Home β-Diketonates and their Analogs: Stabilization of the Dimeric M2{L}4(D)2 (M = Co, Ni) Core in the Complexes with Dimethyl-N-trichloroacetylamidophosphate {Cl3C(O)NP(O)(OCH3)2}-
Article
Licensed
Unlicensed Requires Authentication

β-Diketonates and their Analogs: Stabilization of the Dimeric M2{L}4(D)2 (M = Co, Ni) Core in the Complexes with Dimethyl-N-trichloroacetylamidophosphate {Cl3C(O)NP(O)(OCH3)2}-

  • Elizaveta A. Bundya , Vladimir M. Amirkhanov , Vladimir A. Ovchynnikov , Victor A. Trush , Konstantin V. Domasevitch , Joachim Sieler and Victor V. Skopenko
Published/Copyright: June 2, 2014
Become an author with De Gruyter Brill
Author Information Explore this Subject
Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 54 Issue 8

The coordination compounds of general formula [M{X}2(2-propanol)]2 (M = Co(II) (1), Ni(II) (2); {X} = Cl3CC(O)NP(O)(OCH3)2) have been prepared and characterized by means of IR, UV-VIS spectroscopy and X-ray analysis. The compounds are isomorphous according to X-ray powder diffraction studies. Crystal data for 1: triclinic, P1̄, with a = 9.510(2), b = 12.053(2), c = 23.594(5) Å ,a = 84.74(3), b = 86.47(3), g = 75.45(3)°, Z = 2, V = 2604.7(9) Å3, R1 = 0.067, wR2 = 0.143 for 6299 unique reflection used). The complex adopts a dimeric centrosymmetric molecular array with Co-O-Co bridges formed via the oxygen atoms of phosphoryl groups. This structure is stabilized by intradimeric hydrogen bonds of the type P = O---H with the coordinated 2-propanol. The metal atoms are coordinated in slightly distorted octahedra (Co-O 2.050(5)-2.140(5) Å). Unlike the β-diketonate compounds of similar structure, the dimeric complexes are stable towards donor species and in 2-propanol solution.

: Carbacylamidophosphates; β-Diketonates; Cobalt(II); Nickel(II); X-Ray Data
Received: 1998-11-24
Published Online: 2014-6-2
Published in Print: 1999-8-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Darstellung und Eigenschaften von Tetra(n-butyl)ammonium-cis-diacidooxophthalocyaninato( 2-)niobaten(V) und -tantalaten(V); Kristallstruktur von (nBu4N)CIS[Nb(F)2Opc2-]
  2. Metallkomplexe mit biologisch wichtigen Liganden, CXXI [1]. Orthopalladierte Enolate aus N-(Diphenylmethylen)-Schiff-Basen von a-Aminosäureestern als ambivalente 1,3-Dipole in [2+3]-Cycloadditionsreaktionen. Strukturen einer Reihe von Cycloaddukten
  3. Metallkomplexe mit biologisch wichtigen Liganden, CXX [1]. Halbsandwich-Komplexe von Ruthenium(II) und Iridium(III) mit 3-(3-Pyridyl)-D-alaninat
  4. Metallboranate und Boranatometallate, 25. 25Mg-Kernresonanzuntersuchungen an Magnesiumboranaten [1]
  5. Kristallstruktur, Infrarot- und Ramanspektren sowie thermische Zersetzung von Magnesiumtetrahydrogendimesoperiodat, MgH4I2O10 · 6H2O
  6. Kristallstrukturen, Schwingungsspektren und Normalkoordinatenanalyse von cis-(n-Bu4N)2[ReBr4(NCS)(SCN)], trans-(n-Bu4N)2[ReBr4(NCS)(SCN)] und trans-(n-Bu4N)2[ReBr4(NCSe)(SeCN)]
  7. Serendipitous Formation of the Cyclic Sulfite DIMTH(SO3) by Reaction of DIMTH(OH)2 with SOCl2
  8. Neue Tetraaminophosphonium-Salze durch Anionenaustausch in flüssigem Ammoniak
  9. The Crystal Structure of N,N′-Bis-(1,3-dihydroxy-2-methylprop-2-yl)- pyrazine-2,3-dicarboxamide Semihydrate
  10. β-Diketonates and their Analogs: Stabilization of the Dimeric M2{L}4(D)2 (M = Co, Ni) Core in the Complexes with Dimethyl-N-trichloroacetylamidophosphate {Cl3C(O)NP(O)(OCH3)2}-
  11. Synthesis and Electronic Spectra of Tricarbonylrhenium(I) Chloride Complexes with 9,10-Phenanthrenequinone and 9,10-Phenanthrenequinone Diimine as Acceptor Ligands
  12. Synthesis of Benzisochalcogenol and -azole Derivatives via ortho Metalation of Isophthalamides
  13. Synthesis, Reactions and Spectroscopy of 3-Benzoyl-6-phenylpyridazines of Expected Biological Activity
  14. Imidazole Nucleosides, V. Synthesis of 3′-Fluoro-3′-deoxy-ribofuranosides of 4(5)-Amino-imidazoIe-5(4)carboxamide
  15. Synthetic Potential Inherent in D-Isoascorbic Acid as a Precursor for Pyridazine and Furo[3,2-c]pyridazine Ring Systems with Two Asymmetric Centers
  16. Chiral Pool Synthesis of 4a-Substituted Carbocyclic Cyclopentanoid Nucleoside Precursors, I
  17. Chiral Pool Synthesis of 4a-Substituted Carbocyclic Cyclopentanoid Nucleoside Precursors, II
  18. Die Kristallstruktur von Bis(bromotriphenyl) arsen(V)-hexabromotellurat( IV), [Ph3AsBr]2[TeBr6]
  19. Darstellung und Kristallstruktur von Hexacaesium-hexatelluridodigermanat( III) (Cs6Ge2Te6)
https://doi.org/10.1515/znb-1999-0810

