Startseite Naturwissenschaften Trace element and isotopic (S, Pb) constraints on the formation of the giant Chalukou porphyry Mo deposit, NE China
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Trace element and isotopic (S, Pb) constraints on the formation of the giant Chalukou porphyry Mo deposit, NE China

  • Qingqing Zhao ORCID logo , Degao Zhai , Anthony E. Williams-Jones und Jiajun Liu ORCID logo
Veröffentlicht/Copyright: 3. Januar 2023
Veröffentlichen auch Sie bei De Gruyter Brill
Informationen für Autor*innen
American Mineralogist
Aus der Zeitschrift American Mineralogist Band 108 Heft 1

Abstract

Porphyry-type Mo deposits have supplied most of the Mo to the world. However, the source of the Mo and the controls on its enrichment in such deposits is still a matter of great debate. In this study, we present in situ trace element and isotopic data for a giant porphyry Mo deposit (the Chalukou Mo deposit in NE China) and use these data to address these issues. Three primary paragenetic stages of mineralization were recognized at Chalukou: (Stage I) K-feldspar + quartz + minor pyrite (Py-I) + minor molybdenite (Mol-I); (Stage II) quartz + sericite + molybdenite (Mol-II) + pyrite (Py-II); (Stage III) quartz + chlorite + epidote + fluorite + pyrite (Py-III) + galena + sphalerite + minor chalcopyrite. The bulk of the molybdenite was deposited in Stage II. In situ S isotope analyses of the sulfide ores show that the δ34S values vary from –5.2 to +7.8‰ (mean = +2.9‰) and correspond to δ34SH2S values from –2.4 to +3.3‰ (mean = +1.1‰). These values are consistent with a magmatic source for the sulfur. In situ Pb isotope compositions of the sulfide ores are almost identical to those of the local Mesozoic granites and other magmatic-hydrothermal ore deposits in this region, suggesting a close genetic association between the Mo mineralization and felsic magmatism.

Pyrite from the three stages of mineralization differs significantly in its trace element composition. The first generation, Py-I, has a high Cu content (8.7 ± 49.6 ppm; where the first value is the median and the second is the standard deviation) and Mo content (6.9 ± 3.8 ppm). Pyrite-II has the lowest Cu concentration (1.3 ± 2.1 ppm) and a relatively high Mo concentration (5 ± 128 ppm), and Py-III has a high Cu content (8.7 ± 37.1 ppm) but the lowest Mo content (0.05 ± 5.7 ppm). From this, we infer that pyrite recorded the chemical evolution in the Mo/Cu ratio of the ore fluid and that this ratio reached a maximum in Stage II, coinciding with the widespread saturation of the fluid in molybdenite. The evolution of the Mo/Cu ratio in pyrite implies that the fluid was undersaturated in chalcopyrite at the high temperature of Stage I, despite the Cu concentration of the fluid apparently being at its high level, and chalcopyrite only saturated later, at a lower temperature. Molybdenite, however, because of its lower solubility, saturated early (Stage I) and in the subsequent stage (Stage II) was supersaturated in the fluid.

There is a significant enrichment of Mo in the syn-ore intrusions at Chalukou compared to the pre-ore monzogranite. The very low Sr/Y ratios for the Chalukou syn-ore intrusions, which are in sharp contrast to the high Sr/Y ratios of the pre-ore monzogranite and those of porphyries related to Cu deposits, suggest that fractional crystallization of plagioclase may have been a key factor in generating the syn-ore magmas. Molybdenum is a highly incompatible metal and will concentrate in the crust, and assimilation of old continental crust, therefore, may explain the Mo enrichment of the syn-ore intrusions and ultimately the formation of the giant Chalukou deposit.

Keywords: Sulfur and lead isotopes; trace element chemistry; porphyry Mo deposits; magma and fluid evolution; metal source and enrichment

Funding statement: This research was supported financially by the National Natural Science Foundation of China (42122012, 41503042), the Fundamental Research Funds for the Central Universities (QZ05201904), and the 111 Project of the Ministry of Science and Technology (BP0719021). D.Z. was supported financially by the China Scholarship Council (CSC) (201906405012) to visit McGill University.

Acknowledgments

We thank Li Su and Hongyu Zhang (CUGB) for performing sulfide in situ trace element analyses. Constructive suggestions from Constantinos Mavrogonatos and an anonymous reviewer, Associate Editor Paul Tomascak and Editor Hongwu Xu significantly improved this manuscript.

