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Metal-free catalyzed arylsulfonylation of chloroquinoline with sodium arylsulfinates under microwave irradiation

  • Xi-Yong Li , Ya-Min Sun and Jin-Wei Yuan EMAIL logo
Published/Copyright: April 19, 2018
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 73 Issue 5

Abstract

An efficient protocol for the synthesis of 2-arylsulfonyl quinolines has been developed via a metal-free catalyzed cross-coupling reaction of chloroquinoline with sodium arylsulfinates in moderate-to-good yields under microwave irradiation. The reactions proceed with a wide range of substrates with good functional group tolerance.

Keywords: 2-arylsulfonyl quinolone; chloroquinoline; metal-free catalysis; sodium arylsulfinates; sulfonylation

Acknowledgments

We gratefully acknowledge the Department of Henan Province Natural Science and Technology Foundation (No. 172102210225), Natural Science Foundation in Henan Province Department of Education (No. 17A150005), the Program for Innovative Research Team from Zhengzhou (No. 131PCXTD605), and the Project of Youth Backbone Teachers of Henan University of Technology (2016).

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Supplemental Material:

The online version of this article offers supplementary ma(https://doi.org/10.1515/znb-2018-0007).

Received: 2018-1-6
Accepted: 2018-3-30
Published Online: 2018-4-19
Published in Print: 2018-5-24

©2018 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. In this Issue
  3. Synthesis of hexahydro-4-phenylquinoline-3-carbonitriles using Fe3O4@SiO2-SO3H nanoparticles as a superior and retrievable heterogeneous catalyst under ultrasonic irradiations
  4. 2-Naphthol-pyrazole conjugates as substrates in the Mannich reaction
  5. A heterotrimetallic Ni(II)–Dy(III) bis(salamo)-based complex: synthesis, structure and fluorescent property
  6. A highly effective and mild protocol for the production of 1-thioamidoalkyl-2-naphthols using 1,3-disulfonic acid imidazolium trifluoroacetate as a dual-functional catalyst
  7. Metal-free catalyzed arylsulfonylation of chloroquinoline with sodium arylsulfinates under microwave irradiation
  8. Triclinic conformational polymorph of N,N,N′,N′-tetrakis(2-cyanoethyl)-1,2-ethylenediamine (TCED)
  9. Lanthanide(III) complex metal-organic frameworks with a phenanthroline-carboxylate derivate and 2,5-thiophenedicarboxylate coligand: hydrothermal synthesis, crystal structure, and high thermostability
  10. Synthesis, crystal structure and photoluminescence of Re(I)2(μ-4,4′-bipyridine)(8-quinolinolato)2(CO)6
  11. A dinuclear molybdenum(VI) complex with a triaminoguanidine ligand: synthesis and structure of [Mo2O4(OH2)(DMF)(HtBu6L)]·3DMF ([H6tBu6L]Cl=tris(3,5-di-tert-butyl-2-hydroxybenzylidene)-triaminoguanidinium chloride)
  12. Syntheses and crystal structures of ruthenium complexes with bidentate salicylaldiminato and dithiophosphato ligands
  13. Synthesis and characterization of the new tin borate SnB8O11(OH)4
  14. Strukturen zweier Salze des Bis(thioharnstoff)gold(I)-Kations
  15. Book Review
  16. Metallo-Drugs: Development and Action of Anticancer Agents
https://doi.org/10.1515/znb-2018-0007
Keywords for this article
2-arylsulfonyl quinolone; chloroquinoline; metal-free catalysis; sodium arylsulfinates; sulfonylation

Articles in the same Issue

  1. Frontmatter
  2. In this Issue
  3. Synthesis of hexahydro-4-phenylquinoline-3-carbonitriles using Fe3O4@SiO2-SO3H nanoparticles as a superior and retrievable heterogeneous catalyst under ultrasonic irradiations
  4. 2-Naphthol-pyrazole conjugates as substrates in the Mannich reaction
  5. A heterotrimetallic Ni(II)–Dy(III) bis(salamo)-based complex: synthesis, structure and fluorescent property
  6. A highly effective and mild protocol for the production of 1-thioamidoalkyl-2-naphthols using 1,3-disulfonic acid imidazolium trifluoroacetate as a dual-functional catalyst
  7. Metal-free catalyzed arylsulfonylation of chloroquinoline with sodium arylsulfinates under microwave irradiation
  8. Triclinic conformational polymorph of N,N,N′,N′-tetrakis(2-cyanoethyl)-1,2-ethylenediamine (TCED)
  9. Lanthanide(III) complex metal-organic frameworks with a phenanthroline-carboxylate derivate and 2,5-thiophenedicarboxylate coligand: hydrothermal synthesis, crystal structure, and high thermostability
  10. Synthesis, crystal structure and photoluminescence of Re(I)2(μ-4,4′-bipyridine)(8-quinolinolato)2(CO)6
  11. A dinuclear molybdenum(VI) complex with a triaminoguanidine ligand: synthesis and structure of [Mo2O4(OH2)(DMF)(HtBu6L)]·3DMF ([H6tBu6L]Cl=tris(3,5-di-tert-butyl-2-hydroxybenzylidene)-triaminoguanidinium chloride)
  12. Syntheses and crystal structures of ruthenium complexes with bidentate salicylaldiminato and dithiophosphato ligands
  13. Synthesis and characterization of the new tin borate SnB8O11(OH)4
  14. Strukturen zweier Salze des Bis(thioharnstoff)gold(I)-Kations
  15. Book Review
  16. Metallo-Drugs: Development and Action of Anticancer Agents
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