Articles in the same Issue

  1. Darstellung und Eigenschaften von Tetra(n-butyl)ammonium-cis-diacidooxophthalocyaninato( 2-)niobaten(V) und -tantalaten(V); Kristallstruktur von (nBu4N)CIS[Nb(F)2Opc2-]
  2. Metallkomplexe mit biologisch wichtigen Liganden, CXXI [1]. Orthopalladierte Enolate aus N-(Diphenylmethylen)-Schiff-Basen von a-Aminosäureestern als ambivalente 1,3-Dipole in [2+3]-Cycloadditionsreaktionen. Strukturen einer Reihe von Cycloaddukten
  3. Metallkomplexe mit biologisch wichtigen Liganden, CXX [1]. Halbsandwich-Komplexe von Ruthenium(II) und Iridium(III) mit 3-(3-Pyridyl)-D-alaninat
  4. Metallboranate und Boranatometallate, 25. 25Mg-Kernresonanzuntersuchungen an Magnesiumboranaten [1]
  5. Kristallstruktur, Infrarot- und Ramanspektren sowie thermische Zersetzung von Magnesiumtetrahydrogendimesoperiodat, MgH4I2O10 · 6H2O
  6. Kristallstrukturen, Schwingungsspektren und Normalkoordinatenanalyse von cis-(n-Bu4N)2[ReBr4(NCS)(SCN)], trans-(n-Bu4N)2[ReBr4(NCS)(SCN)] und trans-(n-Bu4N)2[ReBr4(NCSe)(SeCN)]
  7. Serendipitous Formation of the Cyclic Sulfite DIMTH(SO3) by Reaction of DIMTH(OH)2 with SOCl2
  8. Neue Tetraaminophosphonium-Salze durch Anionenaustausch in flüssigem Ammoniak
  9. The Crystal Structure of N,N′-Bis-(1,3-dihydroxy-2-methylprop-2-yl)- pyrazine-2,3-dicarboxamide Semihydrate
  10. β-Diketonates and their Analogs: Stabilization of the Dimeric M2{L}4(D)2 (M = Co, Ni) Core in the Complexes with Dimethyl-N-trichloroacetylamidophosphate {Cl3C(O)NP(O)(OCH3)2}-
  11. Synthesis and Electronic Spectra of Tricarbonylrhenium(I) Chloride Complexes with 9,10-Phenanthrenequinone and 9,10-Phenanthrenequinone Diimine as Acceptor Ligands
  12. Synthesis of Benzisochalcogenol and -azole Derivatives via ortho Metalation of Isophthalamides
  13. Synthesis, Reactions and Spectroscopy of 3-Benzoyl-6-phenylpyridazines of Expected Biological Activity
  14. Imidazole Nucleosides, V. Synthesis of 3′-Fluoro-3′-deoxy-ribofuranosides of 4(5)-Amino-imidazoIe-5(4)carboxamide
  15. Synthetic Potential Inherent in D-Isoascorbic Acid as a Precursor for Pyridazine and Furo[3,2-c]pyridazine Ring Systems with Two Asymmetric Centers
  16. Chiral Pool Synthesis of 4a-Substituted Carbocyclic Cyclopentanoid Nucleoside Precursors, I
  17. Chiral Pool Synthesis of 4a-Substituted Carbocyclic Cyclopentanoid Nucleoside Precursors, II
  18. Die Kristallstruktur von Bis(bromotriphenyl) arsen(V)-hexabromotellurat( IV), [Ph3AsBr]2[TeBr6]
  19. Darstellung und Kristallstruktur von Hexacaesium-hexatelluridodigermanat( III) (Cs6Ge2Te6)
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 16.9.2025 from https://www.degruyterbrill.com/document/doi/10.1515/znb-1999-0810/html
Scroll to top button