Startseite An asymmetric mononuclear cobalt(II) compound derived from 3-bromo-pyridine-2,6-dicarboxylic acid involving in-situ hydrothermal decarboxylation: structure, magnetic property and Hirshfeld surface analysis
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An asymmetric mononuclear cobalt(II) compound derived from 3-bromo-pyridine-2,6-dicarboxylic acid involving in-situ hydrothermal decarboxylation: structure, magnetic property and Hirshfeld surface analysis

  • Jun-Xia Li EMAIL logo , Shuai Ge , Yi-Jing Lu , Xiao-Jie Xu , Chang Liu und Shi-Hui Li EMAIL logo
Veröffentlicht/Copyright: 20. Februar 2023
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Zeitschrift für Kristallographie - Crystalline Materials
Aus der Zeitschrift Zeitschrift für Kristallographie - Crystalline Materials Band 238 Heft 3-4

Abstract

A new cobalt(II) compound with the formula [Co(5-Br-pyc)(2,2′-bipy)(H2O)(Cl)]·2H2O (1·H2O) (5-Br-Hpyc = 5-bromo-pyridine-2-carboxylic acid, 2,2′-bipy = 2,2′-bipyridine) has been hydrothermally synthesized and well characterized. The X-ray single-crystal diffraction analysis showed that 1⋅2H2O has crystallizes in the monoclinic system, space group P21/c (no. 14). The Co(II) center was octahedrally bonded by one bidentate chelate 5-Br-pyc anion and one 2,2′-bipy, one water molecule as well as one chloride anion to form the mononuclear structure of 1⋅2H2O. Complex 1⋅2H2O forms a 3D network through abundant O–H⋅⋅⋅O hydrogen bonds and π⋅⋅⋅π stacking interactions. Notably, the 5-Br-Hpyc ligand was in situ generated by decarboxylation of the 3-bromo-pyridine-2,6-dicarboxylic acid (3-Br-H2pydc) precursor selectively on 2-position under hydrothermal conditions. The magnetic properties, the Hirshfeld surface structure and the synthetic process for 1⋅2H2O have been carefully described and discussed.

Keywords: 3-bromo-pyridine-2,6-dicarboxylic acid; 5-bromo-pyridine-2-carboxylic acid; cobalt complex; Hirshfeld surface analysis; in-situ hydrothermal decarboxylation; magnetic property
Corresponding authors: Jun-Xia Li and Shi-Hui Li, Henan Key Laboratory of Function-Oriented Porous Materials, College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, Henan Province, 471934, P. R. China, E-mail: (J.-X. Li) and

Funding source: Key scientific research projects in colleges

Award Identifier / Grant number: 21A150036

Funding source: Universities of Henan province

Award Identifier / Grant number: 23A150002

  1. Author contributions: Jun-Xia Li: Methodology, conceptualization, data curation, software, writing-original draft, writing-review and editing. Shuai Ge: Formal analysis. Yi-Jing Lu: Writing draft. Xiao-Jie Xu: Software, validation. Chang Liu: Data curation. Shi-Hui Li: Conceptualization, resources, writing-review and editing.

  2. Research funding: This work was supported by the key scientific research projects in colleges and universities of Henan province (No. 21A150036 and 23A150002).

  3. Conflict of interest statement: The authors declare that they have no conflicts of interest.

  4. Code availability: Not applicable.

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Supplementary Material

This article contains supplementary material (https://doi.org/10.1515/zkri-2023-0001).

Received: 2023-01-03
Accepted: 2023-02-05
Published Online: 2023-02-20
Published in Print: 2023-03-28

© 2023 Walter de Gruyter GmbH, Berlin/Boston

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  7. NiAs-derived cyanamide (carbodiimide) structures – a group-theoretical view
  8. Trimorphic TaCrP – A diffraction and 31P solid state NMR spectroscopic study
  9. Microporous framework polar silicate-germanates with a wide isomorphic substitution: (K2.9Cs0.1)(Sc0.7In0.3)[(Si2.95Ge0.05)O9]·H2O and (K2.16Cs0.84)Bi[(Si1.5Ge1.5)O9]·H2O
  10. Organic and Metalorganic Crystal Structures (Original Paper)
  11. A new copper(II) complex containing triclopyr: one-pot crystallization, structure, conformation and Hirshfeld surface analyses
  12. An asymmetric mononuclear cobalt(II) compound derived from 3-bromo-pyridine-2,6-dicarboxylic acid involving in-situ hydrothermal decarboxylation: structure, magnetic property and Hirshfeld surface analysis
https://doi.org/10.1515/zkri-2023-0001
Schlagwörter für diesen Artikel
3-bromo-pyridine-2,6-dicarboxylic acid; 5-bromo-pyridine-2-carboxylic acid; cobalt complex; Hirshfeld surface analysis; in-situ hydrothermal decarboxylation; magnetic property

Artikel in diesem Heft

  1. Frontmatter
  2. In this issue
  3. Micro Review
  4. Organic-inorganic interface chemistry for sustainable materials
  5. Inorganic Crystal Structures (Original Paper)
  6. Magnesium-rich intermetallic compounds Gd5Cu5Mg13 and Tb5Cu5Mg13 – intergrowth variants with CsCl and AlB2 related slabs
  7. NiAs-derived cyanamide (carbodiimide) structures – a group-theoretical view
  8. Trimorphic TaCrP – A diffraction and 31P solid state NMR spectroscopic study
  9. Microporous framework polar silicate-germanates with a wide isomorphic substitution: (K2.9Cs0.1)(Sc0.7In0.3)[(Si2.95Ge0.05)O9]·H2O and (K2.16Cs0.84)Bi[(Si1.5Ge1.5)O9]·H2O
  10. Organic and Metalorganic Crystal Structures (Original Paper)
  11. A new copper(II) complex containing triclopyr: one-pot crystallization, structure, conformation and Hirshfeld surface analyses
  12. An asymmetric mononuclear cobalt(II) compound derived from 3-bromo-pyridine-2,6-dicarboxylic acid involving in-situ hydrothermal decarboxylation: structure, magnetic property and Hirshfeld surface analysis
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