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Compositional trends in Ba-, Ti-, and Cl-rich micas from metasomatized mantle rocks of the Gföhl Unit, Bohemian Massif, Austria

  • Tereza Zelinková ORCID logo , Martin Racek and Rainer Abart
Published/Copyright: October 4, 2023
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Abstract

Ba-, Ti-, and Cl-rich micas associated with other Ba- and/or Cl-rich minerals in the rock matrix or in garnet and clinopyroxene hosted multiphase solid inclusions (MSI) are observed in mantle-derived garnet pyroxenites. The micas show extremely high variability in chemical composition ranging between Ba-rich phlogopite, chloroferrokinoshitalite, and oxykinoshitalite. Elemental covariation trends in mineral chemical data reveal the principal substitution mechanisms responsible for the observed chemical variability. The substitution Ba2+Al3+ ↔ K1+Si4+ associated with either OH1– ↔ Cl1– or Ti4+2O2– ↔ Mg2+2OH1 links phlogopite to chloroferrokinoshitalite and oxykinoshitalite, respectively, whereas the substitution Ti4+2O2– ↔ Fe2+2Cl1– links chloroferrokinoshitalite to oxykinoshitalite. The preferred incorporation of Cl in Fe-rich mica and of Ti+O in Mg-rich mica indicates that XFe (Fetot/Fetot+Mg) exerts an important control on mica composition. The positive correlation of XFe with Cl led to the formation of possibly the most Cl-rich mica so far described classified as chloroferrokinoshitalite (XFe0.88, Ba0.95K0.03Fe2.68Mg0.37Al1.91Si2.01Cl1.98) with 10.98 wt% Cl. Substantial substitution of OH by Cl and O2– in mica, and the presence of Cl-apatite, a rare Cl-rich phosphate goryainovite, and carbonates together with Cl-rich micas indicate high-Cl and -CO2 activity and low-H2O activity in metasomatizing fluids or melts that may be classified as Ba-Cl-rich silicocarbonatitic. The coexistence of two micas with distinct compositions close to chloroferrokinoshitalite (XFe0.57–0.77, K~0.1Ba0.6–0.8Mg0.7–1.3Fe1.7–2.3Ti0.0–0.1 Si2.2–2.3Al1.5–1.7Cl1.2–1.8) and oxykinoshitalite (XFe0.19–0.20, K~0.3Ba~0.5Mg2.0–2.1Fe~0.5Ti0.2–0.4Si2.4–2.6Al~1.8Cl~0.3) suggests that a miscibility gap exists between these two compositions. The exotic mineral assemblage was formed by interaction with metasomatizing fluids or melts whose origin cannot be defined with certainty. They may be derived from crustal or mantle lithologies or from the host garnet pyroxenites. The textural position of the MSI in garnet and their characteristic mineral assemblages indicate that they have been introduced into the garnet crystals under post-peak conditions, possibly during decompression. With this research we document substitution mechanisms in Ba-, Ti-, and Cl-rich micas and shed light on the behavior and composition of fluids or melts at the upper mantle/lower crust interface.

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Received: 2022-08-04
Accepted: 2022-11-08
Published Online: 2023-10-04
Published in Print: 2023-10-26

© 2023 by Mineralogical Society of America

Articles in the same Issue

  1. Heavy halogen compositions of lamprophyres derived from metasomatized lithospheric mantle beneath eastern North China Craton
  2. Compositional trends in Ba-, Ti-, and Cl-rich micas from metasomatized mantle rocks of the Gföhl Unit, Bohemian Massif, Austria
  3. Experimental determination of quartz solubility in H2O-CaCl2 solutions at 600–900 °C and 0.6–1.4 GPa
  4. The use of boron nitride to impose reduced redox conditions in experimental petrology
  5. Structures and transport properties of supercritical SiO2-H2O and NaAlSi3O8-H2O fluids
  6. Hydrologic regulation of clay-mineral transformations in a redoximorphic soil of subtropical monsoonal China
  7. Witness to strain: Subdomain boundary length and the apparent subdomain boundary density in large strained olivine grains
  8. Libyan Desert Glass: New evidence for an extremely high-pressure-temperature impact event from nanostructural study
  9. Crystal vs. melt compositional effects on the partitioning of the first-row transition and high field strength elements between clinopyroxene and silicic, alkaline, aluminous melts
  10. Microbially induced clay weathering: Smectite-to-kaolinite transformation
  11. Hydrous wadsleyite crystal structure up to 32 GPa
  12. Multiple fluid sources in skarn systems: Oxygen isotopic evidence from the Haobugao Zn-Fe-Sn deposit in the southern Great Xing’an Range, NE China
  13. Crocobelonite, CaFe23+(PO4)2O, a new oxyphosphate mineral, the product of pyrolytic oxidation of natural phosphides
  14. Tetrahedrite-(Ni), Cu6(Cu4Ni2)Sb4S13, the first nickel member of tetrahedrite group mineral from Luobusa chromite deposits, Tibet, China
  15. New Mineral Names: Heavy metal and minerals from China
  16. Book Review
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