Extraction of Heavy Metals from Aqueous Medium by Husk Biomass: Adsorption Isotherm, Kinetic and Thermodynamic study
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Khalida Naseem
Abstract
This study describes the adsorption of Cu (II), Co (II) and Ni (II) ions from wastewater on Vigna radiata husk biomass. The ability of adsorbent to capture the metal ions has been found to be in the order of Ni (II)>Co (II) and Cu (II) depending upon the size and nature of metal ions to be adsorbed. It has been observed that percentage removal of Cu (II), Co (II) and Ni (II) ions increases with increase of adsorbent dosage, contact time and pH of the medium but up to a certain extent. Maximum adsorption capacity (qmax) for Cu (II), Co (II) and Ni (II) ions has been found to be 11.05, 15.04 and 19.88 mg/g, respectively, under optimum conditions of adsorbent dosage, contact time and pH of the medium. Langmuir model best fits the adsorption process with R2 value approaches to unity for all metal ions as compared to other models because adsorption sites are seemed to be equivalent and only monolayer adsorption may occur as a result of binding of metal ion with a functional moiety of adsorbent. Pseudo second order kinetic model best interprets the adsorption process of Cu (II), Co (II) and Ni (II) ions. Thermodynamic parameters such as negative value of Gibbs energy (∆G°) gives information about feasibility and spontaneity of the process. Adsorption process was found to be endothermic for Cu (II) ions while exothermic for Co (II) and Ni (II) ions as signified by the value of enthalpy change (∆H°). Husk biomass was recycled three times for removal of Ni (II) from aqueous medium to investigate its recoverability and reusability. Moreover V. radiata husk biomass has a potential to extract Cu (II) and Ni (II) from electroplating wastewater to overcome the industrial waste water pollution.
Acknowledgments
This work was supported by University of the Punjab, Lahore, Pakistan under research Grant No:/999/EST.I for the fiscal year of 2017–2018. A. Irfan and A. G. Al-Sehemi would like to acknowledge the support of the King Khalid University for this research through a grant RCAMS/KKU/005-18 under the (Research Center for Advanced Materials Science) at King Khalid University, Kingdom of Saudi Arabia.
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Supplementary Material
The online version of this article offers supplementary material (https://doi.org/10.1515/zpch-2018-1182).
©2019 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
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- Study of Intermolecular Interactions of CTAB with Amino Acids at Different Temperatures: A Multi Technique Approach
- The Differential Spectroscopic Investigation of Partitioning of Reactive Dyes in Micellar Media of Cationic Surfactant, Cetyl Trimethylammonium Bromide (CTAB)
- Extraction of Heavy Metals from Aqueous Medium by Husk Biomass: Adsorption Isotherm, Kinetic and Thermodynamic study
- Adsorption and Computational Studies for Evaluating the Behavior of Silicon Based Compounds as Novel Corrosion Inhibitors of Carbon Steel Surfaces in Acidic Media
- Volumetric, Viscosity and Conductance Studies of Solute–Solute and Solute–Solvent Interactions of Some Alkali Metal Chlorides in Aqueous Citric Acid at Different Temperatures
- Solubility and Thermodynamics of 6-Phenyl-4,5-dihydropyridazin-3(2H)-one in Various (PEG 400+Water) Mixtures
- Micellar Supported Ultrafiltration of Malachite Green: Experimental Verification of Theoretical Approach
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Artikel in diesem Heft
- Frontmatter
- Study of Intermolecular Interactions of CTAB with Amino Acids at Different Temperatures: A Multi Technique Approach
- The Differential Spectroscopic Investigation of Partitioning of Reactive Dyes in Micellar Media of Cationic Surfactant, Cetyl Trimethylammonium Bromide (CTAB)
- Extraction of Heavy Metals from Aqueous Medium by Husk Biomass: Adsorption Isotherm, Kinetic and Thermodynamic study
- Adsorption and Computational Studies for Evaluating the Behavior of Silicon Based Compounds as Novel Corrosion Inhibitors of Carbon Steel Surfaces in Acidic Media
- Volumetric, Viscosity and Conductance Studies of Solute–Solute and Solute–Solvent Interactions of Some Alkali Metal Chlorides in Aqueous Citric Acid at Different Temperatures
- Solubility and Thermodynamics of 6-Phenyl-4,5-dihydropyridazin-3(2H)-one in Various (PEG 400+Water) Mixtures
- Micellar Supported Ultrafiltration of Malachite Green: Experimental Verification of Theoretical Approach
- Experimental and Theoretical Study on the Interaction of P-Aminophenol Hydrochloride with H2O
