  4. The use of boron nitride to impose reduced redox conditions in experimental petrology
  5. Structures and transport properties of supercritical SiO2-H2O and NaAlSi3O8-H2O fluids
  6. Hydrologic regulation of clay-mineral transformations in a redoximorphic soil of subtropical monsoonal China
  7. Witness to strain: Subdomain boundary length and the apparent subdomain boundary density in large strained olivine grains
  8. Libyan Desert Glass: New evidence for an extremely high-pressure-temperature impact event from nanostructural study
  9. Crystal vs. melt compositional effects on the partitioning of the first-row transition and high field strength elements between clinopyroxene and silicic, alkaline, aluminous melts
  10. Microbially induced clay weathering: Smectite-to-kaolinite transformation
  11. Hydrous wadsleyite crystal structure up to 32 GPa
  12. Multiple fluid sources in skarn systems: Oxygen isotopic evidence from the Haobugao Zn-Fe-Sn deposit in the southern Great Xing’an Range, NE China
  13. Crocobelonite, CaFe23+(PO4)2O, a new oxyphosphate mineral, the product of pyrolytic oxidation of natural phosphides
  14. Tetrahedrite-(Ni), Cu6(Cu4Ni2)Sb4S13, the first nickel member of tetrahedrite group mineral from Luobusa chromite deposits, Tibet, China
  15. New Mineral Names: Heavy metal and minerals from China
  16. Book Review
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