References cited

Audétat, A. (2010) Source and evolution of molybdenum in the porphyry-Mo(-Nb) deposit at Cave Peak. Journal of Petrology, 51, 1739–1760.Suche in Google Scholar

Audétat, A., Günther, D., and Heinrich, C.A. (2000) Causes for large-scale metal zonation around mineralized plutons: Fluid inclusion LA-ICP-MS evidence from the Mole Granite, Australia. Economic Geology, 95, 1563–1581.Suche in Google Scholar

Audétat, A., Pettke, T., Heinrich, C.A., and Bodnar, R.J. (2008) The composition of magmatic-hydrothermal fluids in barren and mineralized intrusions. Economic Geology, 103, 877–908.Suche in Google Scholar

Bali, E., Keppler, H., and Audétat, A. (2012) The mobility of W and Mo in subduction zone fluids and the Mo-W-Th-U systematics of island arc magmas. Earth and Planetary Science Letters, 351-352, 195–207.Suche in Google Scholar

Blevin, P.L. (2002) The petrographic and compositional character of variably K-enriched magmatic suites associated with Ordovician porphyry Cu-Au mineralisation in the Lachlan Fold Belt, Australia. Mineralium Deposita, 37, 87–99.Suche in Google Scholar

Camus, F. (1975) Geology of the El Teniente orebody with emphasis on wallrock alteration. Economic Geology, 70, 1341–1372.Suche in Google Scholar

Carten, R.B., Geraghty, E.P., Walker, B.M., and Shannon, J.R. (1988) Cyclic development of igneous features and their relationship to high-temperature hydrothermal features in the Henderson porphyry molybdenum deposit, Colorado. Economic Geology, 83, 266–296.Suche in Google Scholar

Carten, R.B., White, W.H., and Stern, H. (1993) High-grade granite-related molybdenum systems: Classification and origin. Geological Association of Canada—Special Paper, 40, 521–554.Suche in Google Scholar

Chang, J., Li, J.W., and Audétat, A. (2018) Formation and evolution of multistage magmatic-hydrothermal fluids at the Yulong porphyry Cu-Mo deposit, Eastern Tibet: Insights from LA-ICP-MS analysis of fluid inclusions. Geochimica et Cosmochimica Acta, 232, 181–205.Suche in Google Scholar

Chen, Z.G., Zhang, L.C., Wan, B., Wu, H.Y., and Cleven, N. (2011) Geochronology and geochemistry of the Wunugetushan porphyry Cu-Mo deposit in NE China, and their geological significance. Ore Geology Reviews, 43, 92–105.Suche in Google Scholar

Chen, Y.J., Zhang, C., Li, N., Yang, Y.F., and Deng, K. (2012) Geology of the Mo deposits in northeast China. Journal of Jilin University, 42, 1224–1268 (Earth Science edition) (in Chinese with English abstract).Suche in Google Scholar

Chen, Y.J., Zhang, C., Wang, P., Pirajno, F., and Li, N. (2017) The Mo deposits of northeast China: A powerful indicator of tectonic settings and associated evolutionary trends. Ore Geology Reviews, 81, 602–640.Suche in Google Scholar

Chiaradia, M. (2014) Copper enrichment in arc magmas controlled by overriding plate thickness. Nature Geoscience, 7, 43–46.Suche in Google Scholar

Chu, S.X., Liu, J.M., Xu, J.H., Wei, H., Chai, H., and Tong, K.Y. (2012) Zircon U-Pb dating, petrogenesis and tectonic significance of the granodiorite in the Sankuanggou skarn Fe-Cu deposit, Heilongjiang Province. Acta Petrologica Sinica, 28, 433–450 (in Chinese with English abstract).Suche in Google Scholar

Ciobanu, C.L., Cook, N.J., Kelson, C.R., Guerin, R., Kalleske, N., and Danyushevsky, L. (2013) Trace element heterogeneity in molybdenite fingerprints stages of mineralization. Chemical Geology, 347, 175–189.Suche in Google Scholar

Clark, A.H., Farrar, E., Kontak, D.J., Langridge, R.J., Arenas, M., France, L.J., McBride, S.L., Woodman, P.I., Wasteneys, H.A., Sandeman, H.A., and Archibald, D.A. (1990) Geologic and geochronologic constraints on the metallogenic evolution of the Andes of southeastern Peru. Economic Geology, 85, 1520–1583.Suche in Google Scholar

Cook, N.J., Ciobanu, C.L., Meria, D., Silcock, D., and Wade, B. (2013) Arsenopyrite-pyrite association in an orogenic gold ore: Tracing mineralization history from textures and trace elements. Economic Geology, 108, 1273–1283.Suche in Google Scholar

Core, D.P., Kesler, S.E., and Essene, E.J. (2006) Unusually Cu-rich magmas associated with giant porphyry copper deposits: Evidence from Bingham, Utah. Geology, 34, 41–44.Suche in Google Scholar

Deng, K., Li, Q., Chen, Y., Zhang, C., Zhu, X., and Xu, Q. (2018) Geochronology geochemistry and Sr-Nd-Pb-Hf isotopes of the Early Jurassic granodiorite from the Sankuanggou intrusion, Heilongjiang Province, Northeastern China: Petrogenesis and geodynamic implications. Lithos, 296-299, 113–128.Suche in Google Scholar

Duan, P.X., Liu, C., Mo, X.X., Deng, D.F., Qin, J.H., Zhang, Y., and Tian, S.P. (2018) Discriminating characters of ore-forming intrusions in the super-large Chalukou porphyry Mo deposit, NE China. Geoscience Frontiers, 9, 1417–1431.Suche in Google Scholar

Fritzell, E.H., Bull, A.L., and Shephard, G.E. (2016) Closure of the Mongol-Okhotsk Ocean: Insights from seismic tomography and numerical modelling. Earth and Planetary Science Letters, 445, 1–12.Suche in Google Scholar

