Startseite Synthesis and Characterization of Bromo- and Bromochloroplumbates(II). Crystal Structures of [Ph4E]2[Pb3Br8] (E = P, As) and [Ph4P][PbBrCl2] • CH3CN
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Synthesis and Characterization of Bromo- and Bromochloroplumbates(II). Crystal Structures of [Ph4E]2[Pb3Br8] (E = P, As) and [Ph4P][PbBrCl2] • CH3CN

  • Thomas M. Klapötke EMAIL logo , Burkhard Krumm , Kurt Polbom und Claudia M. Rienäcker
Veröffentlicht/Copyright: 2. Juni 2014
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Zeitschrift für Naturforschung B
Aus der Zeitschrift Zeitschrift für Naturforschung B Band 55 Heft 5

[Ph4P]2[Pb3Br8] and [Ph4As]2[Pb3Br8] crystallize both in the monoclinic space group P 21/n. The lattice parameters of [Ph4P]2[Pb3Br8] are a = 14.637(7), b = 8.151(3), c = 23.388(8) Å, β = 106.02(3)°, Z = 2 and of [Ph4As]2[Pb3Br8] are a = 14.697(7), b = 8.219(3), c = 23.527(8) Å, β = 106.27(3)°, Z = 2. The lattice parameters of [Ph4P][PbBrCl2]·CH3CN, which crystallizes in the triclinic space group (P 1̅), are a = 9.435(3), b = 10.2577(14), c = 14.055(2) Å, α = 88.320(11)°, β = 84.82(2)°, γ = 84.19(2)°, Z = 2. 207Pb NMR shifts of halogenoplumbates in solution are reported.

Keywords: Tetraphenylphosphonium(arsonium) Octabromotriplumbate; Tetraphenylphosphonium Bromodichloroplumbate; Quantum Chemical Calculations
Received: 2000-1-18
Published Online: 2014-6-2
Published in Print: 2000-5-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Artikel in diesem Heft

  1. Crystal and Molecular Structures of the Sulfurization and Selenation Products of Bis[bis(trimethylsilyl)amino]germanium(II). Crystal Structure of (Triphenylphosphine)gold(I) Bis(trimethylsilyl)amide
  2. New Diazasilaphosphetidines and their Precursors
  3. The Solid State Conformation of Diaryl Ditellurides and Diselenides: The Crystal and Molecular Structures of (C4H3E2)2E'2 (E = O, S; E' = Te, Se)
  4. Asymmetrische Katalyse, 134 [1]. Naproxen-Derivate durch enantioselektive Decarboxylierung / Asymmetrische Katalyse, 134 [1]. Naproxen-Derivate durch enantioselektive Decarboxylierung
  5. Synthesis and Structure of a Palladium(II) Chloride Complex with 2-(2-Methyl-3-phenyl-isoxazolidin-5-yl)-pyridine
  6. Synthesis and Characterization of Bromo- and Bromochloroplumbates(II). Crystal Structures of [Ph4E]2[Pb3Br8] (E = P, As) and [Ph4P][PbBrCl2] • CH3CN
  7. Kristallstruktur und schwingungsspektroskopische Daten von Silbercyanamid / Crystal Structure and Spectroscopic Data of Silver Cyanamide
  8. Luminescence Detection and Photodimerization of 1,3-Dimethyluracil Coordinated to Copper(I)
  9. Supersilylsilane R*SiX3: Darstellung, Charakterisierung und Strukturen; sterische und van-der-Waals Effekte der Substituenten X [1] / Supersilylsilanes R*SiX3: Syntheses, Characterization and Structures; Steric and van-der-Waals Effects of Substituents X [1]
  10. Supersilylsilane R*SiX3: Umwandlung in Disilane R*X2Si-SiX2R*, Silylene R*XSi, Cyclosilane (R*XSi)n, Disilene R*XSi=SiXR*, Tetrasupersilyl-tetrahedro-tetrasilan [1] / Supersilylsilanes R*SiX3: Conversion into Disilanes R*X2Si-SiX2R*, Silylenes R*XSi, Cyclosilanes (R*XSi)n, D isilenes R*XSi=SiXR*, Tetrasupersilyl-tetrahedro-tetrasilane [1]
  11. Chemistry of Seven-Membered Heterocycles, VI. Synthesis of Novel Bicyclic Heterocyclic Compounds as Potential Anticancer and Anti-HIV Agents
  12. Crystal Structure and Properties of the Titanium Stannide Ti2Sn3
  13. Regeneration of Carbonyl Compounds from Oximes under Microwave Irradiation in Solventless System
  14. Umsetzung von N-Alkylpyridinium-Salzen mit Hydroxylamin / Reaction of N-Alkylpyridinium Salts with Hydroxylamine
  15. Enaminouraciles as Precursors for Synthesis of Pyrimido[4,5-a]pyrimidine- 2,4-diones
  16. [Co4(ν3-NPEt3)2(HNPEt3)2(O2C-CH3)2- (ν-OSiMe2OSiMe2O)2] - ein vierkerniger Cobalt(II)-Komplex mit Leiterstruktur / [Co4(ν3-NPEt3)2(HNPEt3)2(O2C-CH3)2-(ν-OSiMe2OSiMe2O)2] - a Tetranuclear Cobalt(II) Complex with Ladder Structure
https://doi.org/10.1515/znb-2000-0506
Schlagwörter für diesen Artikel
Tetraphenylphosphonium(arsonium) Octabromotriplumbate; Tetraphenylphosphonium Bromodichloroplumbate; Quantum Chemical Calculations

