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Synthesis and Structure of a Palladium(II) Chloride Complex with 2-(2-Methyl-3-phenyl-isoxazolidin-5-yl)-pyridine

  • Andrey B. Lysenko , Oleg V. Shishkin and Rostislav D. Lampeka EMAIL logo
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 55 Issue 5

The 1:1 complex of palladium(II) chloride with 2-(2-methyl-3-phenyl-isoxazolidin-5-yl)- pyridine (L) has been prepared and studied by means of elemental analysis, 1H NMR spectroscopy and X-ray diffraction (monoclinic, space group P21/n with parameters: a = 8.141(2), b = 9.750(2),c = 20.691(6)Å ,β = 95.62(3)°,V = 1634.4(7)Å3 ,Z = 4 ;R1= 0.054 and wR2= 0.144 for 3352 unique reflections). A square-planar coordination polyhedron has been established for the palladium atom both in acetone solution and in the solid state. The organic ligand is coordinated toometal in a bidentate manner via nitrogen atoms of the pyridine substituent (Pd-N(2) 2.125(3) Å) and the isoxazolidine heterocycle (Pd-N(l) 2.102(3) Å). The other two coordination positions of palladium are occupied by chlorine atoms (Pd-Cl(l) 2.321(1) and Pd-Cl(2) 2.333(1) Å). The six-membered chelate ring formed by Pd, N(2), C(4), C(1), 0(1) and N (1) possesses a “twist-tub” conformation. The isoxazolidine cycle has an envelope conformation with an equatorial orientation of the methyl group.

Keywords: Isoxazolidines; Palladium(II) Complexes; IR Data
Received: 1999-12-22
Published Online: 2014-6-2
Published in Print: 2000-5-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Crystal and Molecular Structures of the Sulfurization and Selenation Products of Bis[bis(trimethylsilyl)amino]germanium(II). Crystal Structure of (Triphenylphosphine)gold(I) Bis(trimethylsilyl)amide
  2. New Diazasilaphosphetidines and their Precursors
  3. The Solid State Conformation of Diaryl Ditellurides and Diselenides: The Crystal and Molecular Structures of (C4H3E2)2E'2 (E = O, S; E' = Te, Se)
  4. Asymmetrische Katalyse, 134 [1]. Naproxen-Derivate durch enantioselektive Decarboxylierung / Asymmetrische Katalyse, 134 [1]. Naproxen-Derivate durch enantioselektive Decarboxylierung
  5. Synthesis and Structure of a Palladium(II) Chloride Complex with 2-(2-Methyl-3-phenyl-isoxazolidin-5-yl)-pyridine
  6. Synthesis and Characterization of Bromo- and Bromochloroplumbates(II). Crystal Structures of [Ph4E]2[Pb3Br8] (E = P, As) and [Ph4P][PbBrCl2] • CH3CN
  7. Kristallstruktur und schwingungsspektroskopische Daten von Silbercyanamid / Crystal Structure and Spectroscopic Data of Silver Cyanamide
  8. Luminescence Detection and Photodimerization of 1,3-Dimethyluracil Coordinated to Copper(I)
  9. Supersilylsilane R*SiX3: Darstellung, Charakterisierung und Strukturen; sterische und van-der-Waals Effekte der Substituenten X [1] / Supersilylsilanes R*SiX3: Syntheses, Characterization and Structures; Steric and van-der-Waals Effects of Substituents X [1]
  10. Supersilylsilane R*SiX3: Umwandlung in Disilane R*X2Si-SiX2R*, Silylene R*XSi, Cyclosilane (R*XSi)n, Disilene R*XSi=SiXR*, Tetrasupersilyl-tetrahedro-tetrasilan [1] / Supersilylsilanes R*SiX3: Conversion into Disilanes R*X2Si-SiX2R*, Silylenes R*XSi, Cyclosilanes (R*XSi)n, D isilenes R*XSi=SiXR*, Tetrasupersilyl-tetrahedro-tetrasilane [1]
  11. Chemistry of Seven-Membered Heterocycles, VI. Synthesis of Novel Bicyclic Heterocyclic Compounds as Potential Anticancer and Anti-HIV Agents
  12. Crystal Structure and Properties of the Titanium Stannide Ti2Sn3
  13. Regeneration of Carbonyl Compounds from Oximes under Microwave Irradiation in Solventless System
  14. Umsetzung von N-Alkylpyridinium-Salzen mit Hydroxylamin / Reaction of N-Alkylpyridinium Salts with Hydroxylamine
  15. Enaminouraciles as Precursors for Synthesis of Pyrimido[4,5-a]pyrimidine- 2,4-diones
  16. [Co4(ν3-NPEt3)2(HNPEt3)2(O2C-CH3)2- (ν-OSiMe2OSiMe2O)2] - ein vierkerniger Cobalt(II)-Komplex mit Leiterstruktur / [Co4(ν3-NPEt3)2(HNPEt3)2(O2C-CH3)2-(ν-OSiMe2OSiMe2O)2] - a Tetranuclear Cobalt(II) Complex with Ladder Structure
https://doi.org/10.1515/znb-2000-0505
Keywords for this article
Isoxazolidines; Palladium(II) Complexes; IR Data

