Startseite Microporous framework polar silicate-germanates with a wide isomorphic substitution: (K2.9Cs0.1)(Sc0.7In0.3)[(Si2.95Ge0.05)O9]·H2O and (K2.16Cs0.84)Bi[(Si1.5Ge1.5)O9]·H2O
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Microporous framework polar silicate-germanates with a wide isomorphic substitution: (K2.9Cs0.1)(Sc0.7In0.3)[(Si2.95Ge0.05)O9]·H2O and (K2.16Cs0.84)Bi[(Si1.5Ge1.5)O9]·H2O

  • Anastasiia P. Topnikova EMAIL logo , Elena L. Belokoneva , Anatoly S. Volkov , Olga V. Dimitrova und Sergey Yu. Stefanovich
Veröffentlicht/Copyright: 13. März 2023
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Zeitschrift für Kristallographie - Crystalline Materials
Aus der Zeitschrift Zeitschrift für Kristallographie - Crystalline Materials Band 238 Heft 3-4

Abstract

New silicate-germanates (K2.9Cs0.1)(Sc0.7In0.3)[(Si2.95Ge0.05)O9]·H2O and (K2.16Cs0.84)Bi[(Si0.5Ge0.5)3O9]·H2O have been synthesized in multi-component systems under mild hydrothermal conditions. The new compounds are classified as new representatives of close related K3ScSi3O9·H2O parent structure, sp. gr. Pmn21. Their structural and isomorphic peculiarities are compared with it as well as with earlier investigated K1.46Pb1.54Сa[(Ge0.23Si0.77)3O9](ОН)0.54·0.46Н2О. Together with other known compounds, silicate-germanates form the extensive family A3M[T3O9]·H2O, A = K, Cs, Ca, Pb; M = Ho, Sc, Lu, Tb, Er, Y, Bi, Pb, In; T = Si, Ge, with a mixed microporous framework combined of M-octahedra and T-tetrahedra. Large alkali metal or/and Ca, Pb cations fill broad framework channels with cross-section up to 7.3 Å. Because of wide isomorphic substitution in the channels, and in tetrahedra and octahedra, ion exchange properties in the family are expected. Due to polar symmetry, all the crystals possess second-order nonlinearity which was confirmed with positive SHG tests for four compositions. Powder SHG experiments demonstrated moderate second harmonic intensities of order of α-quartz standard signals.

Keywords: hydrothermal synthesis; isomorphic substitution; mixed microporous framework; second harmonic generation; silicate-germanate; single crystal structure
Corresponding author: Anastasiia P. Topnikova, Crystallography, Lomonosov Moscow State University, Faculty of Geology, Leninskie Gory 1, Moscow 119991, Russian Federation, E-mail:

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: The authors are grateful to Natalia Zubkova for her aid in the collection of the experimental X-ray diffraction data and absorption correction and to Vasiliy Yapaskurt for the determination of crystal chemical composition. We are thankful to Shilie Pan and Zhihua Yang for discussion of nonlinear optical properties in a family of compounds. Anatoly Volkov was partial supported by RFBR grant No. 20-03-00702 a.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2022-08-26
Accepted: 2023-02-20
Published Online: 2023-03-13
Published in Print: 2023-03-28

© 2023 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. In this issue
  3. Micro Review
  4. Organic-inorganic interface chemistry for sustainable materials
  5. Inorganic Crystal Structures (Original Paper)
  6. Magnesium-rich intermetallic compounds Gd5Cu5Mg13 and Tb5Cu5Mg13 – intergrowth variants with CsCl and AlB2 related slabs
  7. NiAs-derived cyanamide (carbodiimide) structures – a group-theoretical view
  8. Trimorphic TaCrP – A diffraction and 31P solid state NMR spectroscopic study
  9. Microporous framework polar silicate-germanates with a wide isomorphic substitution: (K2.9Cs0.1)(Sc0.7In0.3)[(Si2.95Ge0.05)O9]·H2O and (K2.16Cs0.84)Bi[(Si1.5Ge1.5)O9]·H2O
  10. Organic and Metalorganic Crystal Structures (Original Paper)
  11. A new copper(II) complex containing triclopyr: one-pot crystallization, structure, conformation and Hirshfeld surface analyses
  12. An asymmetric mononuclear cobalt(II) compound derived from 3-bromo-pyridine-2,6-dicarboxylic acid involving in-situ hydrothermal decarboxylation: structure, magnetic property and Hirshfeld surface analysis
https://doi.org/10.1515/zkri-2022-0056
Schlagwörter für diesen Artikel
hydrothermal synthesis; isomorphic substitution; mixed microporous framework; second harmonic generation; silicate-germanate; single crystal structure

Artikel in diesem Heft

  1. Frontmatter
  2. In this issue
  3. Micro Review
  4. Organic-inorganic interface chemistry for sustainable materials
  5. Inorganic Crystal Structures (Original Paper)
  6. Magnesium-rich intermetallic compounds Gd5Cu5Mg13 and Tb5Cu5Mg13 – intergrowth variants with CsCl and AlB2 related slabs
  7. NiAs-derived cyanamide (carbodiimide) structures – a group-theoretical view
  8. Trimorphic TaCrP – A diffraction and 31P solid state NMR spectroscopic study
  9. Microporous framework polar silicate-germanates with a wide isomorphic substitution: (K2.9Cs0.1)(Sc0.7In0.3)[(Si2.95Ge0.05)O9]·H2O and (K2.16Cs0.84)Bi[(Si1.5Ge1.5)O9]·H2O
  10. Organic and Metalorganic Crystal Structures (Original Paper)
  11. A new copper(II) complex containing triclopyr: one-pot crystallization, structure, conformation and Hirshfeld surface analyses
  12. An asymmetric mononuclear cobalt(II) compound derived from 3-bromo-pyridine-2,6-dicarboxylic acid involving in-situ hydrothermal decarboxylation: structure, magnetic property and Hirshfeld surface analysis
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