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Crystal and Molecular Structures of the Sulfurization and Selenation Products of Bis[bis(trimethylsilyl)amino]germanium(II). Crystal Structure of (Triphenylphosphine)gold(I) Bis(trimethylsilyl)amide

  • Gerald L. Wegner , Alexander Jockisch , Annette Schier and Hubert Schmidbaur EMAIL logo
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 55 Issue 5

Treatment of bis[bis(trimethylsilyl)amino]germanium(II) with elemental sulfur or selenium affords high yields of the corresponding monosulfide [(Me3Si)2N]2GeS and selenide [(Me3Si)2N]2GeSe, respectively. The crystalline products have now been shown to be cyclic dimers with (GeS/Se)2 four-membered rings by X-ray single crystal structure analysis. The crystal structure of (triphenylphosphine)gold(I) bis(trimethylsilyl)amide (Ph3P)Au-N(SiMe3)2 has also been determined. The molecule is a monomer with a tricoordinate nitrogen atom in a planar configuration [Si2NAu]. The compound does not undergo insertion of the bis[bis(trimethylsilyl)amino]germylene.

Keywords: Germylenes; Germanium(II) Amides; Sulfurization
Received: 2000-3-8
Published Online: 2014-6-2
Published in Print: 2000-5-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Crystal and Molecular Structures of the Sulfurization and Selenation Products of Bis[bis(trimethylsilyl)amino]germanium(II). Crystal Structure of (Triphenylphosphine)gold(I) Bis(trimethylsilyl)amide
  2. New Diazasilaphosphetidines and their Precursors
  3. The Solid State Conformation of Diaryl Ditellurides and Diselenides: The Crystal and Molecular Structures of (C4H3E2)2E'2 (E = O, S; E' = Te, Se)
  4. Asymmetrische Katalyse, 134 [1]. Naproxen-Derivate durch enantioselektive Decarboxylierung / Asymmetrische Katalyse, 134 [1]. Naproxen-Derivate durch enantioselektive Decarboxylierung
  5. Synthesis and Structure of a Palladium(II) Chloride Complex with 2-(2-Methyl-3-phenyl-isoxazolidin-5-yl)-pyridine
  6. Synthesis and Characterization of Bromo- and Bromochloroplumbates(II). Crystal Structures of [Ph4E]2[Pb3Br8] (E = P, As) and [Ph4P][PbBrCl2] • CH3CN
  7. Kristallstruktur und schwingungsspektroskopische Daten von Silbercyanamid / Crystal Structure and Spectroscopic Data of Silver Cyanamide
  8. Luminescence Detection and Photodimerization of 1,3-Dimethyluracil Coordinated to Copper(I)
  9. Supersilylsilane R*SiX3: Darstellung, Charakterisierung und Strukturen; sterische und van-der-Waals Effekte der Substituenten X [1] / Supersilylsilanes R*SiX3: Syntheses, Characterization and Structures; Steric and van-der-Waals Effects of Substituents X [1]
  10. Supersilylsilane R*SiX3: Umwandlung in Disilane R*X2Si-SiX2R*, Silylene R*XSi, Cyclosilane (R*XSi)n, Disilene R*XSi=SiXR*, Tetrasupersilyl-tetrahedro-tetrasilan [1] / Supersilylsilanes R*SiX3: Conversion into Disilanes R*X2Si-SiX2R*, Silylenes R*XSi, Cyclosilanes (R*XSi)n, D isilenes R*XSi=SiXR*, Tetrasupersilyl-tetrahedro-tetrasilane [1]
  11. Chemistry of Seven-Membered Heterocycles, VI. Synthesis of Novel Bicyclic Heterocyclic Compounds as Potential Anticancer and Anti-HIV Agents
  12. Crystal Structure and Properties of the Titanium Stannide Ti2Sn3
  13. Regeneration of Carbonyl Compounds from Oximes under Microwave Irradiation in Solventless System
  14. Umsetzung von N-Alkylpyridinium-Salzen mit Hydroxylamin / Reaction of N-Alkylpyridinium Salts with Hydroxylamine
  15. Enaminouraciles as Precursors for Synthesis of Pyrimido[4,5-a]pyrimidine- 2,4-diones
  16. [Co4(ν3-NPEt3)2(HNPEt3)2(O2C-CH3)2- (ν-OSiMe2OSiMe2O)2] - ein vierkerniger Cobalt(II)-Komplex mit Leiterstruktur / [Co4(ν3-NPEt3)2(HNPEt3)2(O2C-CH3)2-(ν-OSiMe2OSiMe2O)2] - a Tetranuclear Cobalt(II) Complex with Ladder Structure
https://doi.org/10.1515/znb-2000-0501
Keywords for this article
Germylenes; Germanium(II) Amides; Sulfurization