Fu, J.J., Zhao, Y.Y., Zeng, H., and Li, Y. (2014) Chronological and isotopic characteristics of Zhengguang gold deposit in Heilongjiang Province, China. Acta Geologica Sinica—English Edition, 88, 718–719.Suche in Google Scholar

Gao, B.Y., Zhang, L.C., Jin, X.D., Li, W.J., Chen, Z.G., and Zhu, M.T. (2016) Geochronology and geochemistry of the Badaguan porphyry Cu-Mo deposit in Derbugan metallogenic belt of the NE China, and their geological significances. International Journal of Earth Sciences, 105, 507–519.Suche in Google Scholar

Gao, R., Xue, C., Lü, X., Zhao, X., Yang, Y., and Li, C. (2017) Genesis of the Zhengguang gold deposit in the Duobaoshan ore field, Heilongjiang Province, NE China: Constraints from geology, geochronology and S-Pb isotopic compositions. Ore Geology Reviews, 84, 202–217.Suche in Google Scholar

Ge, W.C., Chen, J.S., Yang, H., Zhao, G.C., Zhang, Y.L., and Tian, D.X. (2015) Tectonic implications of new zircon U-Pb ages for the Xinghuadukou Complex, Erguna Massif, northern Great Xing’an Range, NE China. Journal of Asian Earth Sciences, 106, 169–185.Suche in Google Scholar

Gong, X., Zhao, Y.Y., Shui, X.F., Liu, X., Cheng, X.D., Wang, Y.C., and Tan, W. (2020) A study of sulfur and lead isotope characteristics and genesis of the Hulalin gold deposit in upper Heilongjiang basin. Acta Geoscientica Sinica, 3, 395–406 (in Chinese with English abstract).Suche in Google Scholar

Guo, F., Fan, W.M., Gao, X.F., Li, C.W., Miao, L.C., Zhao, L., and Li, H.X. (2010) Sr-Nd-Pb isotope mapping of Mesozoic igneous rocks in NE China: Constraints on tectonic framework and Phanerozoic crustal growth. Lithos, 120, 563–578.Suche in Google Scholar

Heinrich, C.A. (2005) The physical and chemical evolution of low-salinity magmatic fluids at the porphyry to epithermal transition: A thermodynamic study. Mineralium Deposita, 39, 864–889.Suche in Google Scholar

Hou, Z.S. (2014) Ore genesis and tectonic setting of Badaguan copper-molybdenum deposit in Erguna region, Inner Mongolia, 66 p. Master’s thesis, Jilin University, Changchun (in Chinese with English abstract).Suche in Google Scholar

Hou, Z.Q., Yang, Z.M., Lu, Y.J., Kemp, A., Zheng, Y.C., Li, Q.Y., Tang, J.X., Yang, Z. S., and Duan, L.F. (2015) A genetic linkage between subduction- and collision-related porphyry Cu deposits in continental collision zones. Geology, 43, 247–250.Suche in Google Scholar

Hu, X.L., Yao, S.Z., He, M.C., Ding, Z.J., Liu, M., Cui, Y.B., and Shen, J. (2014) Sulfur and lead isotopic characteristics of Chalukou and Daheishan porphyry Mo deposits in northern segment of Da Hinggan Mountains. Mineral Deposits, 33, 776–784 (in Chinese with English abstract).Suche in Google Scholar

Huang, F., Wang, D.H., Chen, Y.C., Wang, C.H., Tang, J.X., Chen, Z.H., Wang, L.Q., Liu, S.B., Li, J.K., Zhang, C.Q., and others. (2014) Trace elements characteristics of molybdenites from endogenous molybdenum deposits in China. Mineral Deposits, 33, 1193–1212 (in Chinese with English abstract).Suche in Google Scholar

Huang, Q.H., Cheng, H.G., Han, M.X., Jin, X.Y., and Zhou, W.J. (2018) Sulfur isotope characteristics of the late Paleozoic strata in No. D101 well at western Songliao Basin. Joint Meetings on the 12th National Congress of the Palaeontological Society of China (PSC) and the 29th Annual Conference of PSC, S11-04 (in Chinese).Suche in Google Scholar

Jin, L.Y., Qin, K.Z., Meng, Z.J., Li, G.M., Song, G.X., Li, Z.Z., Lv, K.P., Kan, X.S., and Zhao, C. (2014) Vein features and occurrences in Chalukou giant molybdenum-zinc-lead deposit, northern Great Xing’an Range, and its indications for mineralization. Mineral Deposits, 33, 742–760 (in Chinese with English abstract).Suche in Google Scholar

Johnson, M.E., Jia-Yu, R., Cheng-Yuan, W., and Ping, W. (2001) Continental island from the Upper Silurian (Ludfordian Stage) of Inner Mongolia: Implications for eustasy and paleogeography. Geology, 29, 955–958.Suche in Google Scholar

Kang, Y.J. (2015) The ore-forming processes and mineralization of Badaguan porphyry Cu-Mo deposit, Inner Mongolia, 112 p. Master’s thesis, Chinese Academy of Geological Sciences, Beijing (in Chinese with English abstract).Suche in Google Scholar

