Startseite Kristallstruktur und schwingungsspektroskopische Daten von Silbercyanamid / Crystal Structure and Spectroscopic Data of Silver Cyanamide
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Kristallstruktur und schwingungsspektroskopische Daten von Silbercyanamid / Crystal Structure and Spectroscopic Data of Silver Cyanamide

  • Michael Becker , Jürgen Nuss und Martin Jansen EMAIL logo
Veröffentlicht/Copyright: 2. Juni 2014
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Ag2CN2 precipitates on mixing aqueous solutions of H2CN2 and silver nitrate as a yellow crystalline solid. The title compound was characterised by single crystal X-ray diffraction and IR-spectroscopy (monoclinic, P21/c (No. 14), a = 7.315(1), b = 6.010(1), c = 6.684(1) Å; β = 102.29( 1)°; Z = 4). The anion is slightly bent (177.1 (5)°) and exhibits two significantly different bond lengths (C-N(l): 1.194(6), C-N(2): 1.266(5) Å).

Received: 2000-1-27
Published Online: 2014-6-2
Published in Print: 2000-5-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

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