Artikel in diesem Heft

  1. Crystal and Molecular Structures of the Sulfurization and Selenation Products of Bis[bis(trimethylsilyl)amino]germanium(II). Crystal Structure of (Triphenylphosphine)gold(I) Bis(trimethylsilyl)amide
  2. New Diazasilaphosphetidines and their Precursors
  3. The Solid State Conformation of Diaryl Ditellurides and Diselenides: The Crystal and Molecular Structures of (C4H3E2)2E'2 (E = O, S; E' = Te, Se)
  4. Asymmetrische Katalyse, 134 [1]. Naproxen-Derivate durch enantioselektive Decarboxylierung / Asymmetrische Katalyse, 134 [1]. Naproxen-Derivate durch enantioselektive Decarboxylierung
  5. Synthesis and Structure of a Palladium(II) Chloride Complex with 2-(2-Methyl-3-phenyl-isoxazolidin-5-yl)-pyridine
  6. Synthesis and Characterization of Bromo- and Bromochloroplumbates(II). Crystal Structures of [Ph4E]2[Pb3Br8] (E = P, As) and [Ph4P][PbBrCl2] • CH3CN
  7. Kristallstruktur und schwingungsspektroskopische Daten von Silbercyanamid / Crystal Structure and Spectroscopic Data of Silver Cyanamide
  8. Luminescence Detection and Photodimerization of 1,3-Dimethyluracil Coordinated to Copper(I)
  9. Supersilylsilane R*SiX3: Darstellung, Charakterisierung und Strukturen; sterische und van-der-Waals Effekte der Substituenten X [1] / Supersilylsilanes R*SiX3: Syntheses, Characterization and Structures; Steric and van-der-Waals Effects of Substituents X [1]
  10. Supersilylsilane R*SiX3: Umwandlung in Disilane R*X2Si-SiX2R*, Silylene R*XSi, Cyclosilane (R*XSi)n, Disilene R*XSi=SiXR*, Tetrasupersilyl-tetrahedro-tetrasilan [1] / Supersilylsilanes R*SiX3: Conversion into Disilanes R*X2Si-SiX2R*, Silylenes R*XSi, Cyclosilanes (R*XSi)n, D isilenes R*XSi=SiXR*, Tetrasupersilyl-tetrahedro-tetrasilane [1]
  11. Chemistry of Seven-Membered Heterocycles, VI. Synthesis of Novel Bicyclic Heterocyclic Compounds as Potential Anticancer and Anti-HIV Agents
  12. Crystal Structure and Properties of the Titanium Stannide Ti2Sn3
  13. Regeneration of Carbonyl Compounds from Oximes under Microwave Irradiation in Solventless System
  14. Umsetzung von N-Alkylpyridinium-Salzen mit Hydroxylamin / Reaction of N-Alkylpyridinium Salts with Hydroxylamine
  15. Enaminouraciles as Precursors for Synthesis of Pyrimido[4,5-a]pyrimidine- 2,4-diones
  16. [Co4(ν3-NPEt3)2(HNPEt3)2(O2C-CH3)2- (ν-OSiMe2OSiMe2O)2] - ein vierkerniger Cobalt(II)-Komplex mit Leiterstruktur / [Co4(ν3-NPEt3)2(HNPEt3)2(O2C-CH3)2-(ν-OSiMe2OSiMe2O)2] - a Tetranuclear Cobalt(II) Complex with Ladder Structure
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