Kobylinski, C., Hattori, K., Smith, S., and Plouffe, A. (2020) Protracted magmatism and mineralized hydrothermal activity at the Gibraltar porphyry copper-molybdenum deposit, British Columbia. Economic Geology, 115, 1119–1136.Suche in Google Scholar

Landtwing, M.R., Pettke, T., Halter, W.E., Heinrich, C.A., Redmond, P.B., Einaudi, M.T., and Kunze, K. (2005) Copper deposition during quartz dissolution by cooling magmatic-hydrothermal fluids: The Bingham porphyry. Earth and Planetary Science Letters, 235, 229–243.Suche in Google Scholar

Lee, C.-T.A., and Tang, M. (2020) How to make porphyry copper deposits. Earth and Planetary Science Letters, 529, 115868.Suche in Google Scholar

Lee, C.-T.A., Luffi, P., Chin, E.J., Bouchet, R., Dasgupta, R., Morton, D.M., Le Roux, V., Yin, Q-Z., and Jin, D. (2012) Copper systematics in arc magmas and implications for crust-mantle differentiation. Science, 336, 64–68.Suche in Google Scholar

Li, Z.Z., Qin, K.Z., Li, G.M., Ishihara, S., Jin, L.Y., Song, G.X., and Meng, Z.J. (2014) Formation of the giant Chalukou porphyry Mo deposit in northern Great Xing’an Range, NE China: Partial melting of the juvenile lower crust in intra-plate extensional environment. Lithos, 202-203, 138–156.Suche in Google Scholar

Li, Z.Z., Qin, K.Z., Li, G.M., Jin, L.Y., and Song, G.X. (2018) Neoproterozoic and early Paleozoic magmatic records from the Chalukou ore district, northern Great Xing’an Range, NE China: Implications for tectonic evolution and Mesozoic Mo mineralization. Journal of Asian Earth Sciences, 165, 96–113.Suche in Google Scholar

Li, Z.Z., Qin, K.Z., Li, G.M., Jin, L.Y., Song, G.X., and Han, R. (2019) Incursion of meteoric water triggers molybdenite precipitation in porphyry Mo deposits: A case study of the Chalukou giant Mo deposit. Ore Geology Reviews, 109, 144–162.Suche in Google Scholar

Liu, J., Mao, J.W., Wu, G., Wang, F., Luo, D.F., Hu, Y.Q., and Li, T.G. (2014a) Fluid inclusions and H-O-S-Pb isotope systematics of the Chalukou giant porphyry Mo deposit, Heilongjiang Province, China. Ore Geology Reviews, 59, 83–96.Suche in Google Scholar

Liu, J., Mao, J.W., Wu, G., Wang, F., Luo, D.F., and Hu, Y.Q. (2014b) Zircon U-Pb and molybdenite Re-Os dating of the Chalukou porphyry Mo deposit in the northern Great Xing’an Range, China and its geological significance. Journal of Asian Earth Sciences, 79, 696–709.Suche in Google Scholar

Liu, J., Mao, J.W., Wu, G., Wang, F., Luo, D.F., and Hu, Y.Q. (2015a) Geochemical signature of the granitoids in the Chalukou giant porphyry Mo deposit in the Heilongjiang Province, NE China. Ore Geology Reviews, 64, 35–52.Suche in Google Scholar

Liu, J., Zhou, Z.H., He, Z.F., and Ouyang, H.G. (2015b) Zircon U-Pb dating and geochemistry of ore-bearing tonalite in Tongshan copper deposit, Heilongjiang Province. Mineral Deposits, 34, 289–308 (in Chinese with English abstract).Suche in Google Scholar

Liu, Y.F., Bagas, L., Jiang, S.H., and Wang, F.X. (2017) The Chalukou deposit in the North Great Xing’an Range of China: A protracted porphyry Mo ore-forming system in a long-lived magmatic evolution cycle. Ore Geology Reviews, 89, 171–186.Suche in Google Scholar

Lv, P.R., Li, D.R., Peng, Y.W., and Zhang, M.Y. (2012) S-Pb isotopic characteristics of ore sulfides and U-Pb dating of zircon from the Sankuanggou skarn-type Cu-Fe-Mo polymetallic deposit in Heilongjiang Province. Geology in China, 39, 717–728 (in Chinese with English abstract).Suche in Google Scholar

Ma, D.Y. (1984) Isotope geology of the Duobaoshan copper ore field. Mineral Deposits, 3, 47–57 (in Chinese with English abstract).Suche in Google Scholar

Mao, J.W., Pirajno, F., Xiang, J.F., Gao, J.J., Ye, H.S., Li, Y.F., and Guo, B.J. (2011) Mesozoic molybdenum deposits in the east Qinling-Dabie orogenic belt: Characteristics and tectonic settings. Ore Geology Reviews, 43, 264–293.Suche in Google Scholar

Mathur, R., Ruiz, J., Titley, S., Gibbins, S., and Margotomo, W. (2000) Different crustal sources for Au-rich and Au-poor ores of the Grasberg Cu-Au porphyry deposit. Earth and Planetary Science Letters, 183, 7–14.Suche in Google Scholar

Mavrogonatos, C., Voudouris, P., Zaccarini, F., Klemme, S., Berndt, J., Tarantola, A., Melfos, V., and Spry, P.G. (2020) Multi-stage introduction of precious and critical metals in pyrite: A case study from the Konos Hill and Pagoni Rachi porphyry/epithermal prospects, NE Greece. Minerals, 10, 784.Suche in Google Scholar