Articles in the same Issue

  1. Crystal and Molecular Structures of the Sulfurization and Selenation Products of Bis[bis(trimethylsilyl)amino]germanium(II). Crystal Structure of (Triphenylphosphine)gold(I) Bis(trimethylsilyl)amide
  2. New Diazasilaphosphetidines and their Precursors
  3. The Solid State Conformation of Diaryl Ditellurides and Diselenides: The Crystal and Molecular Structures of (C4H3E2)2E'2 (E = O, S; E' = Te, Se)
  4. Asymmetrische Katalyse, 134 [1]. Naproxen-Derivate durch enantioselektive Decarboxylierung / Asymmetrische Katalyse, 134 [1]. Naproxen-Derivate durch enantioselektive Decarboxylierung
  5. Synthesis and Structure of a Palladium(II) Chloride Complex with 2-(2-Methyl-3-phenyl-isoxazolidin-5-yl)-pyridine
  6. Synthesis and Characterization of Bromo- and Bromochloroplumbates(II). Crystal Structures of [Ph4E]2[Pb3Br8] (E = P, As) and [Ph4P][PbBrCl2] • CH3CN
  7. Kristallstruktur und schwingungsspektroskopische Daten von Silbercyanamid / Crystal Structure and Spectroscopic Data of Silver Cyanamide
  8. Luminescence Detection and Photodimerization of 1,3-Dimethyluracil Coordinated to Copper(I)
  9. Supersilylsilane R*SiX3: Darstellung, Charakterisierung und Strukturen; sterische und van-der-Waals Effekte der Substituenten X [1] / Supersilylsilanes R*SiX3: Syntheses, Characterization and Structures; Steric and van-der-Waals Effects of Substituents X [1]
  10. Supersilylsilane R*SiX3: Umwandlung in Disilane R*X2Si-SiX2R*, Silylene R*XSi, Cyclosilane (R*XSi)n, Disilene R*XSi=SiXR*, Tetrasupersilyl-tetrahedro-tetrasilan [1] / Supersilylsilanes R*SiX3: Conversion into Disilanes R*X2Si-SiX2R*, Silylenes R*XSi, Cyclosilanes (R*XSi)n, D isilenes R*XSi=SiXR*, Tetrasupersilyl-tetrahedro-tetrasilane [1]
  11. Chemistry of Seven-Membered Heterocycles, VI. Synthesis of Novel Bicyclic Heterocyclic Compounds as Potential Anticancer and Anti-HIV Agents
  12. Crystal Structure and Properties of the Titanium Stannide Ti2Sn3
  13. Regeneration of Carbonyl Compounds from Oximes under Microwave Irradiation in Solventless System
  14. Umsetzung von N-Alkylpyridinium-Salzen mit Hydroxylamin / Reaction of N-Alkylpyridinium Salts with Hydroxylamine
  15. Enaminouraciles as Precursors for Synthesis of Pyrimido[4,5-a]pyrimidine- 2,4-diones
  16. [Co4(ν3-NPEt3)2(HNPEt3)2(O2C-CH3)2- (ν-OSiMe2OSiMe2O)2] - ein vierkerniger Cobalt(II)-Komplex mit Leiterstruktur / [Co4(ν3-NPEt3)2(HNPEt3)2(O2C-CH3)2-(ν-OSiMe2OSiMe2O)2] - a Tetranuclear Cobalt(II) Complex with Ladder Structure
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