Home Die Kristallstruktur von Bis(bromotriphenyl) arsen(V)-hexabromotellurat( IV), [Ph3AsBr]2[TeBr6]
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Die Kristallstruktur von Bis(bromotriphenyl) arsen(V)-hexabromotellurat( IV), [Ph3AsBr]2[TeBr6]

  • Soheila Chitsaz , Bernhard Neumüller and Kurt Dehnicke
Published/Copyright: June 2, 2014
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Yellow-orange single crystals of [Ph3AsBr]2[TeBr6] have been prepared from saturated solutions of Ph3AsBr2 and TeBr4 in acetonitrile and characterized by a crystal structure determination. Space group R3̄c, Z = 12, lattice dimensions at -70 °C: a = b = 1337.9(2), c = 7953.8(4) pm, R = 0.0691. The structure consists of discrete ions [Ph3AsBr]+ and nearly perfectly octahedral [TeBr6]2-.

Received: 1999-5-28
Published Online: 2014-6-2
Published in Print: 1999-8-1

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