McFall, K., Roberts, S., McDonald, I., Boyce, A.J., Naden, J., and Teagle, D. (2019) Rhenium enrichment in the Muratdere Cu-Mo (Au-Re) porphyry deposit, Turkey: Evidence from stable isotope analyses (δ34S, δ18O, δD) and laser ablation-inductively coupled plasma-mass spectrometry analysis of sulfides. Economic Geology, 114, 1443–1466.Suche in Google Scholar

Mi, K.F., Liu, Z.J., Li, C.F., Liu, R.B., Wang, J.P., and Peng, R.M. (2017) Origin of the Badaguan porphyry Cu-Mo deposit, Inner Mongolia, Northeast China: Constraints from geology isotope geochemistry and geochronology. Ore Geology Reviews, 81, 154–172.Suche in Google Scholar

Nadeau, O., Williams-Jones, A.E., and Stix, J. (2010) Sulphide magma as a source of metals in arc-related magmatic hydrothermal ore fluids. Nature Geoscience, 3, 501–505.Suche in Google Scholar

Nie, F.J., Sun, Z.J., Li, C., Liu, Y.F., Lv, K.P., Zhang, K., and Liu, Y. (2011) Re-Os isotopic dating of molybdenite separates from Chalukou porphyry Mo polymetallic deposit in Heilongjiang Province. Mineral Deposits, 30, 828–836 (in Chinese with English abstract).Suche in Google Scholar

Olson, N.H., Dilles, J.H., Kent, A.J.R., and Lang, J.R. (2017) Geochemistry of the Cretaceous Kaskanak Batholith and genesis of the Pebble porphyry Cu-Au-Mo deposit, Southwest Alaska. American Mineralogist, 102, 1597–1621.Suche in Google Scholar

Pettke, T., Oberli, F., and Heinrich, C.A. (2010) The magma and metal source of giant porphyry-type ore deposits based on lead isotope microanalysis of individual fluid inclusions. Earth and Planetary Science Letters, 296, 267–277.Suche in Google Scholar

Ren, Z., Zhou, T.F., Hollings, P., White, N.C., Wang, F.Y., and Yuan, F. (2018) Trace element geochemistry of molybdenite from the Shapinggou super-large porphyry Mo deposit, China. Ore Geology Reviews, 95, 1049–1065.Suche in Google Scholar

Richards, J.P. (2003) Tectono-magmatic precursors for porphyry Cu- (Mo) deposit formation. Economic Geology, 98, 1515–1533.Suche in Google Scholar

Richards, J.P. (2011) High Sr/Y arc magmas and porphyry Cu ± Mo ± Au deposits: Just add water. Economic Geology, 106, 1075–1081.Suche in Google Scholar

Rudnick, R.L., and Gao, S. (2014) Composition of the continental crust. In R.L. Rudnick, Eds., Treatise on Geochemistry, 1–51. Elsevier.Suche in Google Scholar

Seal, R.R. (2006) Sulfur isotope geochemistry of sulfide minerals. Reviews in Mineralogy and Geochemistry, 61, 633–677.Suche in Google Scholar

Shi, P.H., Yang, Y.C., Ye, S.Q., and Han, S.J. (2012) Geological and geochemical characteristics and genesis of ferromolybdenum deposit in Wudaoling, Heilongjiang Province. Global Geology, 31, 262–270 (in Chinese with English abstract).Suche in Google Scholar

Shu, Q.H., and Chiaradia, M. (2021) Mesozoic Mo mineralization in northeastern China did not require reginal-scale pre-enrichment. Economic Geology, 116, 1227–1237.Suche in Google Scholar

Shu, Q.H., Chang, Z.S., Lai, Y., Zhou, Y.T., Sun, Y., and Yan, C. (2016) Regional metallogeny of Mo-bearing deposits in northeastern China with new Re-Os dates of porphyry Mo deposits in the northern Xilamulun district. Economic Geology, 111, 1783–1798.Suche in Google Scholar

Sillitoe, R.H. (2010) Porphyry copper systems. Economic Geology, 105, 3–41.Suche in Google Scholar

Stern, C.R., Funk, J.A., Skewes, M.A., and Arevalo, A. (2007) Magmatic anhydrite in plutonic rocks at the El Teniente Cu-Mo deposit, Chile, and the role of sulfur-and copper-rich magmas in its formation. Economic Geology, 102, 1335–1344.Suche in Google Scholar

Tang, W.L., Zeng, W., Ran, H., Zhou, Y., and Sun, W.L. (2012) Geological features and ore prospecting of Biligangan deposit, Abaga, Inner Mongolia. Geological Survey and Research, 35, 161–166 (in Chinese with English abstract).Suche in Google Scholar

Todt, W., Cliff, R.A., Hanser, A., and Hofmann, A.W. (1993) Recalibration of NBS lead standards using a 207Pb/205 Pb double spike. Terra Abstracts, 5, 396.Suche in Google Scholar