Articles in the same Issue

  1. Crystal and Molecular Structures of the Sulfurization and Selenation Products of Bis[bis(trimethylsilyl)amino]germanium(II). Crystal Structure of (Triphenylphosphine)gold(I) Bis(trimethylsilyl)amide
  2. New Diazasilaphosphetidines and their Precursors
  3. The Solid State Conformation of Diaryl Ditellurides and Diselenides: The Crystal and Molecular Structures of (C4H3E2)2E'2 (E = O, S; E' = Te, Se)
  4. Asymmetrische Katalyse, 134 [1]. Naproxen-Derivate durch enantioselektive Decarboxylierung / Asymmetrische Katalyse, 134 [1]. Naproxen-Derivate durch enantioselektive Decarboxylierung
  5. Synthesis and Structure of a Palladium(II) Chloride Complex with 2-(2-Methyl-3-phenyl-isoxazolidin-5-yl)-pyridine
  6. Synthesis and Characterization of Bromo- and Bromochloroplumbates(II). Crystal Structures of [Ph4E]2[Pb3Br8] (E = P, As) and [Ph4P][PbBrCl2] • CH3CN
  7. Kristallstruktur und schwingungsspektroskopische Daten von Silbercyanamid / Crystal Structure and Spectroscopic Data of Silver Cyanamide
  8. Luminescence Detection and Photodimerization of 1,3-Dimethyluracil Coordinated to Copper(I)
  9. Supersilylsilane R*SiX3: Darstellung, Charakterisierung und Strukturen; sterische und van-der-Waals Effekte der Substituenten X [1] / Supersilylsilanes R*SiX3: Syntheses, Characterization and Structures; Steric and van-der-Waals Effects of Substituents X [1]
  10. Supersilylsilane R*SiX3: Umwandlung in Disilane R*X2Si-SiX2R*, Silylene R*XSi, Cyclosilane (R*XSi)n, Disilene R*XSi=SiXR*, Tetrasupersilyl-tetrahedro-tetrasilan [1] / Supersilylsilanes R*SiX3: Conversion into Disilanes R*X2Si-SiX2R*, Silylenes R*XSi, Cyclosilanes (R*XSi)n, D isilenes R*XSi=SiXR*, Tetrasupersilyl-tetrahedro-tetrasilane [1]
  11. Chemistry of Seven-Membered Heterocycles, VI. Synthesis of Novel Bicyclic Heterocyclic Compounds as Potential Anticancer and Anti-HIV Agents
  12. Crystal Structure and Properties of the Titanium Stannide Ti2Sn3
  13. Regeneration of Carbonyl Compounds from Oximes under Microwave Irradiation in Solventless System
  14. Umsetzung von N-Alkylpyridinium-Salzen mit Hydroxylamin / Reaction of N-Alkylpyridinium Salts with Hydroxylamine
  15. Enaminouraciles as Precursors for Synthesis of Pyrimido[4,5-a]pyrimidine- 2,4-diones
  16. [Co4(ν3-NPEt3)2(HNPEt3)2(O2C-CH3)2- (ν-OSiMe2OSiMe2O)2] - ein vierkerniger Cobalt(II)-Komplex mit Leiterstruktur / [Co4(ν3-NPEt3)2(HNPEt3)2(O2C-CH3)2-(ν-OSiMe2OSiMe2O)2] - a Tetranuclear Cobalt(II) Complex with Ladder Structure
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