Home A novel samarium(III) orotate complex [NaSm(orotate)4(H2O)10]·3H2O – crystal structure and vibrational spectra
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A novel samarium(III) orotate complex [NaSm(orotate)4(H2O)10]·3H2O – crystal structure and vibrational spectra

  • Katarzyna Helios EMAIL logo , Marta Brzezińska and Tamara J. Bednarchuk
Published/Copyright: January 15, 2025
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 80 Issue 1-2

Abstract

A novel Sm(III) orotate complex, [NaSm(orotate)4(H2O)10]·3H2O, has been synthesized and its structure determined by single crystal X-ray diffraction and vibrational (IR and Raman) spectroscopic methods. The title compound crystallizes in the non-centrosymmetric orthorhombic space group Cmc21 with Z = 4. In the crystal structure, one of the two independent orotate ligands links the Sm(III) and Na(I) cations, forming chains. The second orotate ligand completes the coordination environment of the Na(I) ion, resulting in layers that are parallel to the ab plane. This arrangement leads to an extensive three-dimensional network structure, characterized by numerous intermolecular O–H⋯O and N–H⋯O interactions.

Keywords: crystal structure; Sm(III) orotate complexes; 2D structure; vibrational spectra
Corresponding author: Katarzyna Helios, Faculty of Chemistry, Wrocław University of Science and Technology, Smoluchowskiego 23, 50-370 Wrocław, Poland, E-mail:

Acknowledgements

K. Helios would like to thank Gniewko Soboń for assistance in the synthesis of the title complex.

  1. Research ethics: Not applicable.

  2. Informed consent: Not applicable.

  3. Author contributions: All authors have accepted responsibility for the entire content of this manuscript and approved its submission. Katarzyna Helios: Writing - Review & Editing, Visualization, Project administration, Investigation. Marta Brzezińska: Investigation. Tamara J. Bednarchuk: Writing - Review & Editing, Visualization, Investigation.

  4. Use of Large Language Models, AI and Machine Learning Tools: None declared.

  5. Conflict of interest: The authors state no conflict of interest.

  6. Research funding: Internal grant no 25, Faculty of Chemistry, Wrocław University of Science and Technology.

  7. Data availability: Not applicable.

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Supplementary Material

This article contains supplementary material (https://doi.org/10.1515/znb-2024-0091).

Received: 2024-09-30
Accepted: 2024-10-31
Published Online: 2025-01-15
Published in Print: 2025-01-29

© 2024 Walter de Gruyter GmbH, Berlin/Boston

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  7. (NH4)4[SO4][CB11H12]2: a new double salt with carbaborate anions crystallizing in a monoclinic variant of the anti-K2NiF4-type structure
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https://doi.org/10.1515/znb-2024-0091
Keywords for this article
crystal structure; Sm(III) orotate complexes; 2D structure; vibrational spectra

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Research Articles
  4. Polyphosphoric acid (PPA): a new, highly efficient catalyst for the synthesis of functionalized azepino phthalazine hybrids
  5. State-dependent gas chromatography based on flexible and tunable porous coordination polymers
  6. A novel samarium(III) orotate complex [NaSm(orotate)4(H2O)10]·3H2O – crystal structure and vibrational spectra
  7. (NH4)4[SO4][CB11H12]2: a new double salt with carbaborate anions crystallizing in a monoclinic variant of the anti-K2NiF4-type structure
  8. K[Hg(CN)2][H3CCOO]: a pseudo-double salt with mercury(II)-cyanide molecules imbedded into an ionic matrix of potassium acetate
  9. An aminosilyl-functionalized zincocene
  10. The stannide SrPd2.23Sn1.73 with CaBe2Ge2-type structure
  11. Note
  12. Revisiting Na[C(CN)3] – refinement of the crystal structure from X-ray powder diffraction data, the Raman and IR spectra
  13. Corrigendum
  14. Corrigendum zu: Die Serie caesiumhaltiger Thioarsenate(V) der Lanthanoide vom Formeltyp Cs3 Ln[AsS4]2 mit Ln = La–Nd und Sm
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