Wang, G.G., Ni, P., Yu, W., Chen, H., Jiang, L.L., Wang, B.H., Zhang, H.D., and Li, P.F. (2014) Petrogenesis of Early Cretaceous post-collisional granitoids at Shapinggou, Dabie Orogen: Implications for crustal architecture and porphyry Mo mineralization. Lithos, 184-187, 393–415.Suche in Google Scholar

Wang, G.R., Wu, G., Xu, L.Q., Li, X.Z., Liu, J., Zhang, T., Quan, Z.X., Wu, H., Li, T.G., and Chen, Y.C. (2017) Molybdenite Re-Os age, H-O-C-S-Pb isotopes and fluid inclusion study of the Caosiyao porphyry Mo deposit in Inner Mongolia, China. Ore Geology Reviews, 81, 728–744.Suche in Google Scholar

Williams-Jones, A.E., and Migdisov, A.A. (2014) Experimental constraints on the transport and deposition of metals in ore-forming hydrothermal systems. Society of Economic Geologists, Special Publication, 18, 77–95.Suche in Google Scholar

Wu, F.Y., Sun, D.Y., Ge, W.C., Zhang, Y.B., Grant, M.L., Wilde, S.A., and Jahn, B.M. (2011) Geochronology of the Phanerozoic granitoids in northeastern China. Journal of Asian Earth Sciences, 41, 1–30.Suche in Google Scholar

Wu, G., Chen, Y.C., Sun, F.Y., Liu, J., Wang, G.R., and Xu, B. (2015) Geochronology geochemistry and Sr-Nd-Hf isotopes of the early Paleozoic igneous rocks in the Duobaoshan area, NE China, and their geological significance. Journal of Asian Earth Sciences, 97, 229–250.Suche in Google Scholar

Xing, K., Shu, Q., Lentz, D.R., and Wang, F.Y. (2020) Zircon and apatite geochemical constraints on the formation of the Huojihe porphyry Mo deposit in the Lesser Xing’an Range, NE China. American Mineralogist, 105, 382–396.Suche in Google Scholar

Xiong, S.F., He, M.C., Yao, S.Z., Cui, Y.B., Shi, G.Z., Ding, Z.J., and Hu, X.L. (2015) Fluid evolution of the Chalukou giant Mo deposit in the northern Great Xing’an Range, NE China. Geological Journal, 50, 720–738.Suche in Google Scholar

Xu, B., Hou, Z.-Q., Griffin, W.L., Lu, Y., Belousova, E., Xu, J.-F., and O’Reilly, S.Y. (2021) Recycled volatiles determine fertility of porphyry deposits in collisional settings. American Mineralogist, 106, 656–661.Suche in Google Scholar

Yang, Z.M., and Cooke, D.R. (2019) Porphyry copper deposits in China. Society of Economic Geologists, Special Publication, 22, 133–187.Suche in Google Scholar

Yang, Z.M., Lu, Y.J., Hou, Z.Q., and Chang, Z.S. (2015) High-Mg diorite from Qulong in southern Tibet: Implications for the genesis of adakite-like intrusions and associated porphyry Cu deposits in collisional orogens. Journal of Petrology, 56, 227–254.Suche in Google Scholar

Yang, L.Q., Deng, J., Gao, X., He, W.Y., Meng, J.Y., Santosh, M., Yu, H.J., Yang, Z., and Wang, D. (2017) Timing of formation and origin of the Tongchanggou porphyry-skarn deposit: Implications for late Cretaceous Mo-Cu metallogenesis in the southern Yidun Terrane, SE Tibetan Plateau. Ore Geology Reviews, 81, 1015–1032.Suche in Google Scholar

Yuan, H., Liu, X., Chen, L., Bao, Z., Chen, K., Zong, C., Li, X.-C., and Qiu, J.W. (2018a) Simultaneous measurement of sulfur and lead isotopes in sulfides using nanosecond laser ablation coupled with two multi-collector inductively coupled plasma mass spectrometers. Journal of Asian Earth Sciences, 154, 386–396.Suche in Google Scholar

Yuan, M.W., Li, S.R., Li, C.L., Santosh, M., Alam, M., and Zeng, Y.J. (2018b) Geochemical and isotopic composition of auriferous pyrite from the Yongxin gold deposit, Central Asian Orogenic Belt: Implication for ore genesis. Ore Geology Reviews, 93, 255–267.Suche in Google Scholar

Zartman, R.E., and Doe, B.R. (1981) Plumbotectonics. Tectonophysics, 75, 135–162.Suche in Google Scholar

Zeng, Q.D., Liu, J.M., Qin, K.Z., Fan, H.R., Chu, S.X., Wang, Y.B., and Zhou, L.L. (2013) Types characteristics and time-space distribution of molybdenum deposits in China. International Geology Review, 55, 1311–1358.Suche in Google Scholar

Zhai, D.G., Liu, J.J., Zhang, H.Y., Yao, M.J., Wang, J.P., and Yang, Y.Q. (2014) S-Pb isotopic geochemistry, U-Pb and Re-Os geochronology of the Huanggangliang Fe-Sn deposit, Inner Mongolia, NE China. Ore Geology Reviews, 59, 109–122.Suche in Google Scholar

Zhai, D.G., Liu, J.J., Zhang, A.L., and Sun, Y.Q. (2017) U-Pb, Re-Os and 40Ar/39Ar geochronology of porphyry Sn ± Cu ± Mo and polymetallic (Ag-Pb-Zn-Cu) vein mineralization at Bianjiadayuan, Inner Mongolia, NE China: Implications for discrete mineralization events. Economic Geology, 112, 2041–2059.Suche in Google Scholar

Zhai, D.G., Liu, J.J., Cook, N.J., Wang, X.L., Yang, Y.Q., Zhang, A.L., and Jiao, Y.C. (2019) Mineralogical, textural, sulfur and lead isotope constraints on the origin of Ag-Pb-Zn mineralization at Bianjiadayuan, Inner Mongolia, NE China. Mineralium Deposita, 54, 47–66.Suche in Google Scholar

Zhai, D.G., Williams-Jones, A.E., Liu, J.J., Selby, D., Voudouris, P.C., Tombros, S., Li, K., Li, P.L., and Sun, H.J. (2020) The genesis of the giant Shuangjianzishan epithermal Ag-Pb-Zn deposit, Inner Mongolia, Northeastern China. Economic Geology, 115, 101–128.Suche in Google Scholar

Zhang, D.H., and Audétat, A. (2017) Chemistry mineralogy and crystallization conditions of porphyry Mo-forming magmas at Urad-Henderson and Silver Creek, Colorado, USA. Journal of Petrology, 58, 277–296.Suche in Google Scholar

Zhang, C., and Li, N. (2017) Geochronology and zircon Hf isotope geochemistry of granites in the giant Chalukou Mo deposit, NE China: Implications for tectonic setting. Ore Geology Reviews, 81, 780–793.Suche in Google Scholar

Zhang, F.F., Wang, Y.H., Liu, J.J., Wang, J.P., Zhao, C.B., and Song, Z.W. (2016) Origin of the Wunugetushan porphyry Cu-Mo deposit, Inner Mongolia, NE China: Constraints from geology, geochronology, geochemistry, and isotopic compositions. Journal of Asian Earth Sciences, 117, 208–224.Suche in Google Scholar

Zhang, Y.M., Gu, X.X., Liu, R.P., Sun, X., Li, X.L., and Zheng, L. (2017) Geology, geochronology and geochemistry of the Gaogangshan Mo deposit: A newly discovered Triassic collision-type Mo mineralization in the Lesser Xing’an Range, NE China. Ore Geology Reviews, 81, 672–688.Suche in Google Scholar

Zhang, H.Y., Su, L., Yang, L.M., Wang, D.C., Hu, X.L., Song, Y.T., and Xiong, L. (2019) Study on LA-ICP-MS determination of trace elements in sulfide minerals. Hans Journal of Chemical Engineering and Technology, 9, 401–409 (in Chinese with English abstract).Suche in Google Scholar

Zhao, Y., Lv, J.C., Chen, J., Zhang, P., Xu, J., and Bi, Z.W. (2016) Geological and S-Pb geochemical characteristics of Xinzhangfang molybdenum deposit in the northern Greater Khingan Mountains region. Nonferrous Metals, 68, 18–23 (in Chinese with English abstract).Suche in Google Scholar

Zhao, Q.Q., Zhai, D.G., Mathur, R., Liu, J.J., Selby, D., and Williams-Jones, A.E. (2021a) The giant Chalukou porphyry Mo deposit, Northeast China: The product of a short-lived, high flux mineralizing event. Economic Geology, 116, 1209–1225.Suche in Google Scholar

Zhao, Q.Q., Zhai, D.G., Wang, J.P., Liu, J.J., and Williams-Jones, A.E. (2021b) The geochemistry and geochronology of Permian granitoids from central Inner Mongolia, NE China: Petrogenesis and tectonic implications. Lithos, 404-405, 106489.Suche in Google Scholar

Zheng, Y.F., Mao, J.W., Chen, Y.J., Sun, W.D., Ni, P., and Yang, X.Y. (2019) Hydrothermal ore deposits in collisional orogens. Science Bulletin, 64, 205–212.Suche in Google Scholar

Zhou, J.B., Wilde, S.A., Zhang, X.Z., Zhao, G.C., Liu, F.L., Qiao, D.W., Ren, S.M., and Liu, J.H. (2011) A >1300 km late Pan-African metamorphic belt in NE China: New evidence from the Xing’an block and its tectonic implications. Tectonophysics, 509, 280–292.Suche in Google Scholar

Zhou, X., Fei, G.C., Zhou, Y., Wen, C.Q., Zhang, Y., and Yue, X.Y. (2015) Chronology and crust-mantle mixing of ore-forming porphyry of the Bangongco: Evidence from zircon U-Pb age and Hf isotopes of the Naruo porphyry copper-gold deposit. Acta Geologica Sinica—English Edition, 89, 217–228.Suche in Google Scholar

Zorin, Y.A., Zorina, L.D., Spiridonov, A.M., and Rutshtein, I.G. (2001) Geodynamic setting of gold deposits in eastern and central Trans-Baikal (Chita Region Russia). Ore Geology Reviews, 17, 215–232.Suche in Google Scholar
Received: 2021-05-20
Accepted: 2022-01-13
Published Online: 2023-01-03
Published in Print: 2023-01-27

© 2023 Mineralogical Society of America

Artikel in diesem Heft

  1. MSA Review
  2. Nickel in olivine as an exploration indicator for magmatic Ni-Cu sulfide deposits: A data review and re-evaluation
  3. Repeat, fast, and high-resolution mapping of fine-scale trace element distribution in pyrite and marcasite by LA-Q-ICP-MS with the Aerosol Rapid Introduction System (ARIS)
  4. Continuous Be mineralization from two-mica granite to pegmatite: Critical element enrichment processes in a Himalayan leucogranite pluton
  5. An evolutionary system of mineralogy, Part VI: Earth’s earliest Hadean crust (>4370 Ma)
  6. Oxidation or cation re-arrangement? Distinct behavior of riebeckite at high temperature
  7. Fe3+/FeT ratios of amphiboles determined by high spatial resolution single-crystal synchrotron Mössbauer spectroscopy
  8. How clay delamination supports aseismic slip
  9. The influence of Al2O3 on the structural properties of MgSiO3 akimotoite
  10. Atomistic insight into the ferroelastic post-stishovite transition by high-pressure single-crystal X-ray diffraction
  11. Epidote as a conveyor of water into the Earth’s deep mantle in subduction zones: Insights from coupled high-pressure and high-temperature experiments
  12. Potential link between antigorite dehydration and shallow intermediate-depth earthquakes in hot subduction zones
  13. Stability of Fe5O6 and its relation to other Fe-Mg-oxides at high pressures and temperatures
  14. From schwertmannite to natrojarosite: Long-term stability and kinetic approach
  15. Trace element and isotopic (S, Pb) constraints on the formation of the giant Chalukou porphyry Mo deposit, NE China
  16. Textural and chemical evolution of magnetite from the Paleozoic Shuanglong Fe-Cu deposit: Implications for tracing ore-forming fluids
  17. Jingwenite-(Y) from the Yushui Cu deposit, South China: The first occurrence of a V-HREE-bearing silicate mineral
  18. Wenjiite, Ti10(Si,P,◻)7, and kangjinlaite, Ti11(Si,P)10, new minerals in the ternary Ti-P-Si system from the Luobusa ophiolite, Tibet, China
  19. Evaluating the physicochemical conditions for gold occurrences in pyrite
  20. Letter
  21. Synthesis and structural analysis of CaFe2O4-type single crystals in the NaAlSiO4-MgAl2O4-Fe3O4 system
https://doi.org/10.2138/am-2022-8142
Schlagwörter für diesen Artikel
Sulfur and lead isotopes; trace element chemistry; porphyry Mo deposits; magma and fluid evolution; metal source and enrichment

Artikel in diesem Heft

  1. MSA Review
  2. Nickel in olivine as an exploration indicator for magmatic Ni-Cu sulfide deposits: A data review and re-evaluation
  3. Repeat, fast, and high-resolution mapping of fine-scale trace element distribution in pyrite and marcasite by LA-Q-ICP-MS with the Aerosol Rapid Introduction System (ARIS)
  4. Continuous Be mineralization from two-mica granite to pegmatite: Critical element enrichment processes in a Himalayan leucogranite pluton
  5. An evolutionary system of mineralogy, Part VI: Earth’s earliest Hadean crust (>4370 Ma)
  6. Oxidation or cation re-arrangement? Distinct behavior of riebeckite at high temperature
  7. Fe3+/FeT ratios of amphiboles determined by high spatial resolution single-crystal synchrotron Mössbauer spectroscopy
  8. How clay delamination supports aseismic slip
  9. The influence of Al2O3 on the structural properties of MgSiO3 akimotoite
  10. Atomistic insight into the ferroelastic post-stishovite transition by high-pressure single-crystal X-ray diffraction
  11. Epidote as a conveyor of water into the Earth’s deep mantle in subduction zones: Insights from coupled high-pressure and high-temperature experiments
  12. Potential link between antigorite dehydration and shallow intermediate-depth earthquakes in hot subduction zones
  13. Stability of Fe5O6 and its relation to other Fe-Mg-oxides at high pressures and temperatures
  14. From schwertmannite to natrojarosite: Long-term stability and kinetic approach
  15. Trace element and isotopic (S, Pb) constraints on the formation of the giant Chalukou porphyry Mo deposit, NE China
  16. Textural and chemical evolution of magnetite from the Paleozoic Shuanglong Fe-Cu deposit: Implications for tracing ore-forming fluids
  17. Jingwenite-(Y) from the Yushui Cu deposit, South China: The first occurrence of a V-HREE-bearing silicate mineral
  18. Wenjiite, Ti10(Si,P,◻)7, and kangjinlaite, Ti11(Si,P)10, new minerals in the ternary Ti-P-Si system from the Luobusa ophiolite, Tibet, China
  19. Evaluating the physicochemical conditions for gold occurrences in pyrite
  20. Letter
  21. Synthesis and structural analysis of CaFe2O4-type single crystals in the NaAlSiO4-MgAl2O4-Fe3O4 system
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 26.12.2025 von https://www.degruyterbrill.com/document/doi/10.2138/am-2022-8142/html?lang=de
Button zum nach